Thermistor

• US 5,534,843 A
• Filed: 01/28/1994
• Issued: 07/09/1996
• Est. Priority Date: 01/28/1993
• Status: Expired due to Term

• Current Assignee: Mitsubishi Materials Corporation
• Original Assignee: Mitsubishi Materials Corporation
• Inventors: Nakajima, Hiroaki, Tsunoda, Masakiyo, Koshimura, Masami
• Primary Examiner(s): HOANG, TU BA
• Application Number:
  US08/189,163
• Time in Patent Office: 893 Days
• Field of Search: 338/22 R, 338/225 D, 338/262, 338/322, 338/323, 338/324, 338/332
• US Class Current: 338/22.00R
• CPC Class Codes: H01C 1/034 the housing or enclosure being formed as coating or mould without outer sheath H01C1/032 takes precedence
• CPC Class Codes: H01C 1/1406 Terminals or electrodes formed on resistive elements having positive temperature coefficient
• CPC Class Codes: H01C 7/008 Thermistors H01C7/02 - H01C7/06 take precedence

Abstract

An insulating glass layer covers the surface of a thermistor element except at the two end surfaces. The insulating glass layer is partially or fully composed of crystallized glass. A terminal electrode is integrally formed on both end surfaces. The terminal electrodes include a baked-on electrode layer formed from a conductive paste. Layers of nickel and tin or lead/tin are plated onto the baked-on electrode. The insulating glass layer enhances shape-maintainability of the insulating glass layer and the baked-on electrodes, provides a smoother glass surface, resulting in a more aesthetically pleasing thermistor, prevents resistance variance due to plating of the baked-on electrodes and provides a strong anti-breaking strength thermistor. The coefficient of thermal expansion of the glass layer is less than the coefficient of thermal expansion of the thermistor element. This difference in coefficients of thermal expansion tends to help the thermistor element resist stress breakage.

Claims

1. A thermistor, comprising:

a thermistor element having first and second opposed end surfaces, and first, second third and fourth peripheral sides;

an insulating glass layer on said first, second third and fourth peripheral sides;

said first and second opposed end surfaces being substantially free of said insulating glass layer;

said insulating glass layer being at least partially crystallized glass;

a terminal electrode on each of said first and second opposed end surfaces; and

said terminal electrode having a baked-on electrode layer in contact with its respective end surface, and at least one plated layer on said baked-on electrode layer.

2. A thermistor as recited in claim 1, wherein said insulating glass layer includes a substantial proportion of said crystallized glass.

3. A thermistor as recited in claim 1, wherein:

a transition temperature for said insulating glass layer before crystallization is in a range from about 400°

C. to about 1000°

C.; and

a crystallization temperature of said insulating glass layer is higher than said transition temperature.

4. A thermistor as recited in claim 1, wherein said insulating glass layer includes a mixture of SiO₂, ZnO and BaO.

5. A thermistor as recited in claim 1, wherein:

said at least one plated layer includes a first plated layer on said baked-on electrode layer, and second plated layer on said first plated layer;

said first plated layer is nickel; and

said second plated layer is selected from the group consisting of Sn and a mixture of Sn/Pb.

8. A thermistor as recited in claim 1, further comprising:

at least one internal resistance regulating;

electrode on at least one of said first, second, third and fourth peripheral sides element; and

said insulating glass layer covering said at least one internal resistance regulating electrode.

9. A thermistor as recited in claim 1, further comprising:

at least two internal resistance regulating electrodes on at least one of said first and third peripheral sides.

10. A thermistor as recited in claim 9, wherein said at least two internal resistance regulating electrodes are electrically connected to respective terminal electrodes.

11. A thermistor as recited in claim 8, wherein said at least one internal resistance regulating electrode is within said thermistor element.

12. A thermistor as recited in claim 11, wherein said at least one internal resistance regulating electrode is electrically connected to said terminal electrode.

6. A thermistor, comprising:

a thermistor element having first and second opposed end surfaces, and first, second third and fourth peripheral sides;

an insulating glass layer on said first, second third and fourth peripheral sides;

said first and second opposed end surfaces being substantially free of said insulating glass layer;

said insulating glass layer being at least partially crystallized glass;

a terminal electrode on each of said first and second opposed end surfaces; and

said crystallized glass has a thermal expansion coefficient of from about 40 to about 100% of a thermal expansion coefficient of said thermistor element.

7. A thermistor as recited in claim 6, wherein:

said crystallized glass has a thermal expansion coefficient of from about 50 to about 90% of a thermal expansion coefficient of said thermistor element.

13. A thermistor as recited in claim 6, wherein said insulating glass layer includes a substantial proportion of said crystallized glass.

14. A thermistor as recited in claim 6, wherein:

a transition temperature for said insulating glass layer before crystallization is in a range from about 400°

C. to about 1000°

C.; and

a crystallization temperature of said insulating glass layer is higher than said transition temperature.

15. A thermistor as recited in claim 6, further comprising:

at least one internal resistance regulating electrode on at least one of said first, second, third and fourth peripheral sides element; and

said insulating glass layer covering said at least one internal resistance regulating electrode.

16. A thermistor as recited in claim 6, further comprising:

at least two internal resistance regulating electrodes on at least one of said first and third peripheral sides.

17. A thermistor as recited in claim 16, wherein said at least two internal resistance regulating electrodes are electrically connected to respective terminal electrodes.

18. A thermistor as recited in claim 15, wherein said at least one internal resistance regulating electrode is within said thermistor element.

19. A thermistor as recited in claim 18, wherein said at least one internal resistance regulating electrode is electrically connected to said terminal electrode.

20. A thermistor as recited in claim 6, wherein said insulating glass layer includes a mixture of SiO₂, ZnO and BaO.