Silicone rubber compositions

• US 5,521,245 A
• Filed: 06/29/1994
• Issued: 05/28/1996
• Est. Priority Date: 06/30/1993
• Status: Expired due to Term

• Current Assignee: Shin-Etsu Chemical Company Limited
• Original Assignee: Shin-Etsu Chemical Company Limited
• Inventors: Nakamura, Tsutomu, Inokuchi, Yoshinori, Hirabayashi, Satao
• Primary Examiner(s): Sweet, Mark D.
• Application Number:
  US08/267,700
• Time in Patent Office: 699 Days
• Field of Search: 524/493, 524/500, 524/588, 525/478, 528/15, 528/31
• US Class Current: 524/493
• CPC Class Codes: C08G 77/12 containing silicon bound to hydrogen C08G77/045 takes precedence
• CPC Class Codes: C08G 77/20 containing silicon bound to unsaturated aliphatic groups C08G77/045 takes precedence
• CPC Class Codes: C08G 77/70 Siloxanes defined by use of the MDTQ nomenclature
• CPC Class Codes: C08L 2666/54 Inorganic substances
• CPC Class Codes: C08L 83/00 Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 83/04 Polysiloxanes

Abstract

A rubber compound comprising (A) an organopolysiloxane having at least two alkenyl groups in a molecule and (B) reinforcing silica powder is blended with (C) silicone elastomer particles obtained by reacting an organohydrogenpolysiloxane with a vinyl group-containing organopolysiloxane such that the molar ratio of .tbd.SiH group to --CH═CH₂ group ranges from 1.2 to 5 and (D) a platinum catalyst to form a silicone rubber composition which cures into a product having high rubber strength despite the inclusion of silicone elastomer particles. The composition finds typical use as silicone rubber parts in copying machines.

Claims

1. A silicone rubber composition comprising

(A) 100 parts by weight of an organopolysiloxane of the following compositional formula:

space="preserve" listing-type="equation">R.sub.n.sup.1 SiO.sub.(4-n)/2 (

     1)

wherein R¹ is independently selected from monovalent substituted or unsubstituted hydrocarbon groups and letter n is a positive number in the range of from 1.98 to 2.02, having at least two aliphatic unsaturated groups in a molecule,

(B) about 5 to about 70 parts by weight of reinforcing silica powder having a specific surface area of at least 50 m² /g,

(C) about 5 to about 200 parts by weight of silicone elastomer particles obtained by reacting an organohydrogenpolysiloxane with a vinyl group-containing organopolysiloxane such that the molar ratio of .tbd.SiH group to --CH═

CH₂ group ranges from 1.2 to 5, and

(D) a platinum series catalyst optionally in admixture with an organic peroxide catalyst.

2. The composition of claim 1 wherein said silicone elastomer particles are obtained by reacting an organohydrogenpolysiloxane with a vinyl group-containing organopolysiloxane such that the molar ratio of .tbd.SiH group to --CH═

CH₂ group ranges from 1.5 to 3.5.

3. The composition of claim 1 wherein said silicone elastomer particles have a mean particle size of about 0.1 to about 250 μ

m.

4. The composition of claim 1 wherein said platinum series catalyst (D) is present in such an amount to give about 1 to 2,000 parts by weight of elemental platinum per million parts by weight of the organopolysiloxane (A).

5. The composition of claim 1, wherein the silicone elastomer particles are spherical silicone elastomer particles.

6. The composition of claim 5, wherein said spherical silicone elastomer particles are obtained by emulsion polymerization of the organohydrogenpolysiloxane and the vinyl group-containing organopolysiloxane in the presence of a platinum catalyst.

7. The composition of claim 5, wherein said spherical silicone elastomer particles have a mean particle size of about 0.1 to about 250 μ

m.

8. The composition of claim 1, wherein, in component (A), R¹ is a substituted or unsubstituted monovalent hydrocarbon group of 1 to 10 carbon atoms.

9. The composition of claim 8, wherein, in component (A), R¹ is an alkyl, cycloalkyl, alkenyl, phenyl or tolyl group, optionally substituted by halogen atoms or cyano groups.

10. The composition of claim 1, wherein the reinforcing silica powder, (B), has a specific surface area of about 100 to about 300 m² /g.

11. The composition of claim 1, wherein the vinyl group-containing organopolysiloxane used to obtain the silicone elastomer particles is of the following formula (2):

##STR2## wherein R² and R³ are the same or different substituted or unsubstituted monovalent hydrocarbon groups and n is a positive integer of 1 to 1000; and

,

the organohydrogenpolysiloxane used to obtain the silicone elastomer particles has at least two hydrogen atoms bonded to silicon atoms in a molecule and has a degree of polymerization of at most 300.

12. The composition of claim 11, wherein, in the organopolysiloxane of formula (2), R² and R³ are independently an alkyl, cycloalkyl, alkenyl, phenyl or tolyl group, optionally substituted by halogen atoms or cyano groups.

13. The composition of claim 1, wherein the silicone elastomer particles (C) are present in an amount of 10 to 150 parts by weight per 100 parts by weight of the organopolysiloxane (A).

14. The composition of claim 1, wherein component (D) contains a platinum series catalyst in admixture with an organic peroxide catalyst.

15. The composition of claim 14, which contains no organohydrogenpolysiloxane component, other than that used to prepare the silicone elastomer particles, (C).

16. The composition of claim 14, wherein the organic peroxide is present in an amount of 0.1 to 5 parts by weight per 100 parts by weight of the organopolysiloxane (A).