Surface coating with enhanced color contrast for video display

• US 5,523,114 A
• Filed: 03/28/1995
• Issued: 06/04/1996
• Est. Priority Date: 03/28/1995
• Status: Expired due to Term

• Current Assignee: Chunghwa Picture Tubes Limited
• Original Assignee: Chunghwa Picture Tubes Limited
• Inventors: Tong, Hua-Sou, Hu, Chun-Min, Yu, Yu-Chung, Hsu, Ming-Yu, Wang, Kuo-Chu
• Primary Examiner(s): BELL, JANYCE A
• Application Number:
  US08/412,265
• Time in Patent Office: 434 Days
• Field of Search: 427/68, 427/384, 427/64, 427/379, 427/164, 427/165
• US Class Current: 427/68
• CPC Class Codes: H01J 2229/8913 Anti-reflection, anti-glare, viewing angle and contrast improving treatments or devices
• CPC Class Codes: H01J 29/18 Luminescent screens
• CPC Class Codes: H01J 29/898 Spectral filters
• CPC Class Codes: H01J 9/20 Manufacture of screens on or from which an image or pattern is formed, picked up, converted or stored; Applying coatings to the vessel

Abstract

For use in a self-emitting color display device such as a cathode ray tube (CRT) having a display screen with a phosphor coating on its inner surface, a surface coating disposed on the display screen'"'"'s outer surface affords improved color purity, or contrast, by reducing overlap in the color spectrum between two adjacent primary colors, i.e., between red and green and/or between green and blue. An organic dye is added to either an inner antistatic layer or an outer antireflective layer of an antireflective/antistatic outer coating on the display screen, where both of the aforementioned layers contain silane. The dye functions as a color filter absorbing only light within the frequency range between adjacent primary colors, such as between the red and green color phosphors, i.e., in the range of 460-500 nm, and/or between the green and blue color phosphors, i.e., in the range of 560-600 nm. A silane coupling agent is also added to serve as a binding agent bridging the organic dye and silane together. In this manner, the organic dye is bonded to the silane in either the antistatic layer or the antireflective layer to prevent separation and escape of the organic dye filter from either of these layers of the outer coating on the display screen.

Claims

1. For use on an outer surface of a glass faceplate of a self-emitting display device, wherein said glass faceplate further includes a phosphor coating on an inner surface thereof, and wherein said phosphor:

coating is responsive to energetic electrons incident thereon for providing three primary colors of red, green and blue, a coating comprising;

an antireflective/antistatic layer disposed on the outer surface of said faceplate and containing silane;

at least one organic color dye disposed in said antireflective/antistatic layer for absorbing light between two adjacent primary colors; and

a silane binding agent disposed in said antireflective/antistatic layer for coupling said at least one organic color dye to the silane in said layer, wherein said silane binding agent is Y-amino propyl triethoxy silane.

2. The coating of claim 1 wherein said at least one organic color dye is an azo, triarylmethane, or authraquinone dye with acid substituents.

3. The coating of claim 2 wherein said acid substituents include a nitro, carboxy or sulfonic acid.

4. The coating of claim 1 comprised of 0.1-25 wt % of said at least one organic color dye.

5. The coating of claim 1 comprised of 0.1-20 wt % of said silane binding agent.

6. The coating of claim 1 wherein said organic color dye is naphthol yellow S dye for absorbing light in the wavelength range of 480-500 nm or naphthol red dark dye for absorbing light in the wavelength range of 580-600 nm.

7. The coating of claim 1 further including first and second organic color dyes disposed in said antireflective/antistatic coating for absorbing light between the primary colors of red and green and between the primary colors of green and blue.

8. The coating of claim 1 wherein said antireflective/antistatic coating includes an inner antistatic layer and an outer antireflective layer each containing silane, and wherein said organic color dye and said silane binding agent are disposed in either said inner antistatic layer or said outer antireflective layer.

9. The coating of claim 8 further comprising first and second organic color dyes for absorbing light between the red and green primary colors and between the green and blue primary colors.

10. A method for preparing and applying a coating with enhanced color contrast to an outer surface of a video display panel whereon are presented the primary colors of red, green and blue, said method comprising the steps of:

adding a combination of anorganic color dye and a silane binding agent to a coating solution containing silane in forming a bond between said organic color dye and said silane and preventing removal of said organic color dye from said coating solution, wherein said organic color dye absorbs light between and enhances spectral separation between two adjacent primary colors and wherein said silane binding agent is Y-amino propyl triethoxy silane;

preheating the video display panel to a first temperature;

applying said coating solution containing said organic color dye and silane binding agent combination to an outer surface of the video display panel;

heating the video display panel with said coating solution to a second temperature for a time period, wherein said second temperature is greater than said first temperature; and

air cooling the video display panel to room temperature.

11. The method of claim 10 wherein said organic color dye is an azo, triarylmethane, or authraquinone dye with acid substituents.

12. The method of claim 11 wherein said acid substituents include a nitro, carboxy or sulfonic acid.

13. The method of claim 12 wherein said organic color dye is naphthol yellow S dye for absorbing light in the wavelength range of 480-500 nm or naphthol red dark dye for absorbing light in the wavelength range of 580-600 nm.

14. The method of claim 11 wherein said first temperature is in the range of 40°

-45°

C.

15. The method of claim 14 wherein said second temperature is in the range of 110°

-180°

C. and said predetermined time period is in the range of 20-40 minutes.

16. The method of claim 10 further comprising the steps of forming the coating by adding the combination of said organic color dye and silane binding agent to a first antistatic coating solution or a second antireflective coating solution, followed by preheating the video display panel, applying the first antistatic coating solution to the outer surface of the video display panel and applying the second antireflective coating solution to the first antistatic coating solution.