Polymethylpentene/polypropylene blend and film

• US 5,534,593 A
• Filed: 05/23/1995
• Issued: 07/09/1996
• Est. Priority Date: 04/27/1993
• Status: Expired due to Term

• Current Assignee: Norton Performance Plastics Corp (Compagnie de Saint-Gobain SA)
• Original Assignee: Norton Performance Plastics Corp (Compagnie de Saint-Gobain SA)
• Inventors: Friedman, Michael
• Primary Examiner(s): ZEMEL, IRINA SOPJIA
• Application Number:
  US08/447,850
• Time in Patent Office: 413 Days
• Field of Search: 525/240, 525/242
• US Class Current: 525/240
• CPC Class Codes: C08J 2323/12 Polypropene
• CPC Class Codes: C08J 2323/20 having four to nine carbon atoms
• CPC Class Codes: C08J 5/18 Manufacture of films or sheets
• CPC Class Codes: C08L 23/10 Homopolymers or copolymers of propene
• CPC Class Codes: C08L 23/12 Polypropene
• CPC Class Codes: C08L 23/20 having four to nine carbon atoms
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 2666/06 Homopolymers or copolymers of unsaturated hydrocarbons; Derivatives thereof

Abstract

The present invention provides a composition comprising a blend of:

(A) from about 90% to about 10% by weight of polymethylpentene, wherein the polymethylpentene has a molecular weight between from about 200,000 to about 700,000, and a melt flow rate between from about 20 grams/10 minutes to about 200 grams/10 minutes;

(B) from about 10% to about 90% by weight of polypropylene, wherein the polypropylene has a molecular weight between from about 150,000 to about 350,000, and a melt flow rate between from about 1 gram/10 minutes to about 10 grams/10 minutes;

whereby the blend of (A) and (B) has improved elongation and improved release properties.

The invention further provides a blend with improved tensile strength, improved elongation, and improved release properties, and a method of producing a article with improved release properties from the blend.

Claims

1. A release film comprising a blend of:

(A) from about 90% to about 10% by weight of polymethylpentene, wherein the polymethylpentene has a molecular weight from about 200,000 to about 700,000, and a melt flow rate between from about 30 grams/10 minutes to about 200 grams/10 minutes; and

(B) from about 10% to about 90% by weight of polypropylene, wherein the polypropylene has a weight average molecular weight from about 150,000 to about 350,000, and a melt flow rate between from about 1 gram/10 minutes to about 10 grams/10 minutes;

whereby the blend of (A) and (B) has an elongation greater than about 250% and a release load less than about 0.60 lb/in.

2. The film in claim 1, wherein the polypropylene has an atactic fraction of less than about 2%.

3. The film in claim 1, including at least one processing aid.

4. The film in claim 1, including at least one additive.

5. The film in claim 1, wherein the composition of (A) and (B) has a tensile strength greater than about 3000 psi.

11. The film in claim 1, wherein the melt flow rate of the polymethylpentene is from about 60 to about 200 grams/10 minutes.

12. The film in claim 11, wherein the melt flow rate of the polypropylene is from about 2 to about 10 grams/10 minutes.

13. The film in claim 12, wherein the melt flow rate of the polypropylene is from about 4 to about 10 grams/10 minutes.

6. A process for producing a release film comprising the step of:

extruding a film from a composition comprising a blend of;

(A) from about 90% to about 10% by weight of polymethylpentene, wherein the polymethylpentene has a weight average molecular weight from about 200,000 to about 700,000, and a melt flow rate between from about 30 grams/10 minutes to about 200 grams/10 minutes; and

(B) from about 10% to about 90% by weight of polypropylene, wherein the polypropylene has a weight average molecular weight from about 150,000 to about 350,000, and a melt flow rate between from about 1 gram/10 minutes to about 10 grams/10 minutes;

whereby the blend of (A) and (B) has an elongation greater than about 250% and a release load less than about 0.60 lb/in.

7. The process in claim 6, wherein the polypropylene has an atactic fraction of less than about 2%.

8. The process in claim 6, at least one processing aid.

9. The process in claim 6, including at least one additive.

10. The process in claim 6, wherein the composition of (A) and (B) has a tensile strength greater than about 3000 psi.

14. The process of claim 6, wherein the melt flow rate of the polymethylpentene is from about 60 to about 200 grams/10 minutes.

15. The process of claim 14, wherein the melt flow rate of the polypropylene is from about 2 to about 10 grams/10 minutes.

16. The process of claim 15, wherein the melt flow rate of the polypropylene is from about 4 to about 10 grams/10 minutes.