Device for maintaining a vacuum in a thermally insulating jacket and method of making such device

• US 5,544,490 A
• Filed: 06/06/1995
• Issued: 08/13/1996
• Est. Priority Date: 07/07/1994
• Status: Expired due to Term

• Current Assignee: SAES Getters SpA (SAES Getters S)
• Original Assignee: SAES Getters SpA (SAES Getters S)
• Inventors: Belloni, Fortunato, Manini, Paolo
• Primary Examiner(s): KILNER, CHRISTOPHER B
• Application Number:
  US08/479,343
• Time in Patent Office: 434 Days
• Field of Search: 62/46.1, 62/46.2, 62/46.3, 62/45.1, 62/51.1, 417/48, 252/181.1
• US Class Current: 62/46.1
• CPC Class Codes: A47J 41/022 Constructional details of the elements forming vacuum space
• CPC Class Codes: B65D 81/3233 Flexible containers disposed within rigid containers
• CPC Class Codes: F16L 59/065 using vacuum F16L59/075 takes precedence
• CPC Class Codes: F17C 2203/0395 Getter
• CPC Class Codes: F17C 2203/0636 Metals
• CPC Class Codes: F17C 2203/0646 Aluminium
• CPC Class Codes: F17C 2203/0648 Alloys or compositions of metals
• CPC Class Codes: F17C 2203/066 Plastics
• CPC Class Codes: F17C 2209/221 Welding
• CPC Class Codes: F17C 2221/011 Oxygen
• CPC Class Codes: F17C 2221/013 Carbone dioxide
• CPC Class Codes: F17C 2221/014 Nitrogen
• CPC Class Codes: F17C 2221/015 Carbon monoxide
• CPC Class Codes: F17C 2221/03 Mixtures
• CPC Class Codes: F17C 2270/0509 "Dewar" vessels
• CPC Class Codes: F17C 3/08 by vacuum spaces, e.g. Dewar flask for household use A47J41/02

Abstract

A device for maintaining a vacuum in a thermally insulating jacket is described. The device comprises a container formed of a gas-tight material, preferably aluminum, which has an opening to the atmosphere. Inside the container is a first pellet comprising a powder of a Ba--Li alloy getter material. Arranged above, and completely covering, the first pellet is a second pellet comprising a powder of a drying material, optionally including the oxide of a noble metal and a material to prevent contraction of the drier. A process for manufacturing such a device is also described in which the first pellet is obtained by compression of its constituent powders at a pressure between about 30 bar and 1000 bar.

Claims

1. A method for manufacturing a device for maintaining a vacuum, comprising the steps of:

a) providing a substantially gas-impermeable container having open and closed ends;

b) compressing a powder including a Ba--Li getter alloy at a pressure of between about 30 bar and about 1000 bar to form a first pellet;

c) locating said first pellet in said container proximate to said closed end; and

d) locating a second pellet including a drying agent in said container proximate to said open end such that said second pellet covers substantially said first pellet;

whereby said device is capable of maintaining a nitrogen sorption rate of at least about one cubic centimeter/second after exposure to air for fifteen minutes.

2. The method of claim 1, wherein said pressure is between about 150 bar and about 300 bar.

3. The method of claim 2, wherein said first pellet is an alloy having the stoichiometric formula BaLi₄.

4. The method of claim 3, wherein said first pellet comprises a powder of BaLi₄ particles between about 1.0 μ

m and about 1000 μ

m in size.

5. The method of claim 4, wherein said drying agent is selected from the group consisting of barium oxide, strontium oxide and phosphorus oxide and their mixtures.

6. The method of claim 5, wherein drying agent comprises a powder of drying agent particles between about 10 μ

m and about 1000 μ

m in size.

7. The method of claim 6, wherein said drying agent is barium oxide.

8. The method of claim 5, wherein said second pellet further includes a noble metal oxide selected from the group consisting of silver oxide, osmium oxide, iridium oxide, ruthenium oxide, rhodium oxide and palladium oxide.

9. The method of claim 8, wherein the ratio by weight between said drying agent and said noble metal oxide is between 5000:

1 and 10;

1.

10. The method of claim 5, wherein said second pellet further includes an anti-contraction agent selected from the group consisting of alumina, zeolites and activated carbon.

11. The method of claim 10, wherein said anti-contraction agent is alumina.

12. A device for maintaining a vacuum in an enclosed space, comprising:

a) a substantially gas-impermeable container having open and closed ends,

b) a first pellet formed of a getter material including a Ba--Li alloy, said first pellet being located in said container proximate to said closed end; and

c) a second pellet including a drying agent, a noble metal oxide selected from the group consisting of silver oxide, osmium oxide, iridium oxide, ruthenium oxide, rhodium oxide and palladium oxide, and an anti-contraction agent selected from the group consisting of alumina, zeolites and activated carbon, said second pellet being located in said container proximate to said open end, and said second pellet covering substantially said first pellet;

wherein said device is capable of maintaining a nitrogen sorption rate of at least about one cubic centimeter/second after exposure to air for fifteen minutes.

13. The device of claim 12, wherein said anti-contraction agent is alumina.

14. A device for maintaining a vacuum in an enclosed space, comprising:

a) a substantially gas-impermeable container having open and closed ends,

b) a first pellet formed of a getter material including a Ba--Li alloy, said getter material comprising a compressed powder formed by compression of a powder of said getter material at a pressure between about 30 bar and about 1000 bar, said first pellet being located in said container proximate to said closed end; and

c) a second pellet including a drying agent, said second pellet being located in said container proximate to said open end, and said second pellet covering substantially said first pellet;

wherein said device is capable of maintaining a nitrogen sorption rate of at least about one cubic centimeter/second after exposure to air for fifteen minutes.

15. The device of claim 14, wherein said pressure is between about 150 bar and about 300 bar.