Method and apparatus for correcting flow and pressure sensor drift in a gas chromatograph

• US 5,542,286 A
• Filed: 01/23/1995
• Issued: 08/06/1996
• Est. Priority Date: 01/23/1995
• Status: Expired due to Term

• Current Assignee: Agilent Technologies, Inc.
• Original Assignee: Hewlett-Packard Company (HP Inc.)
• Inventors: Wang, Tak K., Henderson, Robert C.
• Primary Examiner(s): Williams, Hezron E.
• Assistant Examiner(s): LARKIN, DANIEL SEAN
• Application Number:
  US08/376,718
• Time in Patent Office: 561 Days
• Field of Search: 73/3, 73/23.21, 73/23.22, 73/23.24
• US Class Current: 73/23.22
• CPC Class Codes: G01N 2030/626 calibration, baseline
• CPC Class Codes: G01N 30/32 of pressure or speed G01N30/36 takes precedence

Abstract

A method and apparatus for correcting flow and pressure sensor drift in a gas chromatograph. At a convenient time when the chromatograph is not being used for analysis, the input valves controlling the input into the chromatograph are shut, reducing internal flow to zero. The indicated rate of flow is then measured using the flow sensor. If the value measured by the flow sensor during this test is different than the originally calibrated offset by some predetermined amount, then the newly measured value replaces the stored offset value. In a chromatograph where some minimum internal gas or liquid flow is necessary to prevent contamination of the instrument, a three-way valve can direct liquid or gas flow away from the flow sensor during this calibration run without eliminating internal flow through the chromatograph. To calibrate the pressure sensor, the pressure sensor is vented to ambient air pressure and its reading at that pressure is then used as an offset during later sample analysis.

Claims

1. In a gas chromatograph having at least a processor and a sample/carrier gas input section with at least a first valve controllable by and coupled to the processor and a first flow sensor, a method for correcting the drift of the flow sensor comprising the steps of:

setting the at least first valve so no carrier gas/sample flows through the flow sensor;

reading the flow registered by the flow sensor using the processor;

comparing the flow measured by the flow sensor with a reference value stored in the processor;

using the reference value in the processor if the flow registered by the flow sensor does not exceed the reference value by a first predetermined amount; and

replacing the reference value with the flow registered by the flow sensor if the flow registered by the flow sensor does exceed the reference value by the first predetermined amount.

2. The method of claim 1 wherein the steps of setting the at least first valve, reading the flow registered by the flow sensor, comparing the flow measured by the flow sensor, using the reference value in the processor, and replacing the measured value in the processor are repeated during one sampling run of the gas chromatograph.

3. The method of claim 1 wherein the sample/carrier gas input section comprises a split/splitless gas input section.

4. The method of claim 1 wherein the sample/carder gas input section comprises a cool on column gas input section.