Probe having coaxial design for use with dissolved oxygen meter

• US 5,527,444 A
• Filed: 04/19/1994
• Issued: 06/18/1996
• Est. Priority Date: 04/19/1994
• Status: Expired due to Fees

• Current Assignee: John W. Sweeney Jr
• Original Assignee: John W. Sweeney Jr
• Inventors: Sweeney, John W. Jr.
• Primary Examiner(s): TUNG, TA HSUNG
• Application Number:
  US08/229,567
• Time in Patent Office: 791 Days
• Field of Search: 204/153.18, 204/415, 204/412
• US Class Current: 204/415
• CPC Class Codes: G01N 27/404 Cells with anode, cathode and cell electrolyte on the same side of a permeable membrane which separates them from the sample fluid , e.g. Clark-type oxygen sensors

Abstract

A probe is disclosed for use with a dissolved gas meter, which is capable of measuring the concentration of dissolved gas in a fluid by measuring the permeation of gas through a membrane into an electrolyte solution. The probe includes an inner member, preferably tubular, disposed inside an outer member, preferably tubular, each tubular member having an open top end. Preferably, the inner tubular member and the outer tubular member are coaxially located such that an annular space is formed between the inner and outer tubular member. The probe further includes a plurality of electrodes operably connected inside the probe to the meter. A counter electrode extends into the central chamber of the inner tubular member, along the central axis. A working electrode is wrapped around the outer tubular member. A reference electrode is wrapped around the inner tubular member. A membrane, preferably made of silicone elastomer material, covers at least a portion of the outer tubular member and encloses the working electrode so as to form a pocket around a portion of the working electrode. Electrolyte solution is injected into the top of the inner tubular member and flows from a central chamber in the inner tubular member to the outside of the outer tubular member and around the working electrode through a series of holes, which create passages for the flow of the solution. As such, the electrodes are in at least in partial fluid communication with the electrolyte solution.

Claims

1. A dissolved gas meter for measuring the concentration of dissolved gas in a fluid by measuring the permeation of gas through a membrane into an electrolyte solution, comprising:

a probe for insertion into a fluid, the probe having an inner tubular member positioned about a central axis, and an outer tubular member coaxially positioned about the central axis of the inner tubular member, at least a portion of the inner tubular member being coaxially located inside the outer tubular member such that an annular space is formed therebetween, the inner tubular member defining a central chamber therein, the inner and outer tubular members each having a plurality of holes, at least one hole providing fluid communication between the central chamber of the inner tubular member, the annular space between the inner and outer tubular members, and substantially around the outer tubular member, and electrolyte solution substantially filling the central chamber inside the inner tubular member and substantially filling the annular space between the inner and outer tubular members;

a plurality of electrodes inside the probe including;

a counter electrode extending substantially along the central axis of the inner tubular member and into the central chamber inside the inner tubular member;

a working electrode extending about the outer tubular member and through at least one of the holes in the outer tubular member;

a reference electrode extending about the inner tubular member and through at least a portion of the outer tubular member; and

the reference electrode, the working electrode, and the counter electrode being at least in partial fluid communication with the electrolyte solution; and

a permeable membrane covering at least a portion of the outer tubular member and at least a portion of the working electrode such that a dissolved gas permeates the membrane, enters into the probe and is detected by the electrodes.

2. The dissolved gas meter of claim 1, the inner tubular member further comprising at least one groove extending about the circumference of the inner tubular member, the groove being adapted in size and shape such that the reference electrode, when inserted into the groove, fits therein.

3. The dissolved gas meter of claim 1, wherein at least one of the holes in the outer tubular member is beveled so as to facilitate insertion of the working electrode into the hole.

4. The dissolved gas meter of claim 1, the inner tubular member comprising a hole at a top end thereof, the probe further comprising a plug for closing the top open end of the inner tubular member.

5. The dissolved gas meter of claim 1, further comprising a control, operably connected to the probe, having means for interpreting data sensed by the electrodes in the probe and means for displaying the interpreted data.

6. A meter for measuring the concentration of dissolved gas in a fluid by measuring the permeation of gas through a membrane into an electrolyte solution, comprising:

a probe for insertion into a fluid, the probe having an inner tubular member positioned about a central axis, and an outer tubular member coaxially positioned about the central axis of the inner tubular member, each having a top end and a bottom end, at least a portion of the inner tubular member being coaxially located inside the outer tubular member such that an annular space is formed therebetween, the inner tubular member defining a central chamber therein, the inner and outer tubular members each having a plurality of holes, at least one hole providing fluid communication between the central chamber of the inner tubular member, the annular space between the inner and outer tubular members, and substantially around the outer tubular member, the inner tubular member being closed at the top end, the electrolyte solution substantially filling the central chamber inside the inner tubular member and substantially filling the annular space between the inner and outer tubular members;

a plurality of electrodes inside the probe including;

a counter electrode extending substantially along the central axis of the inner tubular member and into the central chamber inside the inner tubular member;

a working electrode extending about the outer tubular member and extending through at least one of the holes in the outer tubular member;

a reference electrode extending about the inner tubular member and through at least a portion of the outer tubular member; and

the reference electrode, the working electrode, and the counter electrode being at least in partial fluid communication with the electrolyte solution;

a permeable membrane covering at least a portion of the outer tubular member and the working electrode, such that a dissolved gas permeates the membrane, enters into the probe and is detected by the electrodes; and

a plug, inside the inner tubular member and at substantially the bottom end of the inner tubular member, having a hole for receiving the reference electrode.

7. The meter of claim 6, the inner tubular member further comprising at least one groove extending about the circumference of the inner tubular member, the groove being adapted in size and shape such that the reference electrode, when inserted into the groove, fits therein.

8. The meter of claim 6, wherein at least one of the holes in the outer tubular member is beveled so as to facilitate insertion of the working electrode into the hole.

9. The meter of claim 6, further comprising a control, operably connected to the probe, having means for interpreting data sensed by the electrodes in the probe and means for displaying the interpreted data.

10. A dissolved gas meter for measuring the concentration of dissolved gas in a fluid by measuring the permeation of gas through a membrane into an electrolyte solution, comprising:

a probe for insertion into the fluid, the probe having an inner member positioned about a central axis and an outer member coaxially positioned about the central axis of the inner tubular member, at least a portion of the inner member being coaxially located inside the outer member such that a space is formed between the inner and outer members, the inner member defining a central chamber therein, the inner and outer members each having a plurality of holes, at least one hole providing fluid communication between the central chamber of the inner member, the space between the inner and outer members, and substantially around the outer member, the electrolyte solution substantially filling the central chamber inside the inner member and substantially filling the space between the inner and outer members;

a plurality of electrodes inside the probe including;

a counter electrode extending substantially along the central axis of the inner member and into the central chamber inside the inner member;

a working electrode extending about the outer member and through at least one of the holes in the outer member;

a reference electrode extending about the inner member and through at least a portion of the outer member; and

the reference electrode, the working electrode, and the counter electrode being at least in partial fluid communication with the electrolyte solution; and

a permeable membrane, covering at least a portion of the outer member and at least a portion of the working electrode so as to form a pocket for enclosing the working electrode and exposing a portion of the working electrode to electrolyte solution, wherein a dissolved gas permeates the membrane, enters into the probe and is detected by the electrodes.

11. The dissolved gas meter of claim 10, wherein the outer member is tubular.

12. The dissolved gas meter of claim 11, wherein the inner member is tubular.

13. The dissolved gas meter of claim 10, the inner member further comprising a top, and the probe further comprising a plug for closing the top of the inner member.

14. The dissolved gas meter of claim 13, the inner member being sealed at the top, and the probe further comprising a plug, opposite the sealed end of the inner member, the plug having means for receiving the reference electrode.

15. The dissolved gas meter of claim 10, wherein the membrane is in direct contact with the working electrode.

16. The dissolved gas meter of claim 10, wherein at least one of the holes in the outer member is beveled so as to facilitate insertion of the working electrode into the hole.

17. The dissolved gas meter of claim 10, the inner member further comprising at least one groove extending about the inner member, the groove being adapted in size and shape such that the reference electrode, when inserted into the groove, fits therein.