Two-stage kraft cooking

• US 5,522,958 A
• Filed: 07/18/1994
• Issued: 06/04/1996
• Est. Priority Date: 07/18/1994
• Status: Expired due to Term

• Current Assignee: FPInnovations
• Original Assignee: Pulp & Paper Research Institute of Canada
• Inventors: Li, Jian
• Primary Examiner(s): Lacey, David L.
• Assistant Examiner(s): NGUYEN, TAN D
• Application Number:
  US08/276,804
• Time in Patent Office: 687 Days
• Field of Search: 162/19, 162/39, 162/45, 162/47, 162/59, 162/61, 162/86
• US Class Current: 162/19
• CPC Class Codes: D21C 3/022 in presence of S-containing compounds
• CPC Class Codes: D21C 3/26 Multistage processes

Abstract

A method for the production of kraft pulps in a digester, by modifying the cooking chemical concentration, and lignin concentration profiles during the cook, has provided extended delignification and improved selectivity in a simpler way than has previously been possible. The cooking is performed at an elevated temperature in two stages. The first stage liquor is a mixture of 1) the spent liquor of the second stage and 2) a portion of the conventional charge of fresh cooking chemicals needed for the complete cook. The second stage liquor is made up by adding an aqueous diluent, for example, fresh water or washing filtrate to the remaining portion of the fresh cooking chemicals.

Claims

1. A process for kraft digestion of wood chips to form a cellulosic pulp in first and second cooking stages comprising:

(a) providing a kraft cooking liquor having a predetermined effective alkali (EA) concentration and a predetermined sulfidity,

(b) cooking wood chips in the first stage, in a cooking zone, with a first-stage cooking liquor comprising a first portion of said kraft cooking liquor of step (a) in admixture with a spent kraft cooking liquor from the second stage, such that said first stage cooking liquor has an EA concentration less than said predetermined EA concentration in step (a), and a sulfidity higher than said predetermined sulfidity in step (a), to initiate pulp formation, for a time corresponding to an H-factor of 300 to 700 with formation of by-product liquor, at completion of said first stage, said first portion comprising 40% to 60% of said kraft cooking liquor in step (a),

(c) at completion of said first stage, displacing the by-product liquor from the cooking zone with a second-stage cooking liquor comprising a second, remaining portion of said liquor of step (a), in admixture with an aqueous diluent, such that said second stage cooking liquor has an EA concentration higher than the EA concentration of a partially spent liquor derived by employing the whole of the liquor of step (a) as the first stage cooking liquor in step (b), and a lignin concentration lower than the lignin concentration of said partially spent liquor,

(d) cooking the wood chips from the first stage in the second stage, in said cooking zone, with said second-stage cooking liquor, to complete the pulp formation with production of spent liquor, and

(e) recycling the spent liquor from step (d) to provide said spent kraft cooking liquor in step (b);

wherein the cooking in step (b) is at a temperature of 160°

to 180°

C. and cooking steps (b) and (d) have a total cooking time corresponding to an H-factor of 1200 to 1800.

2. A process according to claim 1, in which said aqueous diluent is water.

3. A process according to claim 1, in which said aqueous diluent is a brownstock washer filtrate.

4. A process according to claim 1, in which said H-factor in step (b) is 500 to 600.

5. A process according to claim 4, in which said first portion, in step (b), comprises 50% of said kraft cooking liquor in step (a) and said second portion, in step (d) comprises the remaining 50% of said kraft cooking liquor.

8. A process according to claim 5, wherein said impregnating in step b) is at a temperature of 70°

to 90°

C., a liquor;

wood chips ratio of 3.5;

1 to 5;

1 and under a pressure of 600 to 800 kPa, to effect pressure impregnation of said wood chips with said first-stage cooking liquor.

9. A process according to claim 1, wherein said second-stage liquor in step (d) is at a temperature of 160°

to 180°

C. and said elevated cooking temperature in step (e) is 160°

to 180°

C.

6. A process for producing a cellulosic pulp from wood chips in a kraft digestion in first and second cooking stages comprising:

(a) providing a kraft cooking liquor having a predetermined concentration of cooking chemicals,

(b) impregnating wood chips with a first-stage cooking liquor, said first-stage cooking liquor comprising a mixture of a first portion of said kraft cooking liquor of step (a) and a spent kraft cooking liquor from the second cooking stage, said first portion comprising 40% to 60% of said kraft cooking liquor in step (a),

(c) in the first cooking stage, cooking the impregnated wood chips in the first stage cooking liquor, in a cooking zone, at a cooking temperature of 160°

to 180°

C. to initiate pulp formation from said wood chips, with formation of a by-product liquor, for a time corresponding to an H-factor of 500 to 600,

(d) displacing the by-product liquor from the cooking zone with a second-stage cooking liquor, said second-stage cooking liquor comprising a second, remainder portion of said kraft cooking liquor of step (a) and a wash liquid,

(e) in the second cooking stage, cooking the wood chips from the first stage in the second-stage cooking liquor at a cooking temperature to produce a cellulosic pulp and a spent liquor, and

(f) recycling said spent liquor formed in step (e) to provide said spent kraft cooking liquor in step (b);

wherein said cooking in steps (c) and (e) is for a total time corresponding to an H-factor of 1200 to 1800.

7. A process according to claim 6, further comprising displacing said spent liquor in step (e), from said cooking zone, with a wash liquid.

10. A process according to claim 6, wherein said wash liquid is water.

11. A process according to claim 6, wherein said wash liquid is a brownstock washer filtrate.

12. A process according to claim 6, wherein

i) said first-stage cooking liquor has a concentration of cooking chemicals less than said predetermined concentration in step (a) and has an effective alkali (EA) concentration lower than that of said liquor in step (a), and a sulfidity higher than that of said liquor in step (a);

and

ii) said second-stage liquor has a concentration of cooking chemicals less than said predetermined concentration in step (a) and has an EA concentration higher than the EA concentration of a partially spent liquor derived by employing the whole of the liquor of step (a) as a first-stage cooking liquor in step (b), and a lignin concentration lower than the lignin concentration of said partially spent liquor.

13. A process for producing a cellulosic pulp by kraft digestion of wood chips in first and second cooking stages comprising:

(a) providing a fresh kraft cooking liquor having a predetermined effective alkali (EA) concentration and a predetermined sulfidity,

(b) impregnating wood chips at an elevated temperature and pressure, with a first-stage cooking liquor in a cooking zone, said first stage cooking liquor comprising a mixture of a spent kraft cooking liquor from the second cooking stage and a first portion of said fresh kraft cooking liquor of step (a), said first-stage cooking liquor having an effective alkali (EA) concentration lower than that of said liquor in step (a), and a sulfidity higher than that of the liquor in step (a), effective to provide a reduced removal of carbohydrates and a reduced degradation of cellulosic material in said wood chips, as compared to that produced by employing the whole of the liquor of step (a) as the first stage cooking liquor, said first portion comprising 40% to 60% of said kraft cooking liquor of step (a),

(c) releasing the elevated pressure, in said first cooking stage and cooking the impregnated wood chips, in said cooking zone, with said first-stage cooking liquor in a first stage cooking, at a temperature of 160°

to 180°

C. for a time corresponding to an H-factor of 500 to 700, to initiate conversion of the wood chips to cellulosic pulp, with formation of by-product liquor,

(d) at completion of said first-stage cooking, displacing the by-product liquor from said cooking zone with a second-stage cooking liquor having a temperature of 160°

to 180°

C., said second-stage cooking liquor comprising a second, remaining portion of said liquor of step (a), in admixture with an aqueous diluent selected from the group consisting of water or brownstock washer filtrate;

said second-stage cooking liquor having an EA concentration higher than the EA concentration of a partially spent liquor derived by employing the whole of the liquor of step (a) as the first stage cooking liquor in step (b), and a lignin concentration lower than the lignin concentration of said partially spent liquor, such that the second-stage cooking has a delignification rate greater than that which would be provided by said partially spent liquor,

(e) cooking the wood chips from the first stage, in the second-stage cooking, in the second-stage cooking liquor, in said cooking zone, at a temperature of 160°

to 180°

C. to produce a cellulosic pulp and a spent liquor,

(f) at completion of said second-stage cooking, displacing the spent liquor from said cooking zone, and

(g) recycling the displaced spent liquor from step (f) to provide said spent kraft cooking liquor in step (b);

wherein the cooking in steps (c) and (e) is for a total cooking time corresponding to an H-factor of 1200 to 1800.

14. A process according to claim 13, wherein said H-factor in step (b) is 500 to 600.