Process for the preparation of alcohols or amines
First Claim
1. A process for the hydrogenation of a compound selected from the class consisting of esters, fatty acids, and nitriles to form corresponding alcohols or amines, said process comprising a reaction of said compound with hydrogen at elevated pressure and elevated temperature in the presence of a catalyst which contains CuO,said catalyst, in its unreduced state, comprising, per 100 parts of said CuO, 40 to 130 parts by weight of ZnO, 2 to 50 parts by weight of Al2 O3, said catalyst having a BET total area of 80 to 175 m2 /g, 75% to 95% of said total area constituting pores having radii rp ≦
- 15 nm.
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Abstract
A process for catalytic preparation of alcohols or amines by reaction of esters, fatty acids, or nitriles with hydrogen at elevated temperature and pressure. The unreduced catalyst contains, per 100 parts by weight of CuO, 40 to 130 parts by weight of ZnO, 2 to 50 parts by weight of Al2 O3, and optionally 0.5 to 8 parts by weight of oxide of Mn, Mo, V, Zr, and/or alkaline earth metal. It has a BET total area of 80 to 175 m2 /g of catalyst in the unreduced state, and 75% to 95% of the BET total area is formed by pores having a radius rp ≦15 nm.
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16 Claims
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1. A process for the hydrogenation of a compound selected from the class consisting of esters, fatty acids, and nitriles to form corresponding alcohols or amines, said process comprising a reaction of said compound with hydrogen at elevated pressure and elevated temperature in the presence of a catalyst which contains CuO,
said catalyst, in its unreduced state, comprising, per 100 parts of said CuO, 40 to 130 parts by weight of ZnO, 2 to 50 parts by weight of Al2 O3, said catalyst having a BET total area of 80 to 175 m2 /g, 75% to 95% of said total area constituting pores having radii rp ≦
Specification