Gas generating propellant

• US 5,538,567 A
• Filed: 03/18/1994
• Issued: 07/23/1996
• Est. Priority Date: 03/18/1994
• Status: Expired due to Term

• Current Assignee: Automotive Systems Laboratory, Incorporated (Ningbo Junsheng Investment Group Co., Ltd.)
• Original Assignee: OLIN Corporation
• Inventors: Henry, Guy H. III, Solverson, Matthew S.
• Primary Examiner(s): Nelson, Peter A.
• Application Number:
  US08/214,509
• Time in Patent Office: 858 Days
• Field of Search: 149/18, 149/92
• US Class Current: 149/18
• CPC Class Codes: C06B 23/009 Wetting agents, hydrophobing agents, dehydrating agents, antistatic additives, viscosity improvers, antiagglomerating agents, grinding agents and other additives for working up
• CPC Class Codes: C06D 5/06 by reaction of two or more solids

Abstract

There is provided a gas generating propellant mix consisting essentially of guanidine nitrate, an oxidizer selected from the group consisting of potassium perchlorate and ammonium perchlorate, a flow enhancer and a binder. When ignited, the propellant mix generates nitrogen, carbon dioxide and steam at an elevated temperature, typically in excess of 800° C. The propellant mix is particularly useful in augmented gas generators to augment the evolution of oxygen from a secondary source such as potassium chlorate. The propellant mix is free of highly toxic compounds and has particular application in automotive airbags.

Claims

1. A gas generating propellant used to deploy an air bag, consisting essentially of:

from about 55% to about 75%, by weight, guanidine nitrate;

from about 25% to about 45%, by weight, of an oxidizer selected from the group consisting of potassium perchlorate and ammonium perchlorate;

from about 0.5% to about 5.0%, by weight, of a flow enhancer; and

up to about 5%, by weight, of a binder.

2. The gas generating propellant of claim 1 wherein said flow enhancer is selected from the group consisting of graphite and carbon black.

3. The gas generating propellant of claim 2 wherein said binder is calcium resinate.

4. The gas generating propellant of claim 2 consisting essentially of from about 57% to about 71%, by weight, guanidine nitrate, from about 28% to about 42%, by weight, potassium perchlorate and from about 0.5% to about 1.5%, by weight, graphite.

5. The gas generating propellant of claim 4 further containing from about 1% to about 3% by weight calcium resinate.

6. The gas generating propellant of claim 4 wherein the average particle size of said guanidine nitrate is from about 75 microns to about 350 microns, the average particle size of said potassium perchlorate is from about 50 microns to about 200 microns and the average particle size of said graphite is from about 7 microns to about 70 microns.

7. The gas generating propellant of claim 6 wherein the average particle size of said guanidine nitrate is from about 100 microns to about 200 microns, the average particle size of said potassium perchlorate is from about 75 microns to about 125 microns and the average particle size of said graphite is from about 15 microns to about 35 microns.

8. A component of an airbag, comprising:

a primary gas generating propellant mix consisting essentially of from about 55% to about 75%, by weight, guanidine nitrate, from about 25% to about 45%, by weight, of an oxidizer selected from the group consisting of potassium perchlorate and ammonium perchlorate, from about 0.5% to about 5.0%, by weight, of a flow enhancer and up to about 5%, by weight, of a binder that is effective to deliver a mixture of nitrogen, carbon dioxide and steam to a secondary gas source, said mixture being delivered at a temperature in excess of about 800°

C.

9. The component of claim 8 wherein said mixture is delivered at a temperature of from about 900°

C. to about 1050°

C.

10. The component of claim 8 wherein said mixture is delivered at a speed of from about 530 meters per second to about 650 meters per second.

11. The component of claim 10 wherein said mixture is delivered at a speed about 560 meters per second to about 625 meters per second.

12. The component of claim 10 wherein said flow enhancer is selected from the group consisting of graphite and carbon black.

13. The component of claim 12 wherein said binder is calcium resinate.

14. The component of claim 12 wherein said gas generating propellant mix consists essentially of from about 57% to about 71%, by weight, guanidine nitrate, from about 28% to about 42%, by weight, potassium perchlorate and from about 0.5% to about 1.5%, by weight, graphite.

15. The component of claim 14 further containing from about 1% to about 3% calcium resinate.

16. The component of claim 14 wherein the average particle size of said guanidine nitrate is from about 75 microns to about 350 microns, the average particle size of said potassium perchlorate is from about 50 microns to about 200 microns and the average particle size of said graphite is from about 7 microns to about 70 microns.