Process for preparing formed articles made of polyurethane foams and formed articles so obtained

• US 5,530,033 A
• Filed: 05/15/1995
• Issued: 06/25/1996
• Est. Priority Date: 09/26/1990
• Status: Expired due to Term

• Current Assignee: The Dow Chemical Company (Dow, Inc.)
• Original Assignee: ECP Enichem Polimeri S.r.l.
• Inventors: Cancellier, Vito, Cecchini, Corrado, Lunardon, Gianflavio, Ciriello, Luciano
• Primary Examiner(s): Seidleck, James J.
• Assistant Examiner(s): GORR, RACHEL F
• Application Number:
  US08/441,644
• Time in Patent Office: 407 Days
• Field of Search: 521/131, 521/155, 521/159, 521/163, 521/174
• US Class Current: 521/131
• CPC Class Codes: C08G 18/482 Mixtures of polyethers containing at least one polyether containing nitrogen
• CPC Class Codes: C08G 2110/0008 flexible
• CPC Class Codes: C08G 2110/0025 rigid
• CPC Class Codes: C08G 2110/005 < 50kg/m3
• CPC Class Codes: C08G 2120/00 Compositions for reaction injection moulding processes
• CPC Class Codes: C08J 2375/04 Polyurethanes
• CPC Class Codes: C08J 9/146 only fluorine as halogen atoms
• CPC Class Codes: C08J 9/148 perfluorinated

Abstract

A process for preparing formed articles made of polyurethane foams, which comprises reacting at least a polyisocyanate with at least a compound containing end activated hydrogens in the presence of an expanding medium, selected from at least a hydrofluoroalkane and/or perfluoroalkane, and of a product, containing at least a structural unit of the aminic type, chemically bound or present in free form in one of the two polyurethane reagents, said expanding medium being dissolved in said one of the two polyurethane reagents.

Claims

1. A process for preparing a polyurethane foam, comprising:

predissolving at least one part by weight of a hydrofluoroalkane and/or perfluoroalkane having one or two carbon atoms in 100 parts by weight of a polyether polyol and an amine having the formula (I);

##STR3## where;

X represents a hydrogen atom or one of the groups Z₁ --R₂ -- or Z₂ --R₁ ;

Z₁ and Z₂ independently represent a hydrogen atom or an OH, NH₂ or NHR₃ group, where R₃ represents an alkyl, a cycloalkyl, an aryl or an alkylaryl radical having 1 to 12 carbon atoms; and

R₁ and R₂ independently represent an alkylene, a cycloalkylene, an arylene or an alkylarylene radical having 1 to 20 carbon atoms or a polyoxyalkylene chain having an average molecular weight of from 60 to 8,000 in which the alkylene group of the polyoxyalkylene chain has 1 to 4 carbon atoms,

in a closed vessel by stirring sufficiently to provide a homogeneous mixture, said homogeneous mixture consisting essentially of (i) said hydrofluoroalkane and/or perfluoroalkane, (ii) said polyether polyol and (iii) said amine in an amount providing at least 0.03 mol of aminic groups per 100 grams of said polyether polyol, and

reacting said homogeneous mixture with a polyisocyanate.

3. The process of claim 1, said process consisting essentially of said predissolving and said reacting steps.

5. The process according to claim 1, wherein the polyisocyanate is selected from the group consisting of low molecular weight diisocyanates of the formula:

space="preserve" listing-type="equation">OCN--R--NCO (II)

where R represents an aliphatic, a cycloaliphatic, an aromatic, or an alkyl-substituted aromatic radical having 1 to 30 carbon atoms.

6. The process according to claim 1, wherein the polyisocyanate consists essentially of a mixture of polymethylene-polyphenyl polyisocyanates having the formula (III):

##STR5## wherein n represents an integer higher than or equal to 1.

7. The process according to claim 1, wherein the polyether polyol contains an aliphatic, a cycloaliphatic, or an aromatic C₂ -C₂₀ chain.

8. The process according to claim 1, wherein the hydrofluoroalkane and/or perfluoroalkane is 1,1,1,2-tetrafluoroethane.

9. The process according to claim 1, wherein said predissolving step further comprises predissolving water in said polyether polyol.

10. The process according to claim 1, wherein said hydrofluoroalkane and/or perfluoroalkane has a feed pressure, said closed vessel has a starting pressure close to said feed pressure, and after said predissolving step, said homogeneous mixture has a vapor pressure lower than 4 bars.

11. The process of claim 1, wherein said hydrofluoroalkane and/or perfluoroalkane is liquid, and said process further comprises the step of feeding said liquid hydrofluoroalkane and/or perfluoroalkane into said closed vessel.

12. A process for preparing formed articles made of a polyurethane foam, comprising pouring a polyurethane foam prepared by the process of claim 1 into a mould.

13. A process for preparing formed articles made of a polyurethane form, comprising preparing a polyurethane foam by the process of claim 1, wherein said reacting step is conducted in a mould.

14. The process of claim 6, wherein said mixture of polymethylene-polyphenyl polyisocyanates are obtained by phosgenating an aniline-formaldehyde condensate.

15. The process of claim 1, wherein said polyisocyanate is an isocyanic prepolymer prepared by reacting polyisocyanates of the formulas (II) and (III):

##STR6## where R represents an aliphatic, a cycloaliphatic, an aromatic, or an alkyl-substituted aromatic radical having 1 to 30 carbon atoms and where n represents an integer higher than or equal to 1;

with an equivalent amount of said polyether polyol and/or said amine of the formula (I), said polyether polyol having a hydroxyl functionality of at least two and a mean molecular weight ranging from 60 to 8,000.

2. A process for preparing a polyurethane foam, comprising:

predissolving at least one part by weight of a hydrofluoroalkane and/or perfluoroalkane having one or two carbon atoms in 100 parts by weight of a polyisocyanate and an amine having the formula (I);

##STR4## where;

X represents a hydrogen atom or one of the groups Z₁ --R₂ -- or Z₂ --R₁ ;

Z₁ and Z₂ independently represent a hydrogen atom or an OH, NH₂ or NHR₃ group, where R₃ represents an alkyl, a cycloalkyl, an aryl or an alkylaryl radical having 1 to 12 carbon atoms; and

R₁ and R₂ independently represent an alkylene, a cycloalkylene, an arylene or an alkylarylene radical having 1 to 20 carbon atoms or a polyoxyalkylene chain having an average molecular weight of from 60 to 8,000 in which the alkylene group of the polyoxyalkylene chain has 1 to 4 carbon atoms,

in a closed vessel by stirring sufficiently to provide a homogeneous mixture, said homogeneous mixture consisting essentially of (i) said hydrofluoroalkane and/or perfluoroalkane, (ii) said polyisocyanate and (iii) said amine in an amount providing at least 0.03 mol of aminic groups per 100 grams of said polyisocyanate, and

reacting said homogeneous mixture with a polyether polyol.

4. The process of claim 2, said process consisting essentially of said predissolving and said reacting steps.