Ring-down cavity spectroscopy cell using continuous wave excitation for trace species detection

• US 5,528,040 A
• Filed: 11/07/1994
• Issued: 06/18/1996
• Est. Priority Date: 11/07/1994
• Status: Expired due to Term

• Current Assignee: The Trustees of Princeton University (Princeton University)
• Original Assignee: The Trustees of Princeton University (Princeton University)
• Inventors: Lehmann, Kevin K.
• Primary Examiner(s): Fields, Carolyn E.
• Assistant Examiner(s): Glick, Edward J.
• Application Number:
  US08/335,052
• Time in Patent Office: 589 Days
• Field of Search: 250/343, 356/439
• US Class Current: 250/343
• CPC Class Codes: G01J 3/42 Absorption spectrometry; Double beam spectrometry; Flicker spectrometry; Reflection spectrometry beam switching arrangements G01J3/08
• CPC Class Codes: G01N 2021/391 Intracavity sample
• CPC Class Codes: G01N 21/39 using tunable lasers

Abstract

An apparatus for detection and measurement of trace species in a sample gas. A ring down cavity cell is filled with the sample gas. A continuous wave laser emits radiation, which is directed from the continuous wave laser to the ring down cavity cell where it resonates. A photodetector measures radiation levels resonated by the ring down cavity cell and produces a corresponding signal. The decay rate of the ring down cavity cell is calculated from the signal produced by the photodetector and is used to determine the level of trace species in the sample gas.

Claims

1. An apparatus for detection and measurement of trace species in a sample gas comprising:

a ring down cavity cell filled with said sample gas and adapted to resonate radiation, said ring down cavity cell having an optical axis;

a continuous wave laser emitting radiation;

means for directing said radiation emitted from said continuous wave laser to said ring down cavity cell;

a first photodetector measuring radiation levels resonated by said ring down cavity cell and producing a corresponding signal;

means, responsive to said signal from said first photodetector, for calculating the decay rate of said ring down cavity cell; and

means, responsive to said decay rate, for determining the level of trace species in said sample gas.

2. The apparatus as recited in claim 1 wherein said continuous wave laser is a tunable diode laser having a narrow band.

3. The apparatus as recited in claim 1 wherein said continuous wave laser is a single mode laser tunable in the wavelength region of 5 nm around 1.39 microns.

4. The apparatus as recited in claim 1 further comprising a temperature controller adapted to tune the wavelength of said continuous wave laser on a predetermined spectral line of the trace species.

5. The apparatus as recited in claim 1 further comprising an isolator positioned between said continuous wave laser and said directing means and in line with the radiation emitted from said continuous wave laser, said isolator minimizing noise in said continuous wave laser.

6. The apparatus as recited in claim 1 wherein said directing means includes:

an optical fiber in which said radiation propagates from said continuous wave laser to said ring-down cavity cell; and

a single mode fiber coupler receiving radiation from said continuous wave laser and directing the radiation into said optical fiber.

7. The apparatus as recited in claim 1 wherein said ring down cavity cell includes a front highly reflective mirror and a rear highly reflective mirror, said mirrors aligned along said optical axis of said ring down cavity cell as a near confocal etalon.

8. The apparatus as recited in claim 7 wherein said highly reflective mirrors have radii of curvature of about 1 meter.

9. The apparatus as recited in claim 8 wherein said highly reflective mirrors are separated by a distance of about 1 meter.

10. The apparatus as recited in claim 1 further comprising a narrow tube coaxial with said optical axis of said ring down cavity cell through which said sample gas flows.

11. The apparatus as recited in claim 1 further comprising means for tuning said continuous wave laser to the peak of a predetermined spectral line of the trace species.

12. The apparatus as recited in claim 11 wherein said tuning means includes:

a beam splitter positioned between said continuous wave laser and said ring down cavity cell dividing the radiation into a first beam directed into said ring down cavity cell and a second beam;

a calibration cell receiving said second beam from said beam splitter;

a second photodetector receiving said second beam from said calibration cell and producing a corresponding signal;

computer and control electronics for tuning said continuous wave laser in response to said signal from said second photodetector.

13. The apparatus as recited in claim 1 wherein said first photodetector is InGaAs.

14. The apparatus as recited in claim 1 further comprising a resonant reference cavity adapted to optically lock said continuous wave laser by feedback.

15. The apparatus as recited in claim 1 wherein the trace species is water.

16. An apparatus for detection and measurement of trace species in a sample gas comprising:

a ring down cavity cell filled with said sample gas and adapted to resonate radiation, said ring down cavity cell having an optical axis, a front highly reflective mirror, and a rear highly reflective mirror, said mirrors aligned along said optical axis as an etalon;

a narrow tube coaxial with said optical axis of said ring down cavity cell through which said sample gas flows;

a single mode, tunable, continuous wave laser having a narrow band and emitting radiation;

a temperature controller adapted to tune the wavelength of said laser on a predetermined spectral line wavelength of said laser on a predetermined spectral line of the trace species;

means for tuning said laser to the peak of the predetermined spectral line of the trace species;

means for directing said radiation emitted from said laser to said ring down cavity cell;

a first photodetector measuring radiation levels resonated by said ring down cavity cell and producing a corresponding signal;

means, responsive to said signal from said first photodetector, for calculating the decay rate of said ring down cavity cell; and

means, responsive to said decay rate, for determining the level of trace species in said sample gas.

17. The apparatus as recited in claim 16 wherein said laser is tunable in the wavelength region of 5 nm around 1.39 microns.

18. The apparatus as recited in claim 16 further comprising an isolator positioned between said laser and said directing means and in line with the radiation emitted from said laser, said isolator minimizing noise in said laser.

19. The apparatus as recited in claim 16 wherein said directing means includes:

an optical fiber in which said radiation propagates from said laser to said ring-down cavity cell; and

a single mode fiber coupler receiving radiation from said laser and directing the radiation into said optical fiber.

20. The apparatus as recited in claim 16 wherein said highly reflective mirrors have radii of curvature of about 1 meter.

21. The apparatus as recited in claim 20 wherein said highly reflective mirrors are separated by a distance of about 1 meter.

22. The apparatus as recited in claim 16 wherein said tuning means includes:

a beam splitter positioned between said laser and said ring down cavity cell dividing the radiation into a first beam directed into said ring down cavity cell and a second beam;

a calibration cell receiving said second beam from said beam splitter;

a second photodetector receiving said second beam from said calibration cell and producing a corresponding signal;

computer and control electronics for tuning said laser in response to said signal from said second photodetector.

23. The apparatus as recited in claim 22 wherein said first and said second photodetectors are InGaAs.

24. The apparatus as recited in claim 16 further comprising a resonant reference cavity adapted to optically lock said laser by feedback.

25. The apparatus as recited in claim 16 wherein the trace species is water.

26. The apparatus as recited in claim 16 wherein said continuous wave laser is a diode laser.