Catalyst for the catalytic afterburning of exhaust gases containing carbon monoxide and/or oxidizable organic compounds

• US 5,527,755 A
• Filed: 04/25/1994
• Issued: 06/18/1996
• Est. Priority Date: 04/09/1992
• Status: Expired due to Fees

• Current Assignee: Consortium Fur Elektrochemische Industrie GmbH
• Original Assignee: Consortium Fur Elektrochemische Industrie GmbH
• Inventors: Wenski, Guido, Hammer, Margit
• Primary Examiner(s): Beck, Shrive
• Assistant Examiner(s): PARKER, FREDERICK JOHN
• Application Number:
  US08/211,984
• Time in Patent Office: 785 Days
• Field of Search: 502/349, 502/350, 502/353, 502/325, 423/213.5
• US Class Current: 502/325
• CPC Class Codes: B01D 53/864 Removing carbon monoxide or hydrocarbons
• CPC Class Codes: B01J 23/6482 Vanadium

Abstract

The invention relates to catalysts for the catalytic post-combustion of exhaust gases containing carbon monoxide and/or oxidizable organic compounds and processes for their production. The catalysts contain 70 to 99% wt., calculated as TiO₂, of a titanium oxide component, 1 to 30% wt., calculated as V₂ O₅ of a vanadium oxide component and 0.01 to 0.9% wt., calculated as noble metal, of a noble metal component from one or more nobel metal compounds of nobel metals of the 8th sub-group. The catalysts are characterized by a low starting (≦220° CC.) and operating temperature and their ability to oxidize even slight pollution of the exhaust gas with oxygen-containing or free aliphatic and aromatic hydrocarbons and carbon monoxide in the presence of gases containing molecular oxygen almost quantitatively to the substantially ecologically acceptable products carbon dioxide and water.

Claims

1. A catalyst for the catalytic afterburning of exhaust gases from phthalic anhydride or maleic anhydride production containing carbon monoxide and/or oxidizable organic compounds in the presence of molecular oxygen containing a) 70-99% by weight, calculated as TiO₂, of a titanium dioxide component, b) 1 to 30% by weight, calculated as V₂ O₅, of a vanadium oxide component selected from the group consisting of vanadium oxides of the formula V_n O_2n+1 wherein n has a value of from 2 to 7 or a vanadium compound which converts into a vanadium oxide on heating in air, and c) 0.01 to 0.9% by weight, calculated as noble metal of a noble metal component consisting of one or more compounds of palladium, platinum, and rhodium and said catalyst having a BET-surface area of 10 to 100 m² /g at an operation temperature of 150°

-550°

C.

2. The catalyst as claimed in claim 1, wherein the noble metal component is at least one compound selected from the group consisting of a palladium compound and a platinum compound.

3. The catalyst as claimed in claim 1, wherein the titanium oxide component is doped with up to 5% by weight, based on TiO₂, of oxide compounds selected from the group consisting of yttrium, lanthanum, the lanthanide elements, zirconium, hafnium, niobium, tantalum, molybdenum and tungsten.

4. The catalyst as claimed in claim 3, wherein the doping compound is 0.1-5% by weight, based on TiO₂, of tungsten oxide or a compound which is converted into tungsten oxide on heating.

5. The catalyst as claimed in claim 1 in the form of homogeneous moldings or extrudates or in form of a non-porous or porous support body, of in the optionally in form of a honeycomb-like support body or support body provided with ducts, coated therewith.

6. A process for the preparation of a catalyst as claimed in claim 1 which comprises mixing or grinding, dry or in the presence of water or another solvent, TiO₂, V₂ O₅ or a compound which converts into V₂ O₅ on heating in air and a compound selected from the group consisting of palladium, platinum and rhodium and, after evaporation of any solvent, activating the product for a period of 0.5-16 hours at 200°

-500°

C. in an air current.

7. A process for the preparation of a catalyst as claimed in claim 1 which comprises a) wetting TiO₂ with V₂ O₅ or a compound which converts into V₂ O₅ on heating in air, by mixing or grinding or impregnating, b) heating the product from step a) for a period of 1-24 hours at 250°

-600°

C. in air c) mixing or grinding the product from step b) with a vanadium oxide or a compound which converts into a vanadium oxide on heating in air, and a compound selected from the group consisting of palladium, platinum and rhodium and d) activating the product from step c) for a period of 0.5-16 hours at 200°

-500°

C. in an air current.

8. A process for the purification of exhaust gases from phthalic anhydride or maleic anhydride production containing carbon monoxide and/or oxidizable organic compounds by catalytic afterburning in the presence of oxygen to form carbon dioxide and water at operating temperatures between 150°

and 550°

C. and kick-off temperatures between 150° and

230°

C. which comprises conducting the process in the presence of the catalyst as claimed in claim 1.