Fuser roll

• US 5,547,742 A
• Filed: 07/05/1994
• Issued: 08/20/1996
• Est. Priority Date: 07/05/1993
• Status: Expired due to Term

• Current Assignee: Shin-Etsu Chemical Company Limited
• Original Assignee: Shin-Etsu Chemical Company Limited
• Inventors: Satoh, Makoto, Okami, Takehide, Shimamoto, Noboru
• Primary Examiner(s): Thibodeau, Paul
• Assistant Examiner(s): Chen, Vivian
• Application Number:
  US08/266,854
• Time in Patent Office: 777 Days
• Field of Search: 428/421, 428/422, 428/446, 428/447, 428/450, 428/451, 428/461, 428/462, 428/425.8, 556/451, 556/476, 556/478, 556/485, 556/487, 556/488, 106/287.13, 106/287.14, 106/287.15, 106/287.16, 528/15, 528/24, 528/31, 528/32, 528/36, 528/42, 525/102, 525/104, 492/53, 492/56, 492/59
• US Class Current: 428/215
• CPC Class Codes: B32B 1/00 Layered products having a non-planar shape
• CPC Class Codes: B32B 2307/718 Weight, e.g. weight per square meter
• CPC Class Codes: B32B 25/042 of natural rubber or synthetic rubber
• CPC Class Codes: B32B 25/20 comprising silicone rubber
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 83/08 containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
• CPC Class Codes: G03G 15/2057 relating to the chemical composition of the heat element and layers thereof
• CPC Class Codes: Y10T 428/24967 Absolute thicknesses specified
• CPC Class Codes: Y10T 428/26 Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
• CPC Class Codes: Y10T 428/269 including synthetic resin or polymer layer or component
• CPC Class Codes: Y10T 428/3154 Of fluorinated addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31544 Addition polymer is perhalogenated
• CPC Class Codes: Y10T 428/31663 As siloxane, silicone or silane
• CPC Class Codes: Y10T 428/31667 Next to addition polymer from unsaturated monomers, or aldehyde or ketone condensation product

Abstract

A fuser roll having a metal core shaft has a resilient layer placed around the metal core shaft with at least the surface layer of the resilient layer comprising a fluorosilicone rubber layer containing 5 to 50 wt. % polytetrafluoroethylene. Since this fuser roll is excellent in releasability and silicone oil resistance, the durability is excellent, and the image obtained by a copying machine wherein the roll is used becomes sharp.

Claims

1. A fuser roll having a metal core shaft and a resilient layer placed around said metal core shaft wherein at least the surface layer part of said resilient layer comprises a fluorosilicone rubber containing 20 to 40 wt. % of fluororesin;

polytetrafluoroethylene;

wherein fluorosilicone rubber is produced by curing a fluorosilicone rubber composition comprising (A) an organopolysiloxane;

(B) a filler;

(C) polytetrafluoroethylene; and

(D) a curing agent; and

wherein said organopolysiloxane (A) has the formula (1);

##STR14## wherein R¹ and R², which may be the same or different, each represent a monovalent hydrocarbon group having no aliphatic unsaturated bonds and is selected from the group consisting of alkyl, cycloalkyl, aryl, aralkyl and cyanoalkyl, R³ is a monovalent aliphatic unsaturated hydrocarbon group, R⁴ represents a single bond or a bivalent hydrocarbon group having no atiphatic unsaturated groups, R_f represents a fluorine-containing organic group, X represents a hydrogen atom or a group represented by the following general formula (2);

##STR15## where R⁷, R⁸ and R⁹ are each a monovalent hydrocarbon group, k and m are each an integer of zero or more, and 1 is an integer of one or more, provided that 0.5≦

l/(k+l+m)≦

one and wherein said organopolysiloxane (A) contains at least one silicon-bonded alkenyl group and has a viscosity at 25°

C. in the range of 100 to 10,000,000 cSt.

2. A fuser roll as claimed in claim 1, wherein the thickness of said resilient layer is 0.5 to 20 mm and the thickness of said fluorosilicone rubber at at least the surface layer part of said resilient layer is at least 0.5 mm.

3. A fuser roll as claimed in claim 1, wherein said resilient layer consists essentially of said fluorosilicone rubber layer containing said fluororesin.

4. A fuser roll as claimed in claim 1, wherein the resilient layer further comprises an inner layer adjacent to said metal core shaft wherein the inner layer is selected from the group consisting of a styrene/butadiene rubber, an ethylene/propylene rubber, a urethane rubber, and a silicone rubber.

5. A fuser roll as claimed in claim 1, wherein said filler (B) comprises one selected from the group consisting of fumed silica, precipitated silica, carbon powder, titanium dioxide, aluminum oxide, quartz powder, talc, sericite, bentonite, asbestos, glass fiber, and organic fiber.

6. A fuser roll as claimed in claim 1 wherein said filler (B) is blended in an amount of 10 to 300 parts by weight per 100 parts by weight of said organopolysiloxane (A).

7. A fuser roll as claimed in claim 1, wherein said curing agent (D) is an organic peroxide.

8. A fuser roll as claimed in claim 7, wherein the amount of said organic peroxide is 0.2 to 5 parts per 100 parts by weight of the organopolysiloxane (A).

9. A fuser roll as claimed in claim 1, wherein said curing agent (D) is an organohydrogenpolysiloxane having at least two silicon-bonded hydrogen atoms in the molecule.

10. A fuser roll as claimed in claim 12, wherein said organohydrogenpolysiloxane is contained in an amount such that the number of the SiH groups contained therein is at least 0.5 per aliphatic unsaturated hydrocarbon group in the organopolysiloxane (A).

11. A fuser roll as claimed in claim 9, wherein said fluorosilicone rubber composition further comprises a catalyst selected from the group consisting of platinum, palladium and rhodium catalysts.

12. A fuser roll as claimed in claim 11, wherein said catalyst is present in an amount of 1 to 500 ppm by weight, based on the organopolysiloxane (A).

13. (Amended) A fuser roll as claimed in claim 1, wherein said curing agent (D) is an organohydrogenpolysiloxane represented by the formula (3):

##STR16## wherein R², R⁴, and R_f have the same meanings as defined in claim 1, s and t are each an integer of zero or more, and u is an integer of two or more.