Method of fabricating thin film cells and printed circuit boards containing thin film cells using a screen printing process

• US 5,540,742 A
• Filed: 04/24/1995
• Issued: 07/30/1996
• Est. Priority Date: 05/01/1989
• Status: Expired due to Term

• Current Assignee: Brother Kogyo Kabushiki Kaisha
• Original Assignee: Brother Kogyo Kabushiki Kaisha
• Inventors: Miyabayashi, Takeshi, Mano, Morimasa, Sangyoji, Kazuo
• Primary Examiner(s): Skapars, Anthony
• Application Number:
  US08/427,222
• Time in Patent Office: 463 Days
• Field of Search: 29/623.5, 427/282, 427/256, 427/272, 101/114, 101/129
• US Class Current: 29/623.5
• CPC Class Codes: H01M 10/052 Li-accumulators
• CPC Class Codes: H01M 10/0565 Polymeric materials, e.g. gel-type or solid-type
• CPC Class Codes: H01M 50/209 adapted for prismatic or rectangular cells H01M50/216 takes precedence
• CPC Class Codes: H01M 6/188 Processes of manufacture
• CPC Class Codes: H01M 6/40 Printed batteries , e.g. thin film batteries
• CPC Class Codes: H05K 1/16 incorporating printed electric components, e.g. printed resistor, capacitor, inductor
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y10T 29/49115 including coating or impregnating

Abstract

Disclosed herein is a thin film cell in which a cell unit is sealed by a polyimide film. Such a cell unit can be obtained by forming an ion-conductive polymer electrolytic layer formed by mixing polyethylene oxide derivatives with lithium salt on a negative-polarity material composed of lithium or a lithium-aluminum metal foil and then forming a layer of a positive-polarity material from composite materials formed by mixing Vanadium oxide and polyethylene oxide derivatives together, on the electrolytic layer, by using a screen printing process. Also disclosed is a printed circuit board with a thin film cell incorporated therein, in which said cell unit is to be mounted on a flexible film substrate, by using a screen printing process. By this invention, the thin film cell and the printed circuit board can be fabricated in a continuous manner by making use of a screen printing process.

Claims

1. A method of fabricating a thin film cell, comprising:

using a screen printing process, forming an electrolytic material layer on a flexible, electrically-conductive foil layer, said foil layer having a polarity such that said foil layer is an anode layer; and

using a screen printing process, forming a cathode layer on said electrolytic material layer.

2. The method according to claim 1, further comprising surrounding said anode layer, electrolytic layer, and cathode layer by a packaging member.

3. The method according to claim 2, wherein said packaging member includes a first and a second sheet of heat-bondable, insulative material containing a lead terminal and wherein said first sheet is placed below said anode layer, said second sheet is placed above said cathode layer and said first and second sheets are vacuum fusion bonded to each other.

4. The method according to claim 1, further comprising a fourth step of forming a current collector layer on said cathode layer.

5. The method according to claim 1, further comprising:

attaching said anode layer on a substrate; and

forming lead terminals and a circuit pattern on said substrate which continuously extend from said anode layer.

6. The method according to claim 5, further comprising:

forming a current collector layer on said cathode layer.

7. The method according to claim 6, wherein at least one of said current collector layer, said lead terminals, and said circuit pattern is formed by a screen printing process.

8. The method according to claim 4, wherein said current collector layer is formed using a screen printing process.

9. The method according to claim 1, wherein said anode layer is an electrically-conductive metal foil.

10. The method according to claim 9, wherein said metal foil is lithium foil.

11. The method according to claim 9, wherein said metal foil is a lithium-aluminum alloy foil.

12. The method according to claim 1, wherein said cathode layer is a composite material obtained by mixing Vanadium oxide and polyethylene oxide derivatives together.

17. The method according to claim 4, wherein said current collector layer is formed by applying conductive paste on said cathode layer.

18. The method according to claim 5, wherein said anode layer is attached to said substrate by applying an epoxy resin adhesive to said substrate prior to forming said anode layer.

19. The method according to claim 6, wherein an insulative layer is formed over a portion of said electrolytic layer prior to formation of said cathode layer for preventing short-circuiting between said cathode layer and said lead terminals.

20. The method according to claim 19, wherein said insulative layer is polyimide.

21. The method according to claim 5, wherein said substrate is a polyester film.

25. The method of claim 1, wherein the step of forming an electrolytic material layer comprises forming the electrolytic material layer in a predetermined pattern, and

wherein the step of forming a cathode layer comprises forming the cathode layer in a predetermined pattern.

13. A method of fabricating a thin film cell, said thin film cell having a flexible, electrically-conductive foil layer, an electrolytic material layer and an electrode layer, said foil layer and said electrode layer having polarities such that when said foil layer is a cathode layer said electrode layer is an anode layer, and when said foil layer is an anode layer said electrode layer is a cathode layer, said method comprising the steps of:

using a screen printing process, forming said electrolytic material layer on said flexible, electrically-conductive foil layer; and

using a screen printing process, forming said electrode layer on said electrolytic material layer.

14. The method according to claim 13, wherein said electrolytic material layer is an ion-conductive polymer electrolyte.

15. The method according to claim 14, wherein said polymer electrolyte is formed by mixing polyethylene oxide derivatives with lithium salt.

16. The method according to claim 15, wherein said polymer electrolyte further includes carbon powder mixed therein.

22. The method of claim 13, wherein the step of forming said electrolytic material layer comprises forming said electrolytic material layer in a predetermined pattern, and

wherein the step of forming said electrode layer comprises forming said electrode layer in a predetermined pattern.

23. A method of fabricating a thin film cell, comprising:

using a screen printing process, forming an electrolytic material layer on a flexible, electrically-conductive foil layer, said foil layer having a polarity such that said foil layer is a cathode layer; and

using a screen printing process, forming an anode layer on said electrolytic material layer.

24. The method of claim 23, wherein the step of forming an electrolytic material layer comprises forming the electrolytic material layer in a predetermined pattern, and

wherein the step of forming an anode layer comprises forming the anode layer in a predetermined pattern.