Method of removing coating films

• US 5,542,982 A
• Filed: 02/01/1995
• Issued: 08/06/1996
• Est. Priority Date: 09/25/1992
• Status: Expired due to Term

• Current Assignee: Mitsui Chemicals Incorporated (Mitsui Chemicals)
• Original Assignee: Mitsui Petrochemical Industries, Ltd. (Mitsui Chemicals), Nissan Motor Co., Ltd.
• Inventors: Watanabe, Kazuyuki, Saito, Mitsuo, Yusawa, Motoyasu, Terada, Masahiro, Kamae, Hirosuke
• Primary Examiner(s): EL ARINI, ZEINAB
• Application Number:
  US08/383,675
• Time in Patent Office: 552 Days
• Field of Search: 134/2, 134/5, 134/6, 134/7, 134/10, 134/19, 134/38, 134/6, 252/79.5
• US Class Current: 134/5
• CPC Class Codes: B29B 17/02 Separating plastics from other materials
• CPC Class Codes: B29B 2017/0296 Dissolving the materials in aqueous alkaline solutions, e.g. NaOH or KOH
• CPC Class Codes: B29B 2017/0492 Projecting the material on stationary or moving impact surfaces or plates
• CPC Class Codes: B29K 2023/00 Use of polyalkenes or derivatives thereof as moulding material
• CPC Class Codes: B29K 2033/04 Polymers of esters
• CPC Class Codes: B29K 2075/00 Use of PU, i.e. polyureas or polyurethanes or derivatives thereof, as moulding material
• CPC Class Codes: B29L 2009/005 coated
• CPC Class Codes: B29L 2031/3044 Bumpers
• CPC Class Codes: B29L 2031/3055 Cars
• CPC Class Codes: C08J 11/06 without chemical reactions
• CPC Class Codes: Y02P 20/582 Recycling of unreacted starting or intermediate materials
• CPC Class Codes: Y02W 30/62 Plastics recycling; Rubber recycling

Abstract

Improved methods of removing coating films from resin substrates includes first treating the resin substrates in an aqueous alkali solution with a concentration of 0.1 wt % or more at a temperature of 110° C. or more, which temperature is lower than the melting point of the substrates and then polishing the surfaces of the substrates by either bringing them into contact with each other in suitable equipment such as a screw feeder, or using an abrasive in suitable equipment such as a high-speed vessel type stirrer, or subjecting the substrates to a liquid honing process.

Claims

1. A method for removing a cured coating film of a thermosetting resin composition from surfaces of polyolefin resin substrates, comprising the steps of:

treating crushed particulates of polyolefin resin substrates having a particle size in a range of from 0.5 to 20 mm, in an aqueous alkali solution having a concentration of 0.2 to 4.0% by weight at a temperature of 110°

C. or higher, but lower than a melting point of said substrates to obtain treated resin substrate particulates;

contacting the treated resin substrate particulates with each other, thereby removing said cured coating film from said particulates by shearing force in a screw feeder polishing machine or in a polishing machine equipped with a high-speed vessel stirrer; and

recycling resulting treated particulates which have had said cured coating film removed for reuse as polyolefin resin.

2. A method according to claim 1, wherein said particulates are brought into contact with each other in a screw feeder polishing machine, with said particulates being held at a temperature of from 30°

to 110°

C. lower than the melting point of said substrates.

3. A method according to claim 2, wherein said particulates are brought into contact with each other in a screw feeder polishing machine with a shearing energy of at least 0.2 kW per kg of the polyolefin resin substrates.

4. A method according to claim 1, wherein said particulates are brought into contact with each other in a polishing machine equipped with a high-speed vessel stirrer in a presence of an abrasive at a temperature of from 70°

to 120°

C.

5. A method according to claim 4, wherein said particulates are brought into contact with each other in a polishing machine equipped with a high-speed vessel stirrer in a presence of an abrasive at a temperature of from 80°

to 100°

C.

6. A method according to claim 4, wherein said abrasive used for removing the cured coating is quartz sand.

7. A method according to claim 1, wherein said aqueous alkali solution is selected from at least one of NaOH and KOH aqueous solutions.

8. A method according to claim 1, wherein said treating in said aqueous alkali solution is carried out by immersing said particulates in said aqueous alkali solution at a temperature higher than 140°

C.

9. A method-according to claim 1, wherein said thermosetting resin composition comprises at least one member selected from a group consisting of alkyd, acrylic, and polyester resin.

10. A method according to claim 1, wherein said substrates comprises polypropylene.