Reduction of nitrogen oxides emissions from diesel engines

• US 5,535,708 A
• Filed: 10/31/1994
• Issued: 07/16/1996
• Est. Priority Date: 08/30/1993
• Status: Expired due to Term

• Current Assignee: Platinum Plus, Inc.
• Original Assignee: Platinum Plus, Inc.
• Inventors: Valentine, James M.
• Primary Examiner(s): Solis, Erick R.
• Application Number:
  US08/331,473
• Time in Patent Office: 624 Days
• Field of Search: 123/1 A, 123/25 C, 123/25 E, 44/51, 44/301, 44/302
• US Class Current: 123/25.00C
• CPC Class Codes: B01F 2101/505 Mixing fuel and water or other fluids to obtain liquid fuel emulsions
• CPC Class Codes: B01F 23/41 Emulsifying
• CPC Class Codes: C10L 1/10 containing additives
• CPC Class Codes: C10L 1/1216 metal compounds, e.g. hydrides, carbides
• CPC Class Codes: C10L 1/1266 nitrogen containing compounds, (e.g. NH3)
• CPC Class Codes: C10L 1/2227 urea; derivatives thereof; urethane C10L1/221 takes precedence
• CPC Class Codes: C10L 1/224 Amides; Imides carboxylic acid amides, imides C10L1/221, C10L1/2227 take precedence
• CPC Class Codes: C10L 1/2381 polyamides; polyamide-esters; polyurethane, polyureas C10L1/221 takes precedence
• CPC Class Codes: C10L 1/305 organo-metallic compounds (containing a metal to carbon bond)
• CPC Class Codes: C10L 10/02 for reducing smoke development
• CPC Class Codes: F01N 2430/04 by adding non-fuel substances to combustion air or fuel, e.g. additives
• CPC Class Codes: F01N 3/023 using means for regenerating the filters, e.g. by burning trapped particles by electrically controlling the supply of combustible mixture or its constituents only F02D41/0235
• CPC Class Codes: F02B 3/06 with compression ignition compression ignition engines using air or gas for blowing fuel into compressed air in cylinder F02B13/02
• CPC Class Codes: F02B 47/04 the substances being other than water or steam only
• CPC Class Codes: F02M 25/0224 Water treatment or cleaning F02M25/032 takes precedence
• CPC Class Codes: F02M 25/0228 Adding fuel and water emulsion
• CPC Class Codes: Y02T 10/12 Improving ICE efficiencies

Abstract

The present invention relates to a process for reducing nitrogen oxides emissions from a diesel engine, which comprises preparing an emulsion of an aqueous urea solution in diesel fuel, and supplying said emulsion to a diesel engine for combusting therein, whereby combustion of the emulsion leads to a reduction in the nitrogen oxides emissions from the diesel engine when compared with combustion of diesel fuel alone.

Claims

1. A process for reducing nitrogen oxides emissions from a diesel engine comprising forming an emulsion of an aqueous solution in diesel fuel which comprises (a) about 5% to about 70% solution by weight of a compound selected from the group consisting of urea, ammonium carbamate, ammonium carbonate, ammonium bicarbonate, ammonium formate, ammonium oxalate, ammonium hydroxide, bipyridyl, cyanuric acid, urea-formaldehyde reaction product, and stable amines including hexamethylenetetramine, and mixtures of these, and (b) a catalyst comprising a composition or complex of a metal selected from the group consisting of cerium, platinum or a platinum group metal, copper, iron or manganese, wherein at least about 70% of the water droplets in the emulsion have a particle size below about 5 microns Sauter mean diameter, and supplying said emulsion to a diesel engine to be combusted therein, whereby combustion of the emulsion leads to a reduction in the nitrogen oxides emissions from the diesel engine when compared with combustion of diesel fuel alone.

2. The process of claim 1, wherein said aqueous urea solution comprises about 5% to about 35% urea by weight.

3. The process of claim 1, wherein at least about 85% of the water droplets have a particle size below about 5 microns Sauter mean diameter.

4. The process of claim 1, wherein said catalyst comprises a water soluble or water dispersible platinum group metal composition present in the aqueous phase of said emulsion.

5. The process of claim 1, wherein said catalyst comprises a fuel soluble platinum group metal composition present in the fuel phase of said emulsion or in said emulsion after it is formed.

6. A process for reducing nitrogen oxides emissions from a diesel engine comprising:

a. preparing a solution of a compound selected from the group consisting of urea, ammonium carbamate, ammonium carbonate, ammonium bicarbonate, ammonium formate, ammonium oxalate, ammonium hydroxide, bipyridyl, cyanuric acid, urea-formaldehyde reaction product, and stable amines including hexamethylenetetramine, and mixtures of these in water to form an aqueous solution;

b. emulsifying said aqueous solution with diesel fuel to form an emulsion; and

c. incorporating into the emulsion a catalyst comprising a composition or complex of a metal selected from the group consisting of cerium, platinum or a platinum group metal, copper, iron or manganese;

d. supplying said emulsion to a diesel engine to be combusted therein, whereby combustion of the emulsion leads to a reduction in the nitrogen oxides emissions from the diesel engine when compared with combustion of diesel fuel alone.

7. The process of claim 6, wherein said urea solution further comprises an emulsifier.

8. The process of claim 7, wherein said emulsifier is selected from the group consisting of alkanolamides and phenolic surfactants.

9. The process of claim 6, wherein said aqueous solution comprises about 5% to about 35% urea by weight.

10. The process of claim 6, wherein said emulsion comprises about 15% to about 45% aqueous solution by weight.

11. The process of claim 6, wherein said aqueous solution is prepared by first forming a concentrated solution of urea comprising about 30% to about 50% urea by weight and then diluting said concentrated solution with water until the concentration of urea is about 5% to about 25% by weight.

12. The process of claim 6, wherein said catalyst comprises a water soluble or water dispersible platinum group metal composition present in the aqueous phase of said emulsion.

13. The process of claim 6, wherein said catalyst comprises a fuel soluble platinum group metal composition present in the fuel phase or in said emulsion after it is formed.