Precisely shaped particles and method of making the same

• US 5,549,962 A
• Filed: 06/30/1993
• Issued: 08/27/1996
• Est. Priority Date: 06/30/1993
• Status: Expired due to Term

• Current Assignee: 3M Company
• Original Assignee: 3M Company
• Inventors: Studiner, Charles J. III, Klun, Thomas P., Hendrickson, William A., Culler, Scott R., Spurgeon, Kathryn M., Harmon, Kimberly K., Hardy, David H., Heiti, Robert V., Holmes, Gary L.
• Primary Examiner(s): Raimund, Christopher W.
• Application Number:
  US08/085,638
• Time in Patent Office: 1,154 Days
• Field of Search: 428/144, 428/148, 428/149, 428/283, 428/288, 428/290, 428/402, 428/143, 51/293, 51/298
• US Class Current: 428/144
• CPC Class Codes: B24D 11/00 Constructional features of flexible abrasive materials; Special features in the manufacture of such materials
• CPC Class Codes: B24D 18/00 Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for
• CPC Class Codes: B24D 3/28 Resins or natural or synthetic macromolecular compounds B24D3/22 takes precedence
• CPC Class Codes: C09K 3/1409 Abrasive particles per se preparation of diamond C01B32/25
• CPC Class Codes: Y10T 428/24372 Particulate matter
• CPC Class Codes: Y10T 428/2438 Coated
• CPC Class Codes: Y10T 428/24405 Polymer or resin [e.g., natural or synthetic rubber, etc.]
• CPC Class Codes: Y10T 428/24413 Metal or metal compound
• CPC Class Codes: Y10T 428/24421 Silicon containing
• CPC Class Codes: Y10T 428/2982 Particulate matter [e.g., sphere, flake, etc.]
• CPC Class Codes: Y10T 428/2991 Coated
• CPC Class Codes: Y10T 428/2998 including synthetic resin or polymer
• CPC Class Codes: Y10T 442/198 Coated or impregnated
• CPC Class Codes: Y10T 442/2115 At least one coating or impregnation functions to fix pigments or particles on the surface of a coating or impregnation

Abstract

A coated abrasive article comprising:

(a) a backing;

(b) at least one layer comprising a plurality of precisely shaped abrasive particles that comprise abrasive grits and a free-radically polymerized binder, wherein said precisely shaped particles have vertexes and

(c) a bonding medium which serves to adhere said precisely shaped particles to said backing;

wherein the precisely shaped particles are randomly disposed on the backing such that at least a portion of said particles are oriented with said vertexes pointing toward said backing.

Claims

1. A coated abrasive article comprising:

(a) a backing;

(b) at least one layer comprising a plurality of precisely shaped abrasive composites that comprise abrasive grits and a binder formed from a free radically polymerizable binder precursor, wherein said precisely shaped composites have vertexes, and wherein the precisely shaped composites are randomly disposed on the backing such that at least a portion of said particles are oriented with said vertexes point toward said backing;

(c) a bonding medium which serves to adhere said precisely shaped particles to said backing.

2. A coated abrasive article according to claim 1, wherein said backing is selected from the group consisting of paper, nonwoven substrates, polymeric film, primed polymeric film, cloth, vulcanized fiber, and combinations thereof.

3. A coated abrasive article according to claim 1, wherein said abrasive grits are selected from the group consisting of fused aluminum oxide, ceramic aluminum oxide, heat treated aluminum oxide, silicon carbide, alumina zirconia, diamond, ceria, cubic boron nitride, garnet, and combinations thereof.

4. A coated abrasive article according to claim 1, wherein the size of said precisely shaped composites ranges from about 0.1 to about 2500 micrometers.

5. A coated abrasive article according to claim 1, wherein the size of said precisely shaped composites ranges from about 0.1 to about 500 micrometers.

6. A coated abrasive article according to claim 1, wherein said precisely shaped composites have shapes selected from the group consisting of pyramids, cones, and prisms.

7. A coated abrasive article according to claim 1, wherein said precisely shaped composites are triangular-based pyramids.

8. A coated abrasive article according to claim 1, wherein said precisely shaped composites are quadrilateral-based pyramids.

9. A coated abrasive article according to claim 1, wherein said binder precursor is selected from the group consisting of acrylated urethane resins, ethylenically unsaturated resins, aminoplast resins having pendant unsaturated carbonyl groups, isocyanurate derivatives having at least one pendant acrylate group, and isocyanate derivatives having at least one pendant acrylate group.

10. A coated abrasive article according to claim 1, wherein said binder precursor further comprises a free radical initiator.

11. A coated abrasive article according to claim 1, wherein said precisely shaped composites further comprise at least one additive selected from the group consisting of fillers, grinding aids, fibers, antistatic agents, lubricants, wetting agents, surfactants, pigments, dyes, coupling agents, plasticizers, and suspending agents.

12. A coated abrasive article according to claim 1, wherein said precisely shaped composites comprise from 5 to 95% by weight abrasive grits and from 95 to 5% by weight binder.

13. A coated abrasive article according to claim 1, wherein said precisely shaped composites comprise from 20 to 75% by weight abrasive grits and from 80 to 25% by weight binder.

14. A coated abrasive article according to claim 1, wherein said bonding medium comprises a resinous adhesive.

15. A coated abrasive article according to claim 14, wherein said resinous adhesive is selected from the group consisting of phenolic resins, epoxy resins, urea-formaldehyde resins, acrylate resins, acrylated epoxy resins, acrylated urethane resins, aminoplast resins having pendant alpha, beta unsaturated carbonyl groups, maleimide resins, and urethane resins.

16. A coated abrasive article according to claim 1, further comprising individual abrasive grits bonded to said backing by means of said bonding medium.

17. A coated abrasive article according to claim 16, wherein said individual abrasive grits are disposed over said precisely shaped composites.

18. A coated abrasive article according to claim 16, wherein said individual abrasive grits are disposed underneath said precisely shaped composites.

19. A coated abrasive article according to claim 16, wherein said individual abrasive grits are disposed between said precisely shaped composites.

20. A coated abrasive article according to claim 16, wherein said individual abrasive grits are precisely shaped.

21. A coated abrasive article according to claim 16, further comprising a second bonding medium applied over said precisely shaped composites and said individual abrasive grits.

22. A coated abrasive article according to claim 1, wherein at least a portion of said composites are oriented such that said vertexes point away from said backing.