Antistatic hard coat incorporating a polymer comprising pendant fluorinated groups

• US 5,518,788 A
• Filed: 11/14/1994
• Issued: 05/21/1996
• Est. Priority Date: 11/14/1994
• Status: Expired due to Fees

• Current Assignee: 3M Company
• Original Assignee: 3M Company
• Inventors: Invie, Judith M.
• Primary Examiner(s): JAGANNATHAN, VASUDEVAN SALEM
• Application Number:
  US08/339,383
• Time in Patent Office: 554 Days
• Field of Search: 369/275.1, 369/275.5, 369/284, 369/286, 522/109, 522/127, 525/195, 525/200, 525/326.3, 525/326.4, 525/343, 525/366, 525/378, 525/383, 428/65.1
• US Class Current: 428/65.1
• CPC Class Codes: C09K 3/16 Anti-static materials
• CPC Class Codes: G11B 2007/24304 group 2 or 12 elements (e.g. Be, Ca, Mg, Zn, Cd)
• CPC Class Codes: G11B 7/24056 Light transmission layers lying on the light entrance side and being thinner than the substrate, e.g. specially adapted for Blu-ray® discs
• CPC Class Codes: G11B 7/2534 polycarbonates [PC]
• CPC Class Codes: G11B 7/2542 consisting essentially of organic resins
• CPC Class Codes: G11B 7/2585 based on aluminium

Abstract

An optical recording disk having an antistatic hard coat layer provided on at least one surface of the disk, wherein the hard coat layer comprises a fluorinated ionic salt; a polymer comprising a plurality of pendant fluorinated groups, and optionally a nonionic fluorinated surfactant. The polymer comprising a plurality of pendant fluorinated groups is preferably a copolymer derived from monomers comprising a nonfluorinated vinyl monomer; and a vinyl monomer comprising a fluorinated group.

Claims

1. An optical recording disk having an antistatic hard coat layer provided on at least one surface of the disk, wherein the hard coat layer comprises

a) a fluorinated ionic salt;

b) a vinyl copolymer comprising a plurality of pendant fluorinated groups; and

a nonfluorinated polymer.

2. The optical recording disk of claim 1, wherein the fluorinated ionic salt has the formula ##STR25## wherein n is from 1 to 16 and M is chosen from the group consisting of:

Na⁺, Li⁺, K⁺, H⁺, and NH₄⁺.

3. The optical recording disk of claim 2, wherein M is Li⁺ and n is from about 8 to 10.

4. The optical recording disk of claim 1, wherein the polymer comprising a plurality of pendant fluorinated groups is a copolymer derived from monomers comprising:

a) a nonfluorinated vinyl monomer; and

b) a vinyl monomer comprising a fluorinated group.

5. The optical recording disk of claim 4, wherein the nonfluorinated vinyl monomer is a (meth)acrylate functional monomer.

6. The optical recording disk of claim 5, wherein the (meth)acrylate functional monomer has the formula ##STR26## wherein y is from about 1 to 6;

R'"'"' is H or CH₃ ; and

R has a valency y, and comprises species chosen from the group consisting of;

urethanes, oxyalkylene groups, alkyl groups, and allyl-containing groups.

7. The optical recording disk of claim 4, wherein the nonfluorinated vinyl monomer comprises an oxyalkylene group.

8. The optical recording disk of claim 7, wherein the nonfluorinated vinyl monomer has the formula ##STR27## wherein x is chosen such that the average molecular weight of the nonfluorinated vinyl monomer is in the range from 500 to 5000.

9. The optical recording disk of claim 8, wherein the average molecular weight of the nonfluorinated vinyl monomer is in the range from 500 to 1000.

10. The optical recording disk of claim 8, wherein the average molecular weight of the nonfluorinated vinyl monomer is about 750.

11. The optical recording disk of claim 7, wherein the nonfluorinated vinyl monomer is ##STR28## wherein x, y, and z are chosen such that the average molecular weight of the nonfluorinated vinyl monomer is in the range from 500 to 10000, and x is in the range from 7 to 17, y is in the range from 16 to 26, and z is in the range from 7 to 17.

12. The optical recording disk of claim 11, wherein the average molecular weight of the nonfluorinated vinyl monomer is about 2200.

13. The optical recording disk of claim 11, wherein x=12, y=21, and z=12.

14. The optical recording disk of claim 1, wherein the polymer comprising a plurality of pendant fluorinated groups further comprises a plurality of pendant oxyalkylene groups.

15. The optical recording disk of claim 4, wherein the vinyl monomer comprising a fluorinated group is a (meth)acrylate of the formula ##STR29## wherein X is a divalent linking group, R'"'"' is H or CH₃, and R_f is a fluorinated group.

16. The optical recording disk of claim 15, wherein R_f is a perfluoro group having the general formula --C_n F_2n+1, wherein n is in the range from 4 to 16.

17. The optical recording disk of claim 15, wherein the vinyl monomer comprising a fluorinated group has the formula:

##STR30## wherein n is from 4 to 16, X₁ is a divalent linking group, R is hydrogen or a lower alkyl of 1-12 carbon atoms and R'"'"' is H or --CH₃.

18. The optical recording disk of claim 17, wherein n is 8 and R is chosen from the group consisting of CH₃ CH₂ -- and CH₃ CH₂ CH₂ CH₂ --.

19. The optical recording disk of claim 1, wherein the hard coat layer further comprises a nonionic fluorinated surfactant.

20. The optical recording disk of claim 19, wherein the nonionic fluorinated surfactant has the formula ##STR31## wherein x is 7.2.

21. The optical recording disk of claim 1, wherein the nonfluorinated polymer is a copolymer of one or more nonfluorinated vinyl monomers.