Radiation-emitting semiconductor diode and method of manufacturing same

• US 5,545,903 A
• Filed: 06/27/1994
• Issued: 08/13/1996
• Est. Priority Date: 06/28/1993
• Status: Expired due to Term

• Current Assignee: Viavi Solutions, Inc. (Lumentum Holdings Inc.)
• Original Assignee: US Philips Corporation (Koninklijke Philips N.V.)
• Inventors: Ambrosius, Hubertus P. M. M., Valster, Adriaan, Van Der Poel, Carolus J.
• Primary Examiner(s): Monin, Jr., Donald L.
• Application Number:
  US08/266,043
• Time in Patent Office: 778 Days
• Field of Search: 372/45, 372/46, 372/47, 372/43, 257/13, 257/14
• US Class Current: 257/14
• CPC Class Codes: B82Y 20/00 Nanooptics, e.g. quantum optics or photonic crystals
• CPC Class Codes: H01S 5/3211 characterised by special cladding layers, e.g. details on band-discontinuities
• CPC Class Codes: H01S 5/32308 emitting light at a wavelength less than 900 nm
• CPC Class Codes: H01S 5/32316 comprising only (Al)GaAs
• CPC Class Codes: H01S 5/343 in AIIIBV compounds, e.g. AlGaAs-laser , InP-based laser
• CPC Class Codes: H01S 5/34313 with a well layer having only As as V-compound, e.g. AlGaAs, InGaAs
• CPC Class Codes: H01S 5/3432 the whole junction comprising only (AI)GaAs

Abstract

Radiation-emitting semiconductor diodes are used as laser diodes or LEDs inter alia in optical disc systems, laser printers and bar code readers. The emission wavelength in these cases lies preferably in the visible range of the spectrum. Known diodes have an active layer (3A) and cladding layers (2, 4) which comprise either AlGaAs or InAlGaP. These known diodes have the disadvantage that they do not cover a portion of the visible spectrum between 880 and 600 nm.

A diode according to the invention is characterized in that the active layer (3A) comprises Al_x Ga_l-x As and the cladding layers (2, 4) comprise Al_y Ga_w In_l-y-w P, while the active layer (3A) has such an aluminjure content (x) and such a thickness (d) that the wavelength of the photoluminescence emission lies between approximately 770 and 690 nm. This results in the availability of (laser) diodes covering the entire spectrum from approximately 880 nm to 600 nm which operate satisfactorily, supply a high power, and are easy to manufacture. Preferably, the active layer comprises a (multiple) quantum well structure of alternating quantum well layers and barrier layers, both comprising AlGaAs, but with different aluminium contents.

Claims

1. A radiation-emitting semiconductor diode comprising a semiconductor body with a semiconductor substrate (1) of a first conductivity type on which a semiconductor layer structure is present which comprises in that order at least a first cladding layer (2) of the first conductivity type, an active layer (3A) which emits in the visible range of the spectrum, and a second cladding layer (4) of a second conductivity type opposite to the first, while the first and the second cladding layer (2, 4) are provided with means (5, 6, 7, 8) for electrical connection, characterized in that the active layer (3A) comprises Al_x Ga_l-x As, the cladding layers (2, 4) comprise Al_y Ga_w In_l-y-w P, and the active layer (3A) has an aluminium content (x) and a thickness (d) such that the wavelength of the photoluminescence emission lies between approximately 770 and 690 nm.

2. A radiation-emitting semiconductor diode as claimed in claim 1, characterized in that the aluminium content (x) of the active layer (3A) is at least approximately 14.8 at. %, while the thickness (d) of the active layer (3A) is at least approximately 20 nm.

3. A radiation-emitting semiconductor diode as claimed in claim 1, characterized in that the aluminium content (x) of the active layer (3A) is at least approximately 18.0 at. % and the thickness of the active layer (3A) is at least approximately 20 nm.

4. A radiation-emitting semiconductor diode as claimed in claim 1, characterized in that the aluminium content (x) of the active layer (3A) is at least approximately 1 at. % and at most approximately 15 at. %, the active layer (3A) has a quantum well structure, and the thickness of a quantum well is approximately 2.5 nm.

5. A radiation-emitting semiconductor diode as claimed in claim 1, characterized in that the aluminium content (x) of the active layer (3A) is at least approximately 5 at. % and at most approximately 20 at. %, the active layer (3A) has a quantum well structure, and the thickness of a quantum well is at least approximately 4 nm.

6. A radiation-emitting semiconductor diode as claimed in claim 4, characterized in that the active layer (3A) has a multiple quantum well structure with at least four quantum well layers of Al_x Ga_l-x As with the said aluminium content (x) and the said thickness (d), which are mutually separated by barrier layers of Al_z Ga_l-z with a bandgap which is at least 200 meV greater than the bandgap corresponding to that of the emission wavelength and with a thickness of between 4 and 50 nm.

7. A radiation-emitting semiconductor diode as claimed in claim 4, characterized in that separate cladding layers (3B) of Al_z Ga_l-z As with a bandgap which is at least 200 meV greater than the bandgap corresponding to that of the emission wavelength and with a thickness of between approximately 5 and 150 nm are present between the active layer (3A) and the cladding layers (2, 4).

8. A radiation-emitting semiconductor diode as claimed in claim 4, characterized in that the active layer (3A) also comprises phosphorus and the phosphorus content is at most approximately 30 at. %.

9. A radiation-emitting semiconductor diode as claimed in claim 1, characterized in that the thickness of the active layer is smaller than approximately 0.05 μ

m.

10. A radiation-emitting semiconductor diode as claimed in claim 1, characterized in that the surface area of the active region lies between 25×

500 μ

m² and 100×

500 μ

m².

11. A radiation-emitting semiconductor diode as claimed in claim 1, characterized in that the aluminium content (y) of the separate cladding layers (3B) is at most approximately 35 at. % and the indium content (w) is approximately 50 at. %.

12. A method of manufacturing a radiation-emitting semiconductor diode whereby on a semiconductor substrate are provided in that order:

a first cladding layer (2) of a first conductivity type, an active layer (3A) of material which emits in the visible range of the emission spectrum, and a second cladding layer (4) of a second conductivity type opposed to the first, after which the cladding layers (2,

     4) are provided with means (5, 6, 7,

     8) for electrical connection, characterized in that Al_x Ga_l-x As is chosen for the semiconductor material of the active layer (3A) and Al_y Ga_w In_l-y-w P is chosen for the semiconductor material of the cladding layers (2,

     4), while the aluminium content (x) and the thickness (d) of the active layer (3A) are so chosen that the emission wavelength lies between approximately 770 and 690 nm.