Determination of dew point or absolute humidity

• US 5,533,393 A
• Filed: 01/13/1995
• Issued: 07/09/1996
• Est. Priority Date: 01/13/1995
• Status: Expired due to Term

• Current Assignee: Honeywell Incorporated (Honeywell International Inc.)
• Original Assignee: Honeywell Incorporated (Honeywell International Inc.)
• Inventors: Honda, Nobuaki, Bonne, Ulrich, Ohnstein, Thomas R., Kubisiak, David
• Primary Examiner(s): Williams, Hezron E.
• Assistant Examiner(s): WIGGINS, JOHN DAVID
• Application Number:
  US08/372,577
• Time in Patent Office: 543 Days
• Field of Search: 73/335.02, 73/336.50, 73/29.01, 73/29.02, 338/34, 338/35, 374/28, 324/663, 324/689, 324/694, 340/602, 340/580
• US Class Current: 73/335.02
• CPC Class Codes: G01N 25/66 by investigating dew-point
• CPC Class Codes: G01N 27/121 for determining moisture content, e.g. humidity, of the fluid moisture content of the tested material G01N27/048

Abstract

A microsensor system for determining water vapor content of the ambient atmosphere that uses a thin film suspended ceramic diaphragm structure featuring an embedded, patterned thin film heater, temperature sensor and an external film of an hygroscopic salt stabilized in a water-insoluble, crosslinked polymer matrix and contacting a pair of patterned electrodes which are proximate to the heater. The heater controls a selected electrical parameter of the salt to a fixed, predetermined value, as determined by its electrical characteristics. The dew point of the atmosphere is determined based on the dynamic relation with the salt dehydration temperature.

Claims

1. A sensor for determining the absolute amount of water vapor in the ambient atmosphere comprising:

(a) a thin film suspended ceramic structure of silicon nitride;

(b) a substantially planar patterned thin film heater carried within said suspended ceramic structure and having an open central region;

(c) a pair of substantially planar patterned interdigital electrodes forming an electrode area carried by said suspended ceramic structure, said electrodes further being proximate said heater but on the surface of the suspended structure and having a pattern dimension contained within the pattern of said heater;

(d) a film of an hygroscopic salt stabilized in a crosslinked polymer matrix host material substantially insoluble in an humidity-induced solution of said salt and connecting said pair of patterned electrodes; and

(e) a patterned temperature sensing means for sensing the temperature of said salt, said temperature sensing means replacing said open central region of said heater.

2. The device of claim 1 wherein the electrodes are Au/Ag alloy.

3. The device of claim 1 wherein the hygroscopic salt is LiCl and the crosslinked polymer matrix is polyvinyl alcohol (PVA) crosslinked using dicarboxylic malonic acid.

4. The device of claim 1 wherein said temperature sensing means itself comprises a heating device replacing the central portion of the pattern of said heater to also provide temperature uniformity to said electrode area.

5. The device of claim 4 wherein said temperature sensor is of an interdigital pattern.

6. The sensor of claim 1 wherein the suspended structure is less than 2×

2 mm in area.

8. The device of claim 2 including means for sensing the temperature of the supporting ceramic structure as indicative of the atmosphere proximate said suspended ceramic structure.

7. The method of measuring relative humidity using exposed LiCl stabilized in a matrix of PVA crosslinked with malonic acid, temperature stabilized to a known value of an electrical characteristic thereof in which the stabilization temperature is indicative of the dew point and the ambient temperature with the dew point is representative of the relative humidity.

9. A sensor for determining the absolute amount of water vapor in the ambient atmosphere comprising:

(a) a thin film suspended ceramic structure of silicon nitride;

(b) a substantially planar patterned thin film heater carried within said suspended ceramic structure;

(c) a pair of substantially planar patterned interdigital electrodes forming an electrode area carried by said suspended ceramic structure, said electrodes further being proximate said heater but on the surface of the suspended structure and having a pattern dimension contained within the pattern of said heater;

(d) a film of an hygroscopic salt stabilized in a crosslinked polymer matrix host material substantially insoluble in an humidity-induced solution of said salt and connecting said pair of patterned electrodes; and

(e) a patterned temperature sensing means for sensing the temperature of said salt superimposed over the central region of said heater.

10. The method of depositing a film of metal alloy on a substrate from a plurality of targets of pure metals sought to be alloyed using a sputtering method which involves sequentially addressing the plurality of targets comprising the steps of:

(a) passing the substrate sequentially proximate to each of the plurality of targets for a plurality of cycles;

(b) depositing metal at each passage of the substrate proximate to a target, during the plurality of cycles to form a composite metal layer; and

(c) optionally annealing the composite metal layer to achieve a uniform concentration of the plurality of metals in the composite metal layer.

11. The method of claim 10 wherein the pure metals are Au and Ag.

12. The method of claim 11 wherein step (c) comprises heating the layered substrate to approximately 450°

C. in a forming gas comprising nitrogen and hydrogen.

13. The method of claim 11 further comprising the step of patterning the alloy on the substrate.

14. The method of claim 11 wherein the metal alloy is approximately Au 75% and Ag 25%.

15. The method of measuring dew point using exposed LiCl, stabilized in a matrix of PVA crosslinked with malonic acid, temperature stabilized to a known value of an electrical characteristic thereof in which the stabilization temperature is indicative of the dew point.

16. A method of humidity stabilizing an hygroscopic salt exposed to the atmosphere under conditions of high humidity comprising the step of retaining said hygroscopic salt in an host material, said host material comprising a polymer matrix , said polymer matrix being substantially insoluble in an humidity induced water solution of the hygroscopic salt, said polymer matrix further comprising a hydrophilic polymer crosslinked using a cross-linking agent wherein said hydrophilic polymer comprises cross-linked polyvinyl alcohol (PVA) and the crosslinking agent comprises a malonic acid.

17. The method of claim 16 wherein the hygroscopic salt comprises LiCl.

18. The method of claim 17 wherein the ratio of PVA to LiCl is from about 2:

1 to about 1;

2.

19. The method of claim 18 wherein the ratio of PVA to malonic acid is from about 1:

(0.12) to about 1;

(0.36).

20. A stabilized hygroscopic alkali halide salt composite material having a retention property in a host medium that provides for use involving repeated exposure to high humidity as in a dew point or absolute water vapor sensor comprising an amount of alkali halide salt stabilized in a host material selected from polymer matrices of a poly alcohol crosslinked using a carboxylic agent wherein the host material is a polymer matrix in which the poly alcohol is polyvinyl alcohol (PVA) and the carboxylic acid is malonic acid.

21. The composite of claim 20 wherein the hygroscopic salt is LiCl.

22. The composite of claim 21 wherein the ratio of PVA to LiCl is from about 2:

1 to about 1;

2.

23. The composite of claim 22 wherein the ratio of PVA to malonic acid is from about 1:

(0.12) to 1;

(0.36).

24. A device for determining the dew point or absolute atmosphere water vapor content comprising:

(a) an hygroscopic salt exposed to exchange water vapor with the atmosphere but stabilized against washout in a retaining host material selected from the group consisting of porous alumina, magnesia, zirconia, silicon film and polymer matrices selected from those comprising crosslinked hydrophilic polymers substantially insoluble in a humidity induced solution of the hygroscopic salt;

(b) heating means proximate said hygroscopic salt for controlling the temperature of said salt to maintain a selected electrical parameter of said salt at a predetermined value independent variations in conditions of the atmosphere, wherein said parameter is selected from the group consisting of the electrical impedance components, resistance, and capacitance;

(c) means for measuring said selected electrical parameter of said salt;

(d) means for measuring the temperature of said salt and optionally of said atmosphere; and

(e) wherein the host material is a polymer matrix comprising polyvinyl alcohol crosslinked using malonic acid.

25. The device of claim 24 wherein the hygroscopic salt is LiCl.

26. A device for determining the dew point or absolute atmosphere water vapor content comprising:

(a) an hygroscopic salt exposed to exchange water vapor with the atmosphere but stabilized against washout in a retaining host material selected from the group consisting of porous alumina, magnesia, zirconia, silicon film and polymer matrices selected from those comprising crosslinked hydrophilic polymers substantially insoluble in a humidity induced solution of the hygroscopic salt;

(b) heating means proximate said hygroscopic salt for controlling the temperature of said salt to maintain a selected electrical parameter of said salt at a predetermined value independent variations in conditions of the atmosphere, wherein said parameter is selected from the group consisting of the electrical impedance components, resistance and capacitance;

(c) means for measuring said selected electrical parader of said salt;

(d) means for measuring the temperature of said salt and optionally of said atmosphere; and

(e) means for applying an AC signal at a plurality of frequencies to said sensor and means for measuring the selected electric parameter at two different frequencies to produce a ratio thereof.

27. The device of claim 26 wherein the electrical parameter is resistance.

28. The device of claim 26 wherein the electrical parameter is capacitance.

29. A device for determining the absolute amount or water vapor in the atmosphere comprising:

(a) a thin film suspended ceramic structure;

(b) an hygroscopic salt exposed to the atmosphere but retained in a polymeric matrix host material substantially insoluble in an humidity-induced solution of said salt carried on said suspended ceramic structure;

(c) thin film heating means carried on said suspended ceramic structure proximate said hygroscopic salt for controlling the temperature thereof to maintain a selected electrical parameter of said salt at a predetermined value independent of variations in conditions of the atmosphere, wherein said parameter is selected from the group of impedance components consisting of electric resistance and capacitance;

(d) means for measuring said selected electrical parameter of said salt;

(e) means for measuring the temperature of said salt and optionally of said atmosphere; and

(f) wherein the polymeric matrix is a malonic acid crosslinked polyvinyl alcohol and the hygroscopic salt is LiCl.

30. A device for determining the absolute amount or water vapor in the atmosphere comprising:

(a) a thin film suspended ceramic structure;

(b) an hygroscopic salt exposed to the atmosphere but retained in a polymeric matrix host material substantially insoluble in an humidity-induced solution of said salt carried on said suspended ceramic structure;

(c) thin film heating means carried on said suspended ceramic structure proximate said hygroscopic salt for controlling the temperature thereof to maintain a selected electrical parameter of said salt at a predetermined value independent of variations in conditions of the atmosphere, wherein said para mer is selected from the group of impedance components consisting of electric resistance and capacitance;

(d) means for measuring said selected electrical parameter of said salt;

(e) means for measuring the temperature of said salt and optionally of said atmosphere; and

(f) means for applying an AC signal at a plurality of frequencies to said sensor and means for measuring the selected electric parameter at two different frequencies to produce a ratio thereof.

31. The device of claim 30 wherein the impedance component selected is resistance.

32. The device of claim 30 wherein the impedance component selected is capacitance.

33. The device of claim 30 wherein the thin, film suspended ceramic structure is silicon nitride.

34. A method of humidity stabilizing an hygroscopic salt exposed to the atmosphere under conditions of high humidity comprising the step of retaining said hygroscopic salt as a separated incorporated salt in an host material selected from the group consisting of porous alumina, magnesia, zirconia, silicon films and hydrophilic polymer matrices which are substantially insoluble in an humidity induced water solution of the hygroscopic salt, said polymer matrices further being selected from a poly alcohol crosslinked by a carboxylic crosslinking agent;

thereby yielding a host material which resists washout of said hygroscopic salt.

35. The method of claim 34 wherein the hygroscopic salt comprises LiCl.

36. A stabilized hygroscopic alkali halide salt composite material having a retention property in a host medium that provides stabilization against washout of alkali halide salt and provides capability for use involving repeated exposure to high humidity as in a dew point or absolute water vapor sensor comprising an amount of alkali halide salt stabilized as a separately incorporated salt in a host material selected from the group consisting of porous alumina, magnesia, zirconia, silicon film and a polymer hydrophilic matrix of a poly alcohol crosslinked using an acid crosslinking carboxylic agent.

37. A device for determining the absolute amount of water vapor in the atmosphere surrounding said device comprising:

(a) a thin film suspended ceramic structure;

(b) an hygroscopic salt exposed to the atmosphere but retained in a hydrophilic polymeric matrix host material as a separately incorporate salt substantially insoluble in an humidity-induced solution of said salt carried on said suspended ceramic structure;

(c) thin film heating means carried on said suspended ceramic structure proximate said hygroscopic salt for controlling the temperature thereof to maintain a selected electrical parameter of said salt at a predetermined value independent of variations in conditions of the atmosphere, wherein said parameter is selected from the group of impedance components consisting of electric resistance and capacitance;

(d) means for measuring said selected electrical parameter of said salt; and

(e) means for measuring the temperature of said salt and optionally of said atmosphere.