Electrochemical apparatus for power delivery utilizing an air electrode

• US 5,545,492 A
• Filed: 09/29/1993
• Issued: 08/13/1996
• Est. Priority Date: 10/14/1992
• Status: Expired due to Fees

• Current Assignee: International Power Ltd. (ENGIE SA)
• Original Assignee: International Power Ltd. (ENGIE SA)
• Inventors: Zito, Ralph
• Primary Examiner(s): BARTS, SAMUEL A
• Application Number:
  US08/128,127
• Time in Patent Office: 1,049 Days
• Field of Search: 429/39, 429/42, 429/29, 429/46, 429/206, 429/229, 429/14, 429/15
• US Class Current: 429/454
• CPC Class Codes: H01M 12/08 composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
• CPC Class Codes: H01M 8/184 Regeneration by electrochemical means
• CPC Class Codes: H01M 8/20 Indirect fuel cells, e.g. fuel cells with redox couple being irreversible H01M8/18 takes precedence
• CPC Class Codes: Y02E 60/50 Fuel cells
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product

Abstract

An electrochemical apparatus for power delivery employs an array of electrochemical cells which comprises an end +^ve electrode and an end -^ve electrode separated by one or more bipolar mid-electrodes each with a +^ve side and a -^ve side, the +^ve side of each bipolar electrode comprising an electrically conductive substrate with a porous conductive surface. A bubbly dispersion of air/oxygen in an electrolyte is contacted with the +^ve sides of the bipolar electrodes. The electrochemical apparatus of the invention may be used with an oxygen-sulfur couple with these reagents being provided for example as sodium salts in aqueous solutions, the overall reaction being:

4H.sub.2 O+4S.sup.2- +2O.sub.2 →8OH.sup.- +4S,

The process is preferably carried out in an array of cells (20), comprising a plurality of bipolar electrodes 13, each having a +^ve side 12A and a -^ve side 14A spaced from one another by membranes 16 which divide the cell into +^ve and -^ve chambers (22C and 24C) for posilyte and anolyte solutions (22, 24) which are circulated through the chambers.

Claims

1. An array of electrochemical cells forming an electrochemical apparatus for energy storage and power delivery which comprises

a) an end +^ve electrode and an end -^ve electrode separated by one or more of bipolar mid-electrodes each of which has a +^ve side and a -^ve side which each face a respective +^ve chamber and -^ve chamber, the +^ve side of each bipolar electrode comprising an electrically conductive substrate having a porous conductive surface, the bipolar electrodes being separated from one another by cation exchange membranes,

b) means to form an intimate mixture of air/oxygen with an electrolyte to produce a dispersion of bubbles in the electrolyte, and

c) means to circulate the electrolyte produced in step b) through the +^ve chambers of the cell array.

2. An array of cells as defined in claim 1 wherein the porous conductive surface on each of the +^ve sides of the bipolar electrodes is selected from the group consisting of carbon particles, carbon fibres and hollow carbon rods in intimate contact with one another and with the substrate surface.

3. An array of cells as defined in claim 2, wherein the porous conductive surface has a thickness greater than 2.5 mm.

4. An array of cells as defined in claim 2, wherein each of said bipolar electrodes further comprises a non-woven screen provided between said porous conductive surface and an adjacent cation exchange membrane so as to restrain said porous conductive surface.

5. An array of cells as defined in claim 1 wherein the means to form the intimate mixture of air/oxygen with an electrolyte is external to the +^ve chambers of the cell.

6. An array of cells as defined in claim 1 wherein the means to form the intimate mixture of air/oxygen with an electrolyte is within each of the +^ve chambers of the cell.

7. An array of cells as defined in claim 1 wherein the electrolyte circulating in the +^ve chambers is a dilute alkaline solution.

8. An array of cells as defined in claim 7 wherein the electrolyte is selected from the group consisting of sodium hydroxide, potassium hydroxide, lithium hydroxide and ammonium hydroxide.

9. An array of cells as defined in claim 1 wherein the electrolyte circulating in the +^ve chambers is a dilute acid solution.

10. An array of cells as defined in claim 9 wherein the electrolyte is selected from the group consisting of hydrochloric acid and sulfuric acid.

11. An array of cells as defined in claim 1 wherein the the electrolyte circulating through the -^ve chambers during power delivery is selected from a sulfide, a vanadium (V²⁺) salt and a chromium (Cr²⁺) salt.

12. An array of cells as defined in claim 1 which is electrically restorable or chemically replenishable.

13. An array of cells as defined in claim 12 wherein the electrical restoration comprises means to reverse the polarity on the +^ve and -^ve electrodes and means to provide sufficient voltage to drive the chemical reactions in the reverse direction.

14. An array of cells as defined in claim 12 wherein the chemical replenishment comprises means to circulate one or both of the electrolytes from the +^ve and/or -^ve chambers to storage means comprising a volume of electrolyte greater than the volume of the respective +^ve and/or -^ve chambers for extended delivery of power over a longer discharge cycle than the volume of the +^ve and/or -^ve chambers alone would permit.

15. An array of electrochemical cells as defined in claim 1 which are connected in electrical series.

16. An array of cells as defined in claim 1, wherein said porous conductive surface has a porosity in the range of from 0.7 to 0.85.

17. An array of cells as defined in claim 1, wherein the porous conductive surface on each of the +^ve sides of the bipolar electrodes comprises a material selected from the group consisting of carbon particles, carbon fibers, and hollow carbon rods bonded to the +^ve side of the electrically conductive substrate.

18. An array of cells as defined in claim 17, wherein the porous conductive surface has a thickness greater than 2.5 mm.

19. An array of cells as defined in claim 17, wherein each of said bipolar electrodes further comprises a non-woven screen provided between said porous conductive surface and an adjacent cation exchange membrane so as to restrain said porous conductive surface.

20. An array of cells as defined in claim 1, wherein said end +^ve electrode comprises a porous conductive surface.

21. An array of cells as defined in claim 1, wherein said end -^ve electrode and the -^ve side of each bipolar electrode comprises a porous conductive surface.