Plasticized polyvinyl butyral sheet containing epoxy resin

• US 5,529,849 A
• Filed: 04/03/1995
• Issued: 06/25/1996
• Est. Priority Date: 07/01/1993
• Status: Expired due to Term

• Current Assignee: Solutia Incorporated (Eastman Chemical Company)
• Original Assignee: Monsanto Company (Bayer AG)
• Inventors: D'Errico, John J.
• Primary Examiner(s): SLUBY, PATRICIA
• Application Number:
  US08/415,806
• Time in Patent Office: 449 Days
• Field of Search: 428/415, 428/436, 428/437, 428/426, 428/432, 428/433, 428/469, 428/699, 428/701, 428/702, 428/913, 350/1.6, 350/1.7, 350/164
• US Class Current: 428/415
• CPC Class Codes: B32B 17/10005 laminated safety glass or glazing
• CPC Class Codes: B32B 17/10018 comprising only one glass sheet
• CPC Class Codes: B32B 17/10036 comprising two outer glass sheets
• CPC Class Codes: B32B 17/10174 Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
• CPC Class Codes: B32B 17/10688 Adjustment of the adherence to the glass layers
• CPC Class Codes: B32B 17/10706 being photo-polymerized
• CPC Class Codes: B32B 17/10733 containing epoxy
• CPC Class Codes: B32B 17/10761 containing vinyl acetal
• CPC Class Codes: B32B 2367/00 Polyesters, e.g. PET, i.e. polyethylene terephthalate
• CPC Class Codes: Y10S 428/913 Material designed to be responsive to temperature, light, moisture
• CPC Class Codes: Y10T 428/31511 Of epoxy ether
• CPC Class Codes: Y10T 428/31518 Next to glass or quartz
• CPC Class Codes: Y10T 428/31627 Next to aldehyde or ketone condensation product
• CPC Class Codes: Y10T 428/3163 Next to acetal of polymerized unsaturated alcohol [e.g., formal butyral, etc.]

Abstract

Plasticized polyvinyl butyral sheet containing epoxy resin in amount effective, after prolonged exposure to light, to counteract reduction of adhesion between the sheet and a photoreactive component with which it will be in potential contact. The photoreactive component is typically a dielectric such as a metal oxide layer of a heat-wave-reflective or electrically conductive multi-layer coating, which coating can optionally be supported on (a) a thermoplastic substrate sandwiched between two of such polyvinyl butyral sheets forming a prelaminate for use as a constituent of a laminated glazing panel or (b) a glass sheet component of such glazing panel.

Claims

1. A laminated glazing panel sequentially comprising:

(A) a glass sheet;

(B) a heat-wave-reflective or electrically conductive multi-layer coating which includes a photoreactive layer; and

(C) a sheet of plasticized polyvinyl butyral in interfacial contact with the photoreactive layer containing epoxy resin in amount effective to counteract reduction of adhesion between the sheet and the photoreactive layer after prolonged exposure of the glazing panel to light.

2. The panel of claim 1 wherein the epoxy resin is selected from the group consisting of (a) epoxy resins comprised of the monomeric diglycidyl ether of bisphenol-A;

(b) epoxy resins comprised of the monomeric diglycidyl ether of bisphenol-F;

(c) epoxy resins comprised of the hydrogenated diglycidyl ether of bisphenol-A;

(d) polyepoxidized phenol novolacs;

(e) diepoxides of polyglycols; and

(f) a mixture of any of the foregoing epoxy resins of (a) through (e).

3. The panel of claim 2 wherein the epoxy resin is a diepoxide of poly(oxypropylene) glycol.

4. The panel of claim 3 wherein the amount of epoxy resin is about 3 to about 10 parts per 100 parts of polyvinyl butyral.

5. The panel of claim 4 wherein the photoreactive layer is a dielectric material.

6. The panel of claim 5 wherein the dielectric material is ZnO, In₂ O₃ or TiO₂.

7. The panel of any of claims 1, 2, 3, 4, 5, or 6 wherein the sheet of plasticized polyvinyl butyral further contains one or more glass adhesion-control agents and including another glass sheet bonded to the sheet of plasticized polyvinyl butyral.

8. The panel of claim 7 wherein the epoxy resin is substantially inert to the level of adhesion of the plasticized polyvinyl butyral sheet to the glass sheet as regulated by the one or more glass adhesion-control agents in the polyvinyl butyral sheet.

9. A laminated glazing panel sequentially comprising:

(A) a glass sheet;

(B) a heat-wave-reflective or electrically conductive multi-layer coating which includes a dielectric top layer;

(C) a sheet of plasticized polyvinyl butyral in interfacial contact with the dielectric layer containing one or more glass adhesion-reducing agents and about 3 to about 10 parts per 100 parts of polyvinyl butyral of one or more epoxy resins capable of counteracting the reduction of adhesion of the sheet to the dielectric layer after prolonged exposure to light, said one or more epoxy resin being substantially inert to the level of adhesion of the polyvinyl butyral sheet to glass sheet (D); and

(D) a glass sheet.

10. The panel of claim 9 wherein the dielectric layer is a metal oxide.

11. The panel of claim 9 wherein the metal oxide is ZnO, In₂ O₃ or TiO₂.

12. The panel of any of claims 9, 10, 11 wherein the epoxy resin is selected from the group consisting of (a) epoxy resins comprised of the monomeric diglycidyl ether of bisphenol-A;

(b) epoxy resins comprised of the monomeric diglycidyl ether of bisphenol-F;

(c) epoxy resins comprised of the hydrogenated diglycidyl ether of bisphenol-A;

(d) polyepoxidized phenol novolacs;

(e) diepoxides of polyglycols; and

(f) a mixture of any of the foregoing epoxy resins of (a) through (e).