Electrochemical capacitor having a proton conducting solid electrolyte

• US 5,549,989 A
• Filed: 12/20/1993
• Issued: 08/27/1996
• Est. Priority Date: 12/20/1993
• Status: Expired due to Term

• Current Assignee: Google Technology Holdings LLC (Alphabet Inc.)
• Original Assignee: Motorola, Inc. (Motorola Solutions, Inc.)
• Inventors: Anani, Anaba A.
• Primary Examiner(s): Fourson, George
• Assistant Examiner(s): EVERHART, CARIDAD
• Application Number:
  US08/169,231
• Time in Patent Office: 981 Days
• Field of Search: 429/193, 429/191, 429/218
• US Class Current: 429/306
• CPC Class Codes: H01G 9/022 Electrolytes; Absorbents
• CPC Class Codes: H01M 10/0562 Solid materials
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02E 60/13 Energy storage using capacitors

Abstract

An electrochemical capacitor (10) stores an electrical charge from an external source (40). The capacitor has a positive electrode (30) and a negative electrode, each electrode being a metal oxide. A solid, protonically-conducting electrolyte (25 ) is disposed between the positive and negative electrodes and is in contact with each electrode. The electrochemical capacitor stores the electrical charge by changing the oxidation state of the metal oxide, oxidizing the metal at the positive electrode and reducing the metal at the negative electrode. The solid electrolyte is pseudoboehmite, tetramethyl ammonium hydrate, or Li₅ AlO₄. The electrodes are transition metals capable of forming multiple oxides, but not capable of forming metal hydrides.

Claims

1. An electrochemical capacitor for storing an electrical charge from an external source, comprising:

a positive electrode and a negative electrode, each comprising a metal oxide;

a solid, protonically-conducting electrolyte disposed between the positive and negative electrodes and in contact with each electrode, said solid protonically-conducting electrolyte selected from the group consisting of pseudoboehmite, tetramethyl ammonium pentahydrate, Li₅ AlO₄, and combinations thereof; and

the electrochemical capacitor capable of storing the electrical charge by changing the oxidation state of the metal oxide.

2. The electrochemical capacitor as described in claim 1, wherein the electrodes are not capable of forming the electrical charge by forming a metal hydride.

3. The electrochemical capacitor as described in claim 1, wherein the metal oxide comprises an oxide of a transition metal element.

4. The electrochemical capacitor as described in claim 3, wherein the metal oxide comprises an oxide of one or more metals selected from the group consisting of ruthenium, rhenium, and tungsten.

5. An electrochemical capacitor for storing an electrical charge provided by an external source, comprising:

a positive electrode comprising a first metal oxide species;

a negative electrode comprising a second metal oxide species;

a boehmite electrolyte disposed between the positive and negative electrodes and in contact with each electrode; and

the electrochemical capacitor capable of storing the electrical charge by reducing the metal at one electrode to form a third metal oxide species and oxidizing the metal at the other electrode to form a fourth metal oxide species.

6. The electrochemical capacitor as described in claim 5, wherein the electrodes are not capable of forming the electrical charge by forming a metal hydride.

7. The electrochemical capacitor as described in claim 5, wherein the metal oxide comprises an oxide of a transition metal element.

8. The electrochemical capacitor as described in claim 7, wherein the metal oxide comprises an oxide of one or more metals selected from the group consisting of ruthenium, rhenium, and tungsten.

9. A method for storing electrical charge in an electrochemical capacitor having two metal oxide electrodes and a protonically-conducting electrolyte disposed between and in contact with each electrode, comprising:

providing said electrolyte as fabricated from the group consisting of pseudoboehmite, tetramethyl ammonium pentahydrate, and Li₅ AlO₄ ;

providing a source of electrical energy to the electrochemical capacitor;

oxidizing the metal at the positive electrode to form a different metal oxide;

transporting a hydrogen ion across the electrolyte; and

reducing the metal at the negative electrode to form a different metal oxide.

10. The method of storing charge as described in claim 9, wherein the step of oxidizing the metal and the step of reducing the metal both comprise not forming a metal hydride.

11. The method of storing charge as described in claim 9, wherein the step of oxidizing the metal comprises oxidizing a transition metal.

12. An energy storage device for a communication device, comprising:

an energy storage device electrically connected to the radio receiver, the energy storage device comprising;

a positive electrode and a negative electrode, each comprising a metal oxide;

a solid, protonically-conducting electrolyte disposed between the positive and negative electrodes and in contact with each electrode, said solid protonically-conducting electrolyte selected from the group consisting of pseudoboehmite, tetramethyl ammonium pentahydrate, Li₅ AlO₄, and combinations thereof; and

the energy storage device capable of storing the electrical charge by changing the oxidation state of the metal oxide.

13. A method for storing electrical charge in an electrochemical capacitor having two electrodes, each electrode comprising an oxide of a metal selected from the group consisting of ruthenium, rhenium, and tungsten, and having a protonically-conducting electrolyte selected from the group consisting of pseudoboehmite, tetramethyl ammonium pentahydrate, and Li₅ AlO₄ disposed between and in contact with each electrode, the method comprising the steps of:

providing a source of electrical energy to the electrochemical capacitor;

oxidizing the metal at the positive electrode to form a different metal oxide;

transporting a hydrogen ion across the electrolyte; and

reducing the metal at the negative electrode to form a different metal oxide.