Moisture-curable silicone pressure sensitive adhesives

• US 5,545,700 A
• Filed: 01/10/1994
• Issued: 08/13/1996
• Est. Priority Date: 01/10/1994
• Status: Expired due to Fees

• Current Assignee: Dow, Inc., Kinetic Rehabilitation Instruments Incorporated
• Original Assignee: Dow, Inc.
• Inventors: Brady, William P., Mealey, Shawn K., Schmidt, Randall G.
• Primary Examiner(s): MOORE, MARGARET G
• Application Number:
  US08/179,417
• Time in Patent Office: 946 Days
• Field of Search: 525/478, 525/477
• US Class Current: 525/478
• CPC Class Codes: C08G 77/12 containing silicon bound to hydrogen C08G77/045 takes precedence
• CPC Class Codes: C08G 77/16 to hydroxyl groups
• CPC Class Codes: C08G 77/20 containing silicon bound to unsaturated aliphatic groups C08G77/045 takes precedence
• CPC Class Codes: C08G 77/70 Siloxanes defined by use of the MDTQ nomenclature
• CPC Class Codes: C08L 2666/44 Silicon-containing compounds
• CPC Class Codes: C08L 83/00 Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 83/04 Polysiloxanes
• CPC Class Codes: C09J 183/04 Polysiloxanes

Abstract

Silicone pressure sensitive adhesive compositions which cure in the presence of moisture comprise an adhesive component which bears alkoxy radical-containing curing radicals and, optionally, a catalyst to accelerate the reaction of moisture with the alkoxy radicals to form siloxane bonds. Curing provides adhesives ranging from pressure sensitive adhesives having improved properties to permanent adhesives. The adhesives are useful for adhering an object to a surface and thereafter improving the bond between the object and the surface by exposure to moisture.

Claims

1. A pressure sensitive adhesive composition produced by thermally curing a composition comprising:

(A) 50 to 80 parts of a benzene soluble, capped, organopolysiloxane resin consisting essentially of R₃ SiO_1/2 siloxane units and SiO_4/2 siloxane units, wherein R is selected from the group consisting of alkyl radicals having 1 to 10 carbon atoms and aryl radicals having from 6 to 10 carbon atoms;

there being from 0.5 to 1.5 R₃ SiO_1/2 units for every SiO_4/2 units and containing less than 1 weight percent silicon-bonded hydroxyl groups based on the total weight of (A),

(B) 20 to 50 parts of an alkenyl functional polydiorganosiloxane polymer having the general formula R¹₂ R² SiO(R²₂ SiO)_n SiR² R¹₂ wherein each R¹ individually is a radical selected from the group consisting of methyl, ethyl, propyl and phenyl, each R² individually is selected from the group consisting of an alkenyl radical and R¹, as defined above, with the proviso that at least two R² radicals per molecule must be alkenyl; and

n has a value such that the viscosity of (B) is from 100,000 centipoise to 10,000,000 centipoise at 25°

C., the amount of (A) and (B) being 100 parts;

(C) a organohydrogenpolysiloxane compound having an average of at least 3 silicon-bonded hydrogen atoms per molecule;

the amount of (C) present being sufficient to provide from 1 to 30 silicon bonded hydrogen atoms for every olefinically unsaturated radical in the total of (A) plus (B),

(D) 0.5 to 10 parts per 100 parts of (A) and (B) of an alkenetrialkoxysilane having the general formula R³ Si(OR⁴)₃ wherein R³ is an alkenyl group and R⁴ is an alkyl group having from 1 to 4 carbon atoms;

(E) a platinum containing catalyst in sufficient quantity to provide at least 0.1 to 1,000 parts of platinum for every one million parts of (A) through (D), and

(F) 0.5 to 10 parts per 100 parts of (A) and (B) of a moisture curing catalyst in an amount suitable to promote a moisture-initiated reaction of the alkoxy radicals of (D)

wherein said pressure sensitive adhesive is capable of further curing in the presence of moisture.

2. The composition as claimed in claim 1 wherein component (A) consists essentially of (CH₃)₃ SiO_1/2 siloxane units and SiO_4/2 siloxane units.

3. The composition as claimed in claim 1 wherein in component (A) the ratio of R₃ SiO_1/2 units to every SiO_4/2 units is from 0.5 to 1.0.

4. The composition as claimed in claim 1 wherein in component (A) the ratio of R₃ SiO_1/2 units to every SiO_4/2 units is from 1.1 to 1.5.

5. The composition as claimed in claim 1 wherein the resin contains less than 0.6 wt percent silicon-bonded hydroxyl groups based on the total weight of (A).

6. The composition as claimed in claim 1 wherein component (B) has a viscosity of from 1,000,000 to 10,000,000 centipoise at 25°

C.

7. The composition as claimed in claim 1 wherein in component (B) at least 90% of all R¹ radicals are methyl.

8. A composition as claimed in claim 1 wherein the organohydrogenpolysiloxane (C) is a dimethyl-methylhydrogenpolysiloxane copolymer.

9. A composition as claimed in claim 8 wherein the dimethyl-methylhydrogenpolysiloxane copolymer is a linear dimethyl-methylhydrogenpolysiloxane copolymer.

10. A composition as claimed in claim 1 wherein component (D) is a vinyltrialkoxysilane.

11. A composition as claimed in claim 10 wherein the vinyltrialkoxysilane is vinyltrimethoxysilane.

12. A composition as claimed in claim 1 wherein the platinum containing catalyst (E) is a chloroplatinic acid-vinylsiloxane complex.

13. A composition as claimed in claim 1 wherein component (F) is dibutyltin dilaurate.

14. A composition as claimed in claim 1 further comprising a platinum catalyst inhibitor.