Thermal barrier coating system having no bond coat

• US 5,538,796 A
• Filed: 10/13/1992
• Issued: 07/23/1996
• Est. Priority Date: 10/13/1992
• Status: Expired due to Term

• Current Assignee: General Electric Company
• Original Assignee: General Electric Company
• Inventors: Vakil, Himanshu B., Connor, William B., Schaffer, Jon C., Nagaraj, Bangalore A., Murphy, Wendy H.
• Primary Examiner(s): Walsh, Donald P.
• Assistant Examiner(s): JENKINS, DANIEL J
• Application Number:
  US07/960,494
• Time in Patent Office: 1,379 Days
• Field of Search: 427/584, 427/585, 427/532, 428/469, 428/680, 428/938, 148/675, 416/241 B
• US Class Current: 428/469
• CPC Class Codes: C23C 14/02 Pretreatment of the material to be coated C23C14/04 takes precedence
• CPC Class Codes: C23C 14/083 of refractory metals or yttrium
• CPC Class Codes: F01D 5/288 Protective coatings for blades
• CPC Class Codes: F05D 2230/90 Coating; Surface treatment manufacture with deposition of material F05D2230/30
• CPC Class Codes: Y02T 50/60 Efficient propulsion technologies, e.g. for aircraft

Abstract

A coated article is prepared by melting and casting an article substrate formed of a nickel-base superalloy. The article substrate is heated in a hydrogen-containing atmosphere at a temperature of at least 2000° F. for a period sufficient to desulfurize the substrate to a sulfur content of less than about 1 part per million. Optionally, an aluminum-oxide environmental coating is provided overlying the substrate. A ceramic thermal barrier coating is applied overlying the substrate. Significantly, there being no bond coat applied to the substrate prior to the application of the thermal barrier coating.

Claims

1. A method for preparing a coated article, comprising the steps of:

furnishing an aluminum-bearing nickel base superalloy article substrate;

thereafter

desulfurizing the article substrate; and

applying by a physical vapor deposition process a ceramic thermal barrier coating overlying the substrate, there being no bond coat applied to the substrate prior to the application of the thermal barrier coating.

2. The method of claim 1, wherein the step of furnishing includes the steps of melting and casting an alloy that forms the article substrate.

3. The method of claim 1, wherein the step of desulfurizing includes the step of

heating the article substrate to an elevated temperature in the presence of a gaseous reactive agent that reacts with sulfur to form a gaseous sulfide.

4. The method of claim 3, wherein the step of heating includes heating the substrate to a temperature of at least 2000°

F.

5. The method of claim 3, wherein the gaseous reactive agent comprises hydrogen.

6. The method of claim 1, wherein the step of applying the thermal barrier coating by a physical vapor deposition process is selected from the group of physical vapor deposition processes consisting of electron beam deposition and sputtering.

7. The method of claim 6, wherein the thermal barrier coating is yttria-stabilized zirconia.

8. The method of claim 1, including the additional step, after the step of desulfurizing and before the step of applying a thermal barrier coating, of providing an aluminum-oxide environmental coating overlying the substrate.

9. An article prepared by the process of claim 1.

10. A method for preparing a coated article, comprising the steps of:

furnishing an article substrate formed of a nickel-base superalloy;

thereafter

heating the article substrate in a gaseous reactive agent for a period sufficient to desulfurize the substrate; and

applying a ceramic thermal barrier coating by a physical vapor deposition process overlying the substrate, there being no bond coat applied to the substrate prior to the application of the thermal barrier coating.

11. The method of claim 10, wherein the reactive agent comprises hydrogen.

12. The method of claim 10, wherein the step of heating heats the article to a temperature of at least 2000°

F.

13. The method of claim 10, wherein the step of providing includes the step of overcoating at least a portion of the surface of the article with an environmental coating that forms an aluminum-oxide scale upon heating.

14. The method of claim 10, wherein the step of providing includes the step of depositing an aluminum-oxide scale on the surface of the article.

15. The method of claim 10, wherein the step of applying the thermal barrier coating by a physical vapor deposition process is selected from the group of physical vapor deposition processes consisting of electron beam deposition and sputtering.

16. An article prepared by the process of claim 10.

17. The method of claim 10 further including a step of providing an aluminum oxide environmental coating overlying the substrate.

18. The method of claim 17 wherein the aluminum oxide environmental coating is thermally grown onto the substrate.

19. The method of claim 17 wherein the ceramic thermal barrier coating overlies the environmental coating.

20. A method for preparing a coated article, comprising the steps of:

furnishing an article substrate formed of a nickel-base superalloy, the superalloy having a sulfur content of less than about 1 part per million by weight; and

applying, using a low sulfur application method, a ceramic thermal barrier coating overlying the substrate, there being no bond coat applied to the substrate prior to the application of the thermal barrier coating.

21. The method of claim 20, including the additional step, after the step of furnishing and before the step of applying, of providing at least a portion of the surface of the article with an environmental coating that forms an aluminum-oxide scale upon heating.

22. The method of claim 21, wherein the step of providing includes the step of depositing an aluminum-oxide scale on the surface of the article.

23. The method of claim 21, wherein the step of providing includes the step of depositing an aluminum-rich overcoating onto the surface of the substrate.

24. An article prepared by the process of claim 20.