Anode assembly with thin metal current collector and electrochemical cell comprising an anode support structure and a gas release system

• US 5,532,086 A
• Filed: 06/30/1994
• Issued: 07/02/1996
• Est. Priority Date: 06/30/1994
• Status: Expired due to Term

• Current Assignee: Gillette Company (The Procter & Gamble Company)
• Original Assignee: AER Energy Resources, Inc.
• Inventors: Buzzrelli, Edward S., Thibault, William C.
• Primary Examiner(s): KALAFUT, STEPHEN J
• Application Number:
  US08/269,658
• Time in Patent Office: 733 Days
• Field of Search: 429/27, 429/66, 429/82, 429/234, 429/245, 429/246, 204/290 R, 428/626, 428/658, 428/673
• US Class Current: 429/245
• CPC Class Codes: H01M 10/0413 Large-sized flat cells or batteries for motive or stationary systems with plate-like electrodes
• CPC Class Codes: H01M 10/0468 Compression means for stacks of electrodes and separators
• CPC Class Codes: H01M 12/08 composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
• CPC Class Codes: H01M 4/02 Electrodes composed of, or comprising, active material
• CPC Class Codes: H01M 4/64 Carriers or collectors
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product
• CPC Class Codes: Y10T 428/12569 Synthetic resin
• CPC Class Codes: Y10T 428/12792 Zn-base component
• CPC Class Codes: Y10T 428/12896 Ag-base component

Abstract

An anode for use in an electrochemical cell comprising a current collector layer having a thickness less than about 10 mils, and desirably less than about 4 mils, and a rigid support extending adjacent one side of the current collector layer so that the current collector layer is sandwiched between the anodic layer of the anode and the rigid support. The rigid support maintains the current collector layer in the original configuration of the current collector layer during discharge and recharge cycles of the cell. A cell containing the anode is also disclosed. The rigid support for the anode current collector can be mounted in the electrochemical cell case so as to allow for the release from the cell of gas produced at the anode.

Claims

1. An anode for use in an electrochemical cell comprising:

an anodic layer of a metal which is capable of being oxidized in the cell to produce electricity during discharge of the cell, the anodic layer being a substantially solid sheet;

a current collector layer of a metal capable of conducting electricity produced during discharge of the cell but not being oxidized during discharge of the cell, the current collector layer being a substantially solid sheet, having a thickness less than about 10 mils and extending adjacent one side of the anodic layer; and

a rigid support comprising a substantially solid sheet of a material that is not capable of being oxidized during discharge of the cell, the sheet of the rigid support extending adjacent one side of the current collector layer so that the current collector layer is sandwiched between the anodic layer and the rigid support.

2. An anode as in claim 1 wherein the current collector has a thickness less than about 4 mils.

3. An anode as in claim 1 wherein the current collector layer has an original configuration, the rigid support maintaining the current collector layer in a configuration substantially the same as the original configuration during discharging and recharging of the cell.

4. An anode as in claim 1 wherein the rigid support comprises a mechanical spring so that when the anode is mounted in a cell case, the rigid support can be forcibly biased against the one side of the current collector layer, which, in turn, is biased against the anodic layer.

5. An anode as in claim 4 wherein the mechanical spring comprises a bowed plate.

6. An anode as in claim 4 wherein the mechanical spring comprises a leaf spring.

7. An anode as in claim 4 wherein the rigid support comprises a panel and the mechanical spring comprises a plurality of leaf springs extending from the panel to respective distal ends.

9. An anode as in claim 1 wherein the material of the rigid support comprises a layer of porous polypropylene.

13. An anode as in claim 1 wherein the metal of the current collector comprises silver.

16. An anode as in claim 1 wherein the metal of the current collector layer is plated onto the rigid support.

17. An anode as in claim 1 wherein the metal of the current collector layer is plated onto the one side of the anodic layer.

18. An anode as in claim 1 wherein the current collector layer extends across and covers substantially the entire one side of the anodic layer.

23. An anode as in claim 1 wherein the metal of the anodic layer comprises zinc.

24. An anode as in claim 1 wherein the metal of the anodic layer comprises zinc and the metal of the current collector layer comprises silver.

8. An anode for use in an electrochemical cell comprising:

an anodic layer of a metal which is capable of being oxidized in the cell to produce electricity during discharge of the cell;

a current collector layer of a metal capable of conducting electricity produced during discharge of the cell but not being oxidized during discharge of the cell, the current collector layer having a thickness less than about 10 mils and extending adjacent one side of the anodic layer; and

a rigid support comprising a material that is not capable of being oxidized during discharge of the cell, the rigid support extending adjacent one side of the current collector layer so that the current collector layer is sandwiched between the anodic layer and the rigid support,

wherein the rigid support comprises a mechanical spring so that when the anode is mounted in a cell case, the rigid support can be forcibly biased against the one side of the current collector layer, the rigid support comprises a panel, the mechanical spring comprises a plurality of leaf springs extending from the panel to respective distal ends, and the panel of the rigid support has a periphery and the leaf springs extend outwardly from the periphery.

10. An anode for use in an electrochemical cell comprising:

an anodic layer of a metal which is capable of being oxidized in the cell to produce electricity during discharge of the cell;

a current collector layer of a metal capable of conducting electricity produced during discharge of the cell but not being oxidized during discharge of the cell, the current collector layer having a thickness less than about 10 mils and extending adjacent one side of the anodic layer; and

a rigid support comprising a material that is not capable of being oxidized during discharge of the cell, the rigid support extending adjacent one side of the current collector layer so that the current collector layer is sandwiched between the anodic layer and the rigid support, wherein the rigid support forms a flow path for releasing gas produced at the anode.

11. An anode as in claim 10 wherein the rigid support has channels which form the flow path.

12. An anode as in claim 10 wherein the rigid support has openings which form the flow path.

14. An anode for use in an electrochemical cell comprising:

an anodic layer of a metal which is capable of being oxidized in the cell to produce electricity during discharge of the cell;

a current collector layer of a metal capable of conducting electricity produced during discharge of the cell but not being oxidized during discharge of the cell, the current collector layer having a thickness less than about 4 mils and extending adjacent one side of the anodic layer; and

a rigid support comprising a material that is not capable of being oxidized during discharge of the cell, the rigid support extending adjacent one side of the current collector layer so that the current collector layer is sandwiched between the anodic layer and the rigid support, wherein the metal of the current collector layer comprises metal foil.

15. An anode as in claim 14 wherein the metal of the current collector layer comprises silver foil.

19. An anode for use in an electrochemical cell comprising:

an anodic layer of a metal which is capable of being oxidized in the cell to produce electricity during discharge of the cell;

a current collector layer of a metal capable of conducting electricity produced during discharge of the cell but not being oxidized during discharge of the cell, the current collector layer having a thickness less than about 10 mils and extending adjacent one side of the anodic layer; and

a rigid support comprising a material that is not capable of being oxidized during discharge of the cell, the rigid support extending adjacent one side of the current collector layer so that the current collector layer is sandwiched between the anodic layer and the rigid support, wherein the current collector layer forms a flow path for releasing gas produced at the anode.

20. An anode as in claim 19 wherein the current collector layer has openings which form the flow path.

21. An anode for use in an electrochemical cell comprising:

an anodic layer of a metal which is capable of being oxidized in the cell to produce electricity during discharge of the cell;

a current collector layer of a metal capable of conducting electricity produced during discharge of the cell but not being oxidized during discharge of the cell, the current collector layer having a thickness less than about 10 mils and extending adjacent one side of the anodic layer; and

a rigid support comprising a material that is not capable of being oxidized during discharge of the cell, the rigid support extending adjacent one side of the current collector layer so that the current collector layer is sandwiched between the anodic layer and the rigid support, wherein the current collector layer and the rigid support form a flow path for releasing gas produced at the anode.

22. An anode as in claim 21 wherein the current collector layer has openings and the rigid support has channels or openings which form the flow path.

25. An anode for use in an electrochemical cell comprising:

an anodic layer of a metal which is capable of being oxidized in the cell to produce electricity during discharge of the cell;

a current collector layer of a metal capable of conducting electricity produced during discharge of the cell but not being oxidized during discharge of the cell, the current collector layer having a thickness less than about 10 mils and extending adjacent one side of the anodic layer;

a rigid support comprising a material that is not capable of being oxidized during discharge of the cell, the rigid support extending adjacent one side of the current collector layer so that the current collector layer is sandwiched between the anodic layer and the rigid support, and

an anode case, the anodic layer, current collector layer and rigid support disposed in the anode case, the anode case having an opening for releasing gas produced at the anode, and the rigid support mounted in the anode case and spaced apart from at least a portion of the anode case so that the gas can flow to and through the opening in the anode case.

26. An anode as in claim 25 wherein the anode case further comprises a panel and the opening for releasing gas produced at the anode, and the anode comprises a spacer extending between the anode case panel and the rigid support for spacing the rigid support apart from the anode case.

27. An anode as in claim 25 wherein the anode case further comprises a panel and a spacer extending integrally from the anode case, the panel comprising the opening for releasing gas produced at the anode, the rigid support being mounted on the spacer.

28. An anode as in claim 25 wherein the anode case further comprises a panel and the opening for releasing gas produced at the anode, and the rigid support comprises a spacer extending integrally from the rigid support to the anode case panel for spacing the rigid support apart from the anode case.

29. An anode as in claim 25 wherein the anode case comprises a main panel and side walls extending from the main panel, the rigid support being spaced from the main panel and the side walls of the anode case so that the gas can flow between the side walls and the rigid support and between the main panel and the rigid support.

30. An anode as in claim 25 wherein the rigid support has a periphery and the anode case further comprises a panel and a plurality of spacers extending from the anode case and spaced from one another, the panel comprising the opening for releasing gas produced at the anode, the rigid support being mounted on the plurality of spacers and the spacers being arranged about the periphery of the rigid support.

31. An anode as in claim 25 wherein the rigid support further comprises a mechanical spring so that when the anode is mounted in the anode case, the rigid support can be forcibly biased against the one side of the current collector layer.

32. An anode as in claim 31 wherein the mechanical spring comprises a bowed plate.

33. An anode as in claim 31 wherein the mechanical spring comprises a leaf spring.

34. An anode as in claim 31 wherein the rigid support comprises a panel and the mechanical spring comprises a plurality of leaf springs extending from the panel to respective distal ends.

35. An anode as in claim 34 wherein the panel of the rigid support has a periphery and the leaf springs extend outwardly from the periphery.

36. An anode as in claim 33 wherein the leaf spring spaces the rigid support from the anode case.

37. An anode for use in an electrochemical cell comprising:

an anodic layer of a metal which is capable of being oxidized in the cell to produce electricity during discharge of the cell;

a current collector layer of metal foil capable of conducting electricity produced during discharge of the cell but not being oxidized during discharge of the cell, the current collector layer extending adjacent one side of the anodic layer; and

a rigid support comprising a material that is not capable of being oxidized during discharge of the cell, the rigid support extending adjacent one side of the current collector layer so that the current collector layer is sandwiched between the anodic layer and the rigid support.

38. An anode as in claim 37 wherein the metal foil of the current collector is silver foil.

39. An electrochemical cell comprising:

a. a case;

b. a cathode disposed in the cell case;

c. an anode disposed in the cell case, the anode comprising;

an anodic layer of a metal which is capable of being oxidized in the cell to produce electricity during discharge of the cell; and

a current collector layer of metal capable of conducting electricity produced during discharge of the cell but not being oxidized during discharge of the cell, the current collector layer extending adjacent one side of the anodic layer;

d. electrolyte disposed in the cell case between the anode and the cathode; and

e. a rigid support comprising a material that is not capable of being oxidized during discharge of the cell, the rigid support extending adjacent one side of the current collector layer so that the current collector layer is sandwiched between the anodic layer and the rigid support, the anode being between the cathode and the rigid support;

the cell case having an opening for releasing gas produced at the anode, and the rigid support mounted in the case and spaced apart from at least a portion of the case so as to form a flow path for the gas to follow from the anode, to and through the opening in the case.

40. An electrochemical cell as in claim 39 wherein the current collector layer has a thickness less than about 10 mils.

41. An electrochemical cell as in claim 39 wherein the current collector layer has a thickness less than about 4 mils.

42. An electrochemical cell as in claim 41 wherein the current collector layer comprises a layer of metal foil.

43. An electrochemical cell as in claim 39 wherein the case further comprises a panel and the opening for releasing gas produced at the anode, and the cell comprises a spacer extending between the case panel and the rigid support for spacing the rigid support apart from the case.

44. An electrochemical cell as in claim 39 wherein the case further comprises a panel and a spacer extending integrally from the case, the panel comprising the opening for releasing gas produced at the anode, the rigid support being mounted on the spacer.

45. An electrochemical cell as in claim 39 wherein the case further comprises a panel and the opening for releasing gas produced at the anode, and the rigid support comprises a spacer extending integrally from the rigid support to the case panel for spacing the rigid support apart from the case.

46. An electrochemical cell as in claim 39 wherein the case comprises a main panel and side walls extending from the main panel, the rigid support being spaced from the main panel and the side walls of the case so that the gas can flow between the side walls of the case and the rigid support and between the main panel of the case and the rigid support.

47. An electrochemical cell as in claim 39 wherein the rigid support has a periphery and the case further comprises a panel and a plurality of spacers extending from the case and spaced from one another, the panel comprising the opening for releasing produced at the anode, the rigid support being mounted on the plurality of spacers and the spacers being arranged about the periphery of the rigid support.

48. An electrochemical cell as in claim 39 wherein the rigid support comprises a mechanical spring and is mounted in the case so as to be forcibly biased against the one side of the current collector layer.

49. An electrochemical cell as in claim 48 wherein the mechanical spring comprises a bowed plate.

50. An electrochemical cell as in claim 48 wherein the mechanical spring comprises a leaf spring.

51. An electrochemical cell as in claim 48 wherein the rigid support comprises a panel and the mechanical spring comprises a plurality of leaf springs extending from the panel of the rigid support to respective distal ends.

52. An electrochemical cell as in claim 51 wherein the panel of the rigid support has a periphery and the leaf springs extend outwardly from the periphery.

53. An electrochemical cell as in claim 50 wherein the leaf spring spaces the rigid support from the case.

54. An electrochemical cell comprising:

a. a case;

b. a cathode disposed in the cell case;

c. an anode disposed in the cell case, the anode comprising;

an anodic layer of a metal which is capable of being oxidized in the cell to produce electricity during discharge of the cell, the anodic layer being a substantially solid sheet; and

a current collector layer of metal capable of conducting electricity produced during discharge of the cell but not being oxidized during discharge of the cell, the current collector layer being a substantially solid sheet and extending adjacent one side of the anodic layer;

d. electrolyte disposed in the cell case between the anode and the cathode; and

e. a rigid support comprising a substantially solid sheet of a material that is not capable of being oxidized during discharge of the cell, the sheet of the rigid support extending adjacent one side of the current collector layer so that the current collector layer is sandwiched between the anodic layer and the rigid support, the anode being between the cathode and the rigid support;

the rigid support comprising a mechanical spring and being mounted in the case so as to be forcibly biased against the one side of the current collector layer, which, in turn, is forcibly biased against the anode.

55. An electrolytic cell as in claim 54 wherein the mechanical spring of the rigid support is a compressed bowed plate.

56. An electrolytic cell as in claim 54 wherein the mechanical spring of the rigid support is a leaf spring.

57. An electrochemical cell as in claim 56 wherein the rigid support comprises a panel and the mechanical spring comprises a plurality of leaf springs extending from the panel of the rigid support to respective distal ends.

58. An electrochemical cell as in claim 57 wherein the panel of the rigid support has a periphery and the leaf springs extend outwardly from the periphery to the panel of the case.

59. An electrochemical cell as in claim 56 wherein the leaf spring spaces the rigid support from the case.