Pesticide compositions for control of fungal disease in cultivated crops

• US 5,518,987 A
• Filed: 10/03/1995
• Issued: 05/21/1996
• Est. Priority Date: 10/03/1995
• Status: Expired due to Fees

• Current Assignee: Church & Dwight Company Incorporated
• Original Assignee: Church & Dwight Company Incorporated
• Inventors: Winston, Anthony E.
• Primary Examiner(s): Robinson, Allen J.
• Assistant Examiner(s): NOT, DEFINED
• Application Number:
  US08/538,214
• Time in Patent Office: 231 Days
• Field of Search: 504/101, 424/715, 424/716, 424/717, 71/DIG. 1, 514/557, 514/558, 514/560, 514/709, 514/741, 514/770, 514/772, 514/773, 514/774, 514/775, 514/776, 514/777, 514/778, 514/779, 514/780, 514/781, 514/782, 514/784, 514/361 , 514/363
• US Class Current: 504/101
• CPC Class Codes: A01N 2300/00 Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
• CPC Class Codes: A01N 25/24 containing ingredients to enhance the sticking of the active ingredients
• CPC Class Codes: A01N 25/32 Ingredients for reducing the noxious effect of the active substances to organisms other than pests, e.g. toxicity reducing compositions, self-destructing compositions
• CPC Class Codes: A01N 43/82 five-membered rings with three ring hetero atoms
• CPC Class Codes: A01N 59/00 Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
• CPC Class Codes: A01N 59/04 Carbon disulfide; Carbon monoxide; Carbon dioxide
• CPC Class Codes: C05G 3/60 Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
• CPC Class Codes: C05G 3/70 for affecting wettability, e.g. drying agents

Abstract

The present invention provides an effective method for controlling foliage and root fungus infection in cultivated crops. A fungicide composition in the form of an aqueous formulation which is applied to pre-harvest crops contains ingredients such as etridiazole, potassium bicarbonate, sodium carbonate, potassium oleate, potassium caprylate and xanthan gum. The combination of potassium oleate, potassium caprylate and xanthan gum functions as an effective spreader-sticker medium for forming an adherent coating on plant foliage surfaces, and for saturating ground soil. The coating exhibits both immediate and long duration fungicidal activities.

Claims

1. A method for controlling fungal disease in cultivated plants which comprises contacting the plant matter with a fungicidally effective application of an aqueous formulation which has a content comprising (1) between about 0.002-2 weight percent of an ingredient selected from the group consisting of alkali metal and ammonium bicarbonates;

(2) between about 0-1 weight percent of a basic ingredient selected from the group consisting of alkali metal and ammonium carbonates;

(3) between about 0.001-2 weight percent of etridiazole;

(4) between about 0-1 weight percent of a surfactant ingredient;

(5) between about 0-0.25 weight percent of a hydrotrope ingredient selected from the group consisting of alkali metal and ammonium C₇ -C₁₀ fatty acid salts; and

(6) between about 0-0.5 weight percent of a hydrophilic polymer ingredient;

based on the formulation weight.

2. A method in accordance with claim 1 wherein the bicarbonate ingredient is sodium bicarbonate, potassium bicarbonate or ammonium bicarbonate, or any mixture thereof.

3. A method in accordance with claim 1 wherein the basic ingredient is between about 0.01-1 weight percent of sodium carbonate, potassium carbonate, ammonium carbonate or lithium carbonate, or any mixture thereof, and the pH of the formulation is in the range between about 7.5-11.

4. A method in accordance with claim 1 wherein the surfactant ingredient is between about 0.05-1 weight percent of a member selected from the group consisting of alkali metal and ammonium C₁₂ -C₃₀ aliphatic-containing carboxylate, sulfonate, sulfate and phosphate salts.

5. A method in accordance with claim 1 wherein the surfactant ingredient is palmitic acid, stearic acid, oleic acid or palm fatty acid distillate salt or any mixture thereof.

6. A method in accordance with claim 1 wherein the surfactant ingredient is benzenesulfonate or sulfosuccinate salt or any mixture thereof.

7. A method in accordance with claim 1 wherein the surfactant ingredient is an oxyalkylene-containing sulfate salt.

8. A method in accordance with claim 1 wherein the hydrotrope ingredient is between about 0.01-0.25 weight percent of enanthylic acid, caprylic acid, pelargonic acid or capric acid salt or any mixture thereof.

9. A method in accordance with claim 1 wherein the hydrophilic polymer ingredient comprises between about 0.01-0.5 weight percent of a hydrocolloid gum.

10. A method in accordance with claim 1 wherein the hydrophilic polymer ingredient comprises between about 0.01-0.5 weight percent of a cellulosic derivative.

11. A method in accordance with claim 1 wherein the hydrophilic polymer ingredient comprises between about 0.01-0.5 weight percent of a starch derivative.

12. A method in accordance with claim 1 wherein the hydrophilic polymer ingredient comprises between about 0.01-0.5 weight percent of xanthan gum or guar gum.

13. A method in accordance with claim 1 wherein the cultivated plants are in a growth cycle and the aqueous formulation is applied to the plants at least twice with a time interval between about 5-20 days.

14. A method in accordance with claim 1 wherein the cultivated plants are one of a crop selected from the group consisting of peanut, cotton, vegetables, turf, and ornamentals.

15. A method in accordance with claim 1 wherein the disease being controlled is a soil-borne fungus.

16. A method in accordance with claim 1 wherein the disease being controlled is a Rhizoctonia, Pythium, Sclerotinea, Phytophthora or Fusarium fungus.

17. A method in accordance with claim 1 wherein the disease being controlled is a powdery mildew or downy mildew fungus.

18. A method in accordance with claim 1 wherein the disease being controlled is soil-borne Pythium sp. or Sclerotinea Homeocarpa fungus.

19. A fungicide composition which is a dry blend formulation comprising (1) between about 0.02-20 parts by weight of an ingredient selected from the group consisting of alkali metal and ammonium bicarbonates;

(2) between about 0-10 parts by weight of an ingredient selected from the group consisting of alkali metal and ammonium carbonates;

(3) between about 0.01-20 parts by weight of etridiazole;

(4) between about 0-10 parts by weight of a surfactant ingredient;

(5) between about 0-2.5 parts by weight of a hydrotrope ingredient selected from the group consisting of alkali metal and ammonium C₇ -C₁₀ fatty acid salts; and

(6) between about 0-5 parts by weight of a hydrophilic polymer ingredient.

20. A fungicide composition in accordance with claim 19 wherein the surfactant ingredient is between about 0.5-10 parts by weight of a member selected from the group consisting of alkali metal and ammonium C₁₂ -C₃₀ aliphatic-containing carboxylate, sulfonate, sulfate and phosphate salts.

21. A fungicide composition in accordance with claim 19 which has a fertilizer effective ratio and quantity of nitrogen, phosphorus and potassium elements.

22. A fungicide composition in accordance with claim 19 which is a water-diluted formulation for fungicidally effective application to cultivated crops for control of foliar-borne and soil-borne fungal disease.