Abrasive grain containing alumina and zirconia

• US 5,551,963 A
• Filed: 11/06/1995
• Issued: 09/03/1996
• Est. Priority Date: 09/25/1992
• Status: Expired due to Term

• Current Assignee: 3M Company
• Original Assignee: 3M Company
• Inventors: Larmie, Henry A.
• Primary Examiner(s): JONES, DEBORAH D
• Application Number:
  US08/554,033
• Time in Patent Office: 302 Days
• Field of Search: 51/293, 51/307, 51/309
• US Class Current: 51/307
• CPC Class Codes: B24D 11/00 Constructional features of flexible abrasive materials; Special features in the manufacture of such materials
• CPC Class Codes: B24D 3/14 ceramic, i.e. vitrified bondings
• CPC Class Codes: B24D 5/12 Cut-off wheels
• CPC Class Codes: C04B 35/119 with zirconium oxide
• CPC Class Codes: C04B 35/622 Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
• CPC Class Codes: C09K 3/1418 obtained by division of a mass agglomerated by sintering

Abstract

A method of preparing preferred abrasive grain includes: preparing a dispersion including alpha alumina oxide monohydrate and zirconia sol therein; converting the dispersion to base grit material; and sintering the base grit to form abrasive grains. The presence of the zirconia sol within the dispersion from which the base grits are formed provides an improved abrasive grain. The improved abrasive grain are useful in abrasive products.

Claims

1. A method of preparing abrasive grain material;

said method comprising the steps of;

(a) preparing a dispersion of alumina hydrate and zirconia particles, wherein at least about 97% by weight of said zirconia particles are less than about 0.2 micrometer in size;

(b) forming alumina base grits from said dispersion; and

(c) sintering said alumina base grits to provide abrasive grain comprising about 70 to about 99.9 percent by weight alumina and at least about 0.1 percent by weight zirconia, based on the total weight of said abrasive grain, said alumina being present as one of alpha alumina, alumina reaction product, or a combination thereof, said zirconia being present as one of zirconia or zirconia and zirconia reaction product,

with the proviso that said zirconia particles are present in said dispersion in an amount sufficient to increase densification of said abrasive grain of step (c) as compared to an abrasive grain made according to steps (a), (b), and (c) without the presence of zirconia in said abrasive grain.

2. A method according to claim 1 wherein said dispersion is aqueous dispersion, and further comprises the step of calcining said alumina base grits of step (b) before said sintering of step (c).

3. A method according to claim 2 wherein said dispersion contains a sufficient amount of said zirconia particles therein such that said abrasive grain of step (c) comprises between about 0.1% and about 30% by weight zirconia.

4. A method according to claim 2 wherein said dispersion comprises about 15 to about 40% by weight colloidal zirconia particles of which about 50% by weight are less than about 0.05 micrometer in size.

5. A method according to claim 2 wherein said aqueous dispersion comprises about 30 to about 80% by weight water.

6. A method according to claim 2 wherein said aqueous dispersion further comprises a nucleating material.

7. A method according to claim 2 wherein said aqueous dispersion further comprises a metal oxide precursor.

8. A method according to claim 2 including a step of impregnating said calcined alumina base grits with metal oxide precursor prior to said step of sintering.

9. A method according to claim 8 wherein said metal oxide precursor is a precursor of an oxide selected from the group consisting of yttria, magnesium oxide, and a rare earth oxide;

wherein said metal oxide precursor is present in an amount sufficient to provide abrasive grain of step (c) with at least about 0.5% by weight of at least one metal oxide, said metal oxide being present as one of a metal oxide, metal oxide reaction product, or a combination thereof,

(i) said rare earth oxide being selected from the group consisting of oxides of;

praseodymium, samarium, ytterbium, neodymium, lanthanum, gadolinium, cerium, dysprosium, erbium, and mixtures thereof; and

(ii) each of said yttria, magnesium oxide, and rare earth oxide, if present in said abrasive grain of step (c), being present up to about 10% by weight;

and wherein said abrasive grain of step (c) comprises about 70 to about 95 percent by weight alumina and about 0.1 to about 15 percent by weight zirconia.

10. A method according to claim 9 wherein said yttria precursor is present in an amount sufficient to provide abrasive grain with about 0.5 to about 10% yttria.

11. A method according to claim 10 wherein said magnesium oxide precursor is present in an amount sufficient to provide said abrasive grain with about 0.5 to about 1.5% by weight magnesium oxide;

and said rare earth oxide precursor is present in an amount sufficient to provide said abrasive grain with about 0.5 to about 5% by weight rare earth oxide.

12. A method according to claim 2 including a step of coating at least one of said alumina base grits and said calcined alumina base grits with a material selected from the group consisting of metal oxides, precursors thereof, and combinations thereof, prior to said step of sintering, said sintered abrasive grain comprising a sintered core and a metal oxide coating.

13. A method according to claim 2 wherein said dispersion further comprises a metal oxide precursor of an oxide selected from the group consisting of yttria, magnesium oxide, and a rare earth oxide;

wherein said metal oxide precursor is present in an amount sufficient to provide abrasive grain of step (c) with at least about 0.5% by weight of at least one metal oxide, said metal oxide being present as one of a metal oxide, a metal oxide reaction product, or a combination thereof,

(i) said rare earth oxide being selected from the group consisting of oxides of;

praseodymium, samarium, ytterbium, neodymium, lanthanum, gadolinium, cerium, dysprosium, erbium, and mixtures thereof, and

(ii) each of said yttria, magnesium oxide, and rare earth oxide, if present in said abrasive grain of step (c), being present up to about 10% by weight;

and wherein said abrasive grain of step (c) comprises about 70 to about 95 percent by weight alumina and about 0.1 to about 15 percent by weight zirconia.

14. The method according to claim 1 wherein said abrasive grain of step (c) comprises about 70 to about 97 percent by weight alumina.

15. The method according to claim 1 wherein said abrasive grain of step (c) comprises about 70 to about 95 percent by weight alumina.

16. A sintered abrasive grain comprising alpha alumina, including alpha alumina domains comprised of alpha alumina crystallites, and about 0.05 to about 1 micrometer particles of zirconia, said particles of zirconia being substantially uniformly distributed throughout said abrasive grain, and a majority of said zirconia particles in said alpha alumina domains being randomly and uniformly distributed between said alpha alumina crystallites.

17. An abrasive grain according to claim 16 further comprising about 0.5 to about percent by weight yttria and about 0.3 to about 1.5 percent by weight magnesium oxide therein, said yttria being present as yttria reaction product, and said magnesium oxide being present as magnesium oxide reaction product.

18. An abrasive grain according to claim 16 comprising:

(a) about 70 to about 95% by weight alumina;

said alumina being present as one of said alpha alumina or said alpha alumina and an alumina reaction product;

(b) about 0.1 to about 15% by weight zirconia, said zirconia present being as one of said zirconia particles or zirconia particles and a zirconia reaction product;

(c) about 0.5 to about 1.5% by weight magnesium oxide, said magnesium oxide being present as a magnesium oxide reaction product; and

(d) about 0.1 to about 5% by weight of rare earth oxide selected from the group consisting of oxides of;

praseodymium, samarium, ytterbium, neodymium, lanthanum, gadolinium, cerium, dysprosium, erbium and mixtures thereof, said rare earth oxide being present as one of a rare earth oxide, a rare earth oxide reaction product, or a combination thereof.

19. An abrasive grain according to claim 18 including about 0.5 to about 10% by weight yttria, said yttria being present as a yttria reaction product.

20. An abrasive grain comprising a core and a surface coating of metal oxide thereon, said core being said abrasive grain according to claim 19.

21. An abrasive article including:

(a) a binder; and

(b) a plurality of abrasive grain according to claim 16 secured within said article by said binder.

22. An abrasive article according to claim 21 wherein said abrasive article is a grinding wheel.

23. An abrasive article according to claim 21 wherein said abrasive article is a cutoff wheel.

24. An abrasive article according to claim 21 wherein said abrasive article is a nonwoven abrasive product.

25. A coated abrasive article comprising:

(a) a backing having a major surface; and

(b) an abrasive layer comprising abrasive grain according to claim 21 secured to said major surface of said backing by a binder.