Process for the continuous preparation of nitrosyl chloride

• US 5,552,130 A
• Filed: 04/25/1995
• Issued: 09/03/1996
• Est. Priority Date: 05/02/1994
• Status: Expired due to Fees

• Current Assignee: Bayer AG
• Original Assignee: Bayer AG
• Inventors: Klausener, Alexander, Kraus, Helmut, Landscheidt, Heinz
• Primary Examiner(s): LANGEL, WAYNE A
• Application Number:
  US08/429,277
• Time in Patent Office: 497 Days
• Field of Search: 423/386, 423/659
• US Class Current: 423/386
• CPC Class Codes: C01B 21/0846 Nitrosyl chloride
• CPC Class Codes: C07D 213/61 Halogen atoms or nitro radicals
• CPC Class Codes: C07D 231/16 Halogen atoms or nitro radicals

Abstract

The reaction of nitrogen dioxide with hydrogen chloride to give nitrosyl chloride and nitric acid can be advantageously carried out in cocurrent in a reactor in such a way that the reactants are introduced at the bottom and the nitrosyl chloride is taken off at the top and the nitric acid is taken off at the bottom of the reactor.

Claims

1. A gas phase process for preparing pure nitrosyl chloride which consists essentially of continuously introducing hydrogen chloride and 0.4 to 1 times its molar amount of nitrogen dioxide at the bottom of a reactor, continuously taking off nitrosyl chloride from the top of the reactor, and continuously taking off nitric acid at the bottom of the reactor, the reaction being effected in the presence of little or no water.

2. The process according to claim 1, wherein the nitrogen dioxide is introduced in 0.4 to 0.8 times the molar amount of the hydrogen chloride.

3. The process according to claim 1, wherein the nitrogen dioxide is introduced in 0.5 to 0.7 times the molar amount of the hydrogen chloride.

4. The process according to claim 1, wherein the reaction mass is substantially free of water.

5. The process according to claim 4, wherein the nitrogen dioxide is introduced in 0.5 to 0.7 times the molar amount of the hydrogen chloride, and the hydrogen chloride and nitrogen dioxide are introduced in gaseous state.