Radiation detector employing solid-state scintillator material and preparation methods therefor

• US 5,521,387 A
• Filed: 02/01/1991
• Issued: 05/28/1996
• Est. Priority Date: 12/30/1985
• Status: Expired due to Term

• Current Assignee: General Electric Company
• Original Assignee: General Electric Company
• Inventors: Lyons, Robert J., Cusano, Dominic A., Greskovich, Charles D., Riedner, Robert J.
• Primary Examiner(s): Bell, Mark L.
• Assistant Examiner(s): KOSLOW, CAROL M
• Application Number:
  US07/649,332
• Time in Patent Office: 1,943 Days
• Field of Search: 252/301.4 R, 252/301.17, 250/367, 501/152
• US Class Current: 250/367
• CPC Class Codes: C04B 35/50 based on rare-earth compounds non-oxide rare earth compounds C04B35/5156
• CPC Class Codes: C04B 35/505 based on yttrium oxide
• CPC Class Codes: C04B 35/6455 Hot isostatic pressing
• CPC Class Codes: C09K 11/7769 Oxides C09K11/7768 takes precedence
• CPC Class Codes: G01T 1/1644 using an array of optically separate scintillation elements permitting direct location of scintillations G01T1/1645 takes precedence
• CPC Class Codes: G01T 1/202 the detector being a crystal
• CPC Class Codes: G01T 1/2023 Selection of materials see provisionally also G01T1/202
• CPC Class Codes: H01R 13/5205 Sealing means between cable and housing, e.g. grommet H01R13/5221 takes precedence
• CPC Class Codes: H04N 7/04 Systems for the transmission of one television signal, i.e. both picture and sound, by a single carrier H04N7/084, H04N7/087 take precedence

Abstract

A polycrystalline ceramic scintillator exhibiting reduced afterglow includes between about 5 and 50 mole percent Gd₂ O₃, between about 0.02 and 12 mole percent of either Eu₂ O₃ or Nd₂ O₃ as a rare earth activator oxide, and between about 0.003 and 0.5 mole percent of either Pr₂ O₃ and Tb₂ O₃ as an afterglow reducer. The remainder of the scintillator composition is Y₂ O₃. The resulting scintillator is especially useful for a radiation detector of the type having a plurality of radiation receiving channels. A scintillator body is disposed in each channel so that radiation being received therein is incident on the scintillator body and causes the body to convert the incident radiation to light energy of a predetermined wavelength. The radiation detector also includes means for converting the light energy from the scintillator into electrical signals which are proportional to the amount of radiation incident on the scintillator body. Methods for preparing the scintillator of the present invention include sintering, sintering combined with gas hot isostatic pressing, and vacuum hot pressing.

Claims

1. A radiation detector for a computerized tomography scanner exhibiting improved afterglow characteristics when used with a source of penetrating x-ray radiation, said radiation detector comprising:

a detector array housing;

a plurality of channels defined in said housing, for receiving said radiation;

a polycrystalline ceramic scintillator body disposed in each said channel so that x-ray radiation being received by said channel is incident on said scintillator body, and so that said incident radiation causes said body to scintillate at a wavelength, the composition of said scintillator body consisting essentially of between about 5 and 50 mole percent Gd₂ O₃, between about 0.02 and 12 mole percent of a rare earth activator oxide selected from the group consisting of Eu₂ O₃ and Nd₂ O₃, and between about 0.008 and 0.5 mole percent of at least one afterglow reducer selected from the group consisting of Pr₂ O₃ and Tb₂ O₃, the remainder of said composition being Y₂ O₃ ; and

means for detecting said wavelength scintillator energy emitted from each said scintillator body and for generating electrical signals in response thereto, said detecting means being coupled to each said scintillator body so as to produce a set of signals related to the x-ray radiation received in the respective channels of said detector array housing.

2. The detector of claim 1 wherein Gd₂ O₃ is present in an amount of between about 20 and 40 mole percent.

3. The detector of claim 1 wherein said rare earth activator oxide is Eu₂ O₃ present in an amount of between about 1 and 6 mole percent.

4. The detector of claim 1 wherein said rare earth activator oxide is Nd₂ O₃ present in an amount of between about 0.05 and 1.5 mole percent.

5. The detector of claim 1 wherein said afterglow reducer is Pr₂ O₃ present in an amount of between about 0.008 and 0.04 mole percent.

6. The detector of claim 1 wherein said afterglow reducer is Tb₂ O₃ present in an amount of between about 0.008 and 0.035 mole percent.

7. The detector of claim 1 wherein said afterglow reducer is Pr₂ O₃ present in an amount of between about 0.004 and 0.016 mole percent.

8. The detector of claim 1 wherein said afterglow reducer is Tb₂ O₃ present in an amount of between about 0.008 and 0.014 mole percent.

9. A polycrystalline ceramic scintillator exhibiting improved afterglow characteristics, said scintillator comprising a composition consisting essentially of between about 5 and 50 mole percent Gd₂ O₃, between about 0.02 and 12 mole percent of a rare earth activator oxide selected from the group consisting of Eu₂ O₃ and Nd₂ O₃, and between about 0.008 and 0.5 mole percent of at least one afterglow reducer selected from the group consisting of Pr₂ O₃ and Tb₂ O₃, the remainder of said composition being Y₂ O₃.

10. The scintillator of claim 9 wherein Gd₂ O₃ is present in an amount of between about 20 and 40 mole percent.

11. The scintillator of claim 9 wherein said rare earth activator is Eu₂ O₃ present in an amount of between about 1 and 6 mole percent.

12. The scintillator of claim 9 wherein said rare earth activator is Nd₂ O₃ present in an amount of between about 0.05 and 1.5 mole percent.

13. The scintillator of claim 9 wherein said afterglow reducer is present in an amount of between about 0.008 and 0.04 mole percent.

14. A polycrystalline ceramic scintillator exhibiting improved afterglow characteristics, said scintillator comprising a composition consisting essentially of between about 5 and 50 mole percent Gd₂ O₃, between about 0.02 and 12 mole percent of a rare earth activator oxide selected from the group consisting of E₂ O₃ and Nd₂ O₃, and between about 0.008 and 0.016 mole percent of at least one afterglow reducer selected from the group consisting of Pr₂ O₃ and Tb₂ O₃, the remainder of said composition being Y₂ O₃.

15. The scintillator of claim 14 wherein Gd₂ O₃ is present in an amount of between about 20 and 40 mole percent.

16. The scintillator of claim 14 wherein said rare earth activator is Eu₂ O₃ present in an amount of between about 1 and 6 mole percent.

17. The scintillator of claim 14 wherein said rare earth activator is Nd₂ O₃ present in an amount of between about 0.05 and 1.5 mole percent.

18. The scintillator of claim 14 wherein Gd₂ O₃ is present in an amount of about 30 mole percent, and wherein said rare earth activator oxide is Eu₂ O₃ present in an amount of about 3 mole percent.

19. The scintillator of claim 18 wherein said afterglow reducer is present in an amount of between about 0.01 and 0.012 mole percent.

20. A radiation detector exhibiting improved afterglow characteristics when used with a source of penetrating radiation, said radiation detector comprising:

a detector array housing;

a plurality of channels defined in said housing, for receiving said radiation;

a polycrystalline ceramic scintillator body disposed in each said channel so that radiation being received by said channel is incident on said scintillator body, and so that said incident radiation causes said body to scintillate at a wavelength, the composition of said scintillator body consisting essentially of between about 5 and 50 mole percent Gd₂ O₃, between about 0.02 and 12 mole percent of a rare earth activator oxide selected from the group consisting of Eu₂ O₃ and Nd₂ O₃, and between about 0.008 and 0.5 mole percent of an afterglow reducer consisting of Pr₂ O₃, the remainder of said composition being Y₂ O₃ ; and

means for detecting said wavelength scintillator energy emitted from each said scintillator body and for generating electrical signals in response thereto, said detecting means being coupled to each said scintillator body so as to produce a set of signals related to the radiation received in the respective channels of said detector array housing.

21. A polycrystalline ceramic scintillator exhibiting improved afterglow characteristics, said scintillator comprising a composition consisting essentially of between about 5 and 50 mole percent Gd₂ O₃, between about 0.02 and 12 mole percent of a rare earth activator oxide selected from the group consisting of Eu₂ O₃ and Nd₂ O₃, and between about 0.008 and 0.016 mole percent of an afterglow reducer consisting of Pr₂ O₃, the remainder of said composition being Y₂ O₃.