Biodegradable fabric softener compositions with improved perfume longevity

• US 5,531,910 A
• Filed: 07/07/1995
• Issued: 07/02/1996
• Est. Priority Date: 07/07/1995
• Status: Expired due to Fees

• Current Assignee: The Procter & Gamble Company
• Original Assignee: The Procter & Gamble Company
• Inventors: Chung, Alex H., Costa, Jill B., Denutte, Hugo R. G., Severns, John C., Sivik, Mark R., Hartman, Frederick A.
• Primary Examiner(s): Lieberman, Paul
• Assistant Examiner(s): TIERNEY, MICHAEL
• Application Number:
  US08/499,282
• Time in Patent Office: 361 Days
• Field of Search: 252/8.8, 252/8.9, 252/8.6, 252/174.11, 512/18, 512/26, 560/190, 560/205, 560/221, 560/76, 560/95
• US Class Current: 510/102
• CPC Class Codes: C11D 1/62 Quaternary ammonium compounds
• CPC Class Codes: C11D 3/0015 liquid
• CPC Class Codes: C11D 3/507 Compounds releasing perfumes by thermal or chemical activation

Abstract

The present invention relates to liquid and solid biodegradable fabric softener compositions combined with nonionic or anionic esters of a non-allylic alcohol perfumes. These compositions exhibit improved perfume longevity and reduced enviromental impact.

Claims

1. A rinse-added rinse cycle fabric softening composition selected from the group consisting of:

I. a solid particulate composition comprising;

(A) from about 50% to about 95% of biodegradable cationic quaternary ammonium fabric softening compound;

(B) from 0.01% to about 15% by weight of the composition, of a diester having the formula R₁ R'"'"'R₂ wherein R'"'"' is a residue of an acid forming diester selected from the group consisting of succinic acid or maleic acid; and

wherein R₁ and R₂ independently represent a residue of an alcohol forming diester selected from the group consisting of phenoxanol, floralol, B-citronellol, nonadyl, cyclohexyl ethanol, phenyl ethanol, isoborneol, fenchol, isocyclogeraniol, 2-phenyl-1-propanol, 3,7-dimethyl-1-octanol and mixtures thereof;

(C) optionally, from about 0 to about 30% of dipsersibility modifier; and

(D) optionally, from about 0% to about 15% of pH modifier; and

II. a liquid composition comprising;

(A) from about 0.5% to about 80% of biodegrable cationic quaternary ammonium fabric softening compound;

(B) from 0.01% to about 15% by weight of the composition, of a diester having the formula R₁ R'"'"'R₂ wherein R'"'"' is a residue of an acid forming diester selected from the group consisting of succinic acid or maleic acid; and

wherein R₁ and R₂ independently represent a residue of an alcohol forming diester selected from the group consisting of phenoxanol, floralol, B-citronellol, nonadyl, cyclohexyl ethanol, phenyl ethanol, isoborneol, fenchol, isocyclogeraniol, 2-phenyl-1-propanol, 3,7-dimethyl-1-octanol and mixtures thereof;

(C) optionally, from about 0 to about 30% of dipsersibility modifier; and

(D) the balance comprising liquid carrier selected from the group consisting of water, C_1-4 monohydric alcohol, C_2-6 polyhydric alcohol, propylene carbonate, liquid polyethylene glycols and mixtures thereof.

2. The composition of claim 1 wherein component (A) has the formula:

space="preserve" listing-type="equation">(R).sub.4-m --.sup.+ N--((CH.sub.2).sub.n --Y--R.sup.2).sub.m X.sup.-

wherein;

each Y is --O--(O)C--, or --C(O)--O--;

m is 2 or 3;

n is 1 to 4;

each R is a C₁ -C₆ alkyl group, hydroxyalkyl group, benzyl group, or mixtures thereof;

each R² is a C₁₂ -C₂₂ hydrocarbyl or substituted hydrocarbyl substituent; and

X^- is any softener-compatible anion.

3. The composition of claim 2 wherein component (A) is derived from C₁₂ -C₂₂ fatty acyl groups having an Iodine Value of from greater than about 5 to less than about 100, a cis/trans isomer weight ratio of greater than about 30/70 when the Iodine Value is less than about 25, the level of unsaturation of the fatty acyl groups being less than about 65% by weight.

4. The composition of claim 3 wherein said ester component (B) is selected from a group consisting of di(β

-citronellyl) maleate, dinonadyl maleate, diphenoxanyl maleate, di(3,7-dimethyl-1-octanyl) succinate, di(cyclohexylethyl) maleate, difloralyl succinate, and di(phenylethyl) adipate.

5. The composition of claim 4 wherein the level of said component (B) is from about 0.1% to about 6%.

6. The composition of claim 5 wherein the level of said component (B) is from about 0.15% to about 4%.

7. The composition of claim 1 wherein said dispersibility modifier is selected from the group consisting of:

single-long-chain--C₁₀ -C₂₂ alkyl, cationic surfactant;

nonionic surfactant with at least 8 ethoxy moieties;

amine oxide surfactant; and

mixtures thereof.

8. The composition according to claim 7 wherein the dispersibility modifier is a single-long-chain-alkyl cationic surfactant at an effective level of up to about 15% of the composition.

9. The composition according to claim 8 wherein the dispersibility modifier is a quaternary ammonium salt of the general formula:

space="preserve" listing-type="equation">(R.sup.2 N.sup.+ R.sub.3)X.sup.-

wherein the R² group is a C₁₀ -C₂₂ hydrocarbon group, or the corresponding ester linkage interrupted group with a short alkylene (C₁ -C₄) group between the ester linkage and the N, and having a similar hydrocarbon group, each R is a C₁ -C₄ alkyl or substituted alkyl, or hydrogen; and

the counterion X^- is a softener compatible anion.

10. The composition according to claim 9 wherein the dispersibility modifier is C₁₂ -C₁₄ choline ester.

11. The composition according to claim 7 wherein the dispersibility modifier is nonionic surfactant at an effective level of up to about 20% of the composition.

12. The composition according to claim 11 wherein the dispersibility modifier is C₁₀ -C₁₄ alcohol with poly(10-18)ethoxylate.

13. The composition according to claim 7 wherein the dispersibility modifier is amine oxide with one alkyl, or hydroxyalkyl, moiety of about 8 to about 22 carbon atoms and two alkyl moieties selected from the group consisting of alkyl groups and hydroxyalkyl groups containing from one to about three carbon atoms.

14. The composition of claim 1 wherein the composition is a solid particulate composition comprising:

(A) from about 60% to about 90% of biodegradable cationic quaternary ammonium fabric softening compound;

(B) from about 0.05% to about 8% by weight of the composition, of ester of non-allylic alcohol perfume selected from the group consisting of di(β

-citronellyl) maleate, dinonadyl maleate, diphenoxanyl maleate, di(3,7-dimethyl-1-octanyl) succinate, di(cyclohexylethyl) maleate, difloralyl succinate, and combinations thereof and

(C) from 3% to about 15% of dispersibility modifier; and

(D) optionally, from 0% to about 10% of pH modifier.

15. The composition of claim 1 wherein the composition is a liquid composition comprising:

(A) from about 1% to about 35% of biodegradable quaternary ammonium fabric softening compound;

(B) from about 0.05% to about 6% by weight of the composition, of ester of non-allylic alcohol perfume selected from the group consisting of di(β

-citronellyl) maleate, dinonadyl maleate, diphenoxanyl maleate, di(3,7-dimethyl-1-octanyl) succinate, di(cyclohexylethyl) maleate, difloralyl succinate, and combinations thereof and

(C) from about 0.5% to about 10% of dispersibility modifier wherein the dispersibility modifier affects the composition'"'"'s viscosity, dispersibility in a laundry process rinse cycle, or both; and

(D) the balance comprising liquid carrier selected from the group consisting of water;

C₁ -C₄ monohydric alcohols;

C₂ -C₆ polyhydric alcohols;

propylene carbonate;

liquid polyalkylene glycols; and

mixtures thereof.

16. A process of treating textiles in a rinse cycle of a washing machine comprising:

contacting textiles in a washing machine with a fabric softening effective amount of a biodegradable cationic quaternary ammonium fabric softening compound and from 0.01% to about 15% by weight of the composition a diester having the formula R₁ R'"'"'R₂ wherein R'"'"' is a residue of a dicarboxylic acid forming diester selected from the group consisting of succinic acid or maleic acid; and

wherein R₁ and R₂ independently represent a residue of an alcohol forming diester selected from the group consisting of phenoxanol, floralol, B-citronellol, nonadyl, cyclohexyl ethanol, phenyl ethanol, isoborneol, fenchol, isocyclogeraniol, 2-phenyl-1-propanol, 3,7-dimethyl-1-octanol and mixtures thereof.