Silicone coated base material and air bag base material

• US 5,529,837 A
• Filed: 02/27/1995
• Issued: 06/25/1996
• Est. Priority Date: 02/28/1994
• Status: Expired due to Fees

• Current Assignee: Shin-Etsu Chemical Company Limited
• Original Assignee: Shin-Etsu Chemical Company Limited
• Inventors: Fujiki, Hironao, Tanaka, Miyuki
• Primary Examiner(s): DEAN JR, RALPH H
• Application Number:
  US08/394,486
• Time in Patent Office: 484 Days
• Field of Search: 428/266, 428/36.1, 428/36.8, 428/265, 428/267
• US Class Current: 442/136
• CPC Class Codes: B60R 21/235 characterised by their material
• CPC Class Codes: C08L 2666/44 Silicon-containing compounds
• CPC Class Codes: C08L 2666/54 Inorganic substances
• CPC Class Codes: C08L 83/00 Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
• CPC Class Codes: C09D 183/04 Polysiloxanes
• CPC Class Codes: D06M 11/36 with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
• CPC Class Codes: D06M 11/46 Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
• CPC Class Codes: D06M 11/49 Oxides or hydroxides of elements of Groups 8, 9,10 or 18 of the Periodic Table; Ferrates; Cobaltates; Nickelates; Ruthenates; Osmates; Rhodates; Iridates; Palladates; Platinates
• CPC Class Codes: D06M 11/74 with carbon or graphite; with carbides; with graphitic acids or their salts
• CPC Class Codes: D06M 15/643 containing silicon in the main chain
• CPC Class Codes: D06M 15/65 containing epoxy groups
• CPC Class Codes: D06N 3/128 with silicon polymers
• CPC Class Codes: Y10T 428/1362 Textile, fabric, cloth, or pile containing [e.g., web, net, woven, knitted, mesh, nonwoven, matted, etc.]
• CPC Class Codes: Y10T 428/1386 Natural or synthetic rubber or rubber-like compound containing
• CPC Class Codes: Y10T 442/2631 Coating or impregnation provides heat or fire protection
• CPC Class Codes: Y10T 442/2893 Coated or impregnated polyamide fiber fabric

Abstract

A material in the form of polyamide fibers, polyester fibers, woven and non--woven fabric thereof, thermoplastic elastomer, and polyurethane sheet is coated with a silicone coating composition to a thickness of 5 to 20 μm, obtaining a silicone coated base material. The silicone coating composition contains (A) an organopolysiloxane having at least two alkenyl groups, (B) an organohydrogenpolysiloxane having at least two hydrogen atoms, (C) an organic silicon compound having at least one hydrogen atom and at least one epoxy and/or trialkoxy-silyl group, (D) a carbon, NiO₂, FeO, FeO₂, Fe₂ O₃, Fe₃ O₄, CoO₂, CeO₂ or TiO₂ powder having a mean particle size of up to 20 μm, and (E) a platinum catalyst. The silicone coated base material is flame resistant and fully acceptable in practical use even though the silicone coating is as thin as 5 to 20 μm, namely less than about one-half of the conventional coating thickness.

Claims

1. A silicone coated base material comprising a base material selected from the group consisting of polyamide fibers, polyester fibers, woven and non-woven fabrics thereof, thermoplastic elastomers, and polyurethane sheets and a coating formed on at least a portion of said base material to a thickness of 5 to 20 μ

m, said coating being the cured product of a silicone coating composition comprising

(A) 100 parts by weight of an organo-polysiloxane having at least two alkenyl groups each directly bonded to a silicon atom in a molecule,

(B) an organohydrogenpolysiloxane having at least two hydrogen atoms each bonded to a silicon atom in a molecule, in a sufficient amount to give 0.5 to 4 silicon-bonded hydrogen atoms per alkenyl group in component (A),

(C) 0.1 to 10 parts by weight of an organic silicon compound having in a molecule at least one hydrogen atom bonded to a silicon atom and at least one epoxy and/or trialkoxysilyl group bonded to a silicon atom through a carbon atom directly bonded to the silicon atom,

(D) 0.1 to 100 parts by weight of at least one powder having a mean particle size of up to 20 μ

m selected from the group consisting of carbon, NiO₂, FeO, FeO₂, Fe₂ O₃, Fe₃ O₄, CoO₂, CeO₂, and TiO₂, and

(E) a catalytic amount of a platinum catalyst.

2. The silicone coated base material of claim 1 wherein said silicone coating composition further contains

(F) up to 1 part by weight of benzotriazole and/or benzimidazole.

3. The silicone coated base material of claim 1 wherein said silicone coating composition further contains

(G) up to 100 parts by weight of reinforcing silica.

4. An air bag base material wherein a coating of the silicone coating composition of claim 1, is formed on a fibrous base material selected from the group consisting of polyamide fibers, polyester fibers, and woven and non-woven fabrics thereof.

5. The silicone coated base material of claim 1, which is in the form of an air bag for use in an automobile.

6. The silicone coated base material of claim 5, wherein the entire inner surface of the air bag is coated with the coating.

7. The silicone coated base material of claim 1, wherein the organopolysiloxane, (A), is of the following average compositional formula:

space="preserve" listing-type="equation">R.sup.1.sub.n R.sup.2.sub.m SiO.sub.(4-n-m)/2

wherein R¹ is a halo- or cyano-substituted or unsubstituted monovalent hydrocarbon group of 1 to 10 carbon atoms not containing aliphatically unsaturated bonds, R² is an alkenyl group of 2 to 8 carbon atoms and letters n and m are positive numbers satisfying the relationships;

0.7<

n<

2.2, 0<

m 0.1 and 0.8<

m+n≦

2.2.

8. The silicone coated base material of claim 1, wherein the organopolysiloxane, (A), is a straight chain diorganopolysiloxane end-blocked with triorganosilyl groups.

9. The silicone coated base material of claim 1, wherein the organopolysiloxane, (A), is a straight chain diorganopolysiloxane with alkenyl groups bonded to the silicon atoms at both ends of the molecule.

10. The silicone coated base material of claim 1, wherein the organohydrogenpolysiloxane, (B), is of the following average compositional formula:

space="preserve" listing-type="equation">R.sup.3.sub.a H.sub.b SiO.sub.(4-a-b)/2

wherein R³ is a halo- or cyano-substituted or unsubstituted monovalent hydrocarbon group of 1 to 10 carbon atoms not containing aliphatically unsaturated bonds and letters a and b are positive numbers satisfying the relationships;

0.5<

a<

2.2, 0.002≦

b≦

1 and 0.8<

a+b≦

3.

11. The silicone coated base material of claim 1, wherein the epoxy or trialkoxysilyl group in component (C) is of one of the following formulae:

##STR6##

12. The silicone coated base material of claim 1, wherein the organic silicon compound, (C), has a linear or cyclic polysiloxane skeleton.

13. The silicone coated base material of claim 12, wherein the organic silicon compound, (C), has a linear polysiloxane skeleton of about 5 to 50 silicon atoms.

14. The silicone coated base material of claim 12, wherein the organic silicon compound, (C), has a cyclic polysiloxane skeleton with siloxane rings of 3 to 6 silicon atoms.

15. The silicone coated base material of claim 1, wherein the organic silicon compound, (C), is of the one of the following formulae:

##STR7##

16. The silicone coated base material of claim 1, wherein the powder, (D), has a mean particle size of 0.02 to 10 μ

m.

17. The silicone coated base material of claim 1, wherein the silicone coating composition is solventless.

18. The silicone coated base material of claim 1, wherein the silicone coating composition is an aqueous emulsion system.

19. The silicone coated base material of claim 1, wherein the silicone coating composition further comprises benzimidazole for improving the high-temperature resistance.