All-polymeric cold mirror

• US 5,552,927 A
• Filed: 04/04/1994
• Issued: 09/03/1996
• Est. Priority Date: 10/16/1992
• Status: Expired due to Term

• Current Assignee: The Dow Chemical Company (Dow, Inc.)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Wheatly, John A., Motter, Gregg A.
• Primary Examiner(s): Lerner, Martin
• Application Number:
  US08/222,028
• Time in Patent Office: 883 Days
• Field of Search: 359/359, 359/360, 359/580, 359/584, 359/586, 359/588, 359/589, 428/213
• US Class Current: 359/359
• CPC Class Codes: G02B 1/04 made of organic materials, e.g. plastics G02B1/08 takes precedence
• CPC Class Codes: G02B 5/0841 comprising organic materials, e.g. polymers
• CPC Class Codes: G02B 5/0891 Ultraviolet [UV] mirrors apparatus for microlithography exposure G03F7/70; X-ray multilayer structures G21K1/06
• CPC Class Codes: G02B 5/206 comprising particles embedded in a solid matrix
• CPC Class Codes: G02B 5/208 for use with infrared or ultraviolet radiation, e.g. for separating visible light from infrared and/or ultraviolet radiation
• CPC Class Codes: G02B 5/26 Reflecting filters G02B5/28 takes precedence
• CPC Class Codes: G02B 5/287 comprising at least one layer of organic material

Abstract

An all-polymeric cold mirror which reflects visible wavelengths while transmitting a substantial portion of infrared wavelengths is provided. The mirror includes a sufficient number of alternating layers of at least first and second diverse polymeric materials such that at least 50% of peak reflecting visible light of a wavelength of between about 380-680 nm incident on the mirror is reflected and at least 50% of infrared light between about 680-2000 nm is transmitted or absorbed. The mirror may be designed so that it either reflects or absorbs ultraviolet light.

Claims

1. An all polymeric cold mirror of at least first and second diverse polymeric materials, the mirror comprising a sufficient number of alternating layers of said first and second polymeric materials such that at least 50% of light across the visible range of wavelengths between about 380-680 nm incident on said polyemric cold mirror is reflected and at least 80% of infrared light of wavelengths of between about 680-2000 nm is transmitted or absorbed, said alternating layers of said first and second polymeric materials having a layer thickness gradient across the thickness of said mirror.

2. The polymeric cold mirror of claim 1 wherein at least 50% of ultraviolet light between about 300-380 nm incident on said polymeric cold mirror is reflected.

3. The polymeric cold mirror of claim 1 wherein at least 50% of ultraviolet light between about 300-380 nm incident on said polymeric cold mirror is absorbed.

4. The polymeric cold mirror of claim 1 wherein a substantial majority of the individual layers of said mirror have optical thicknesses in the range where the sum of the optical thicknesses in a repeating unit of said polymeric materials is between about 190 nm to about 340 nm, and wherein said polymeric materials differ from each other in refractive index by at least about 0.03 in the wavelength range of from about 380-680 nm.

5. The polymeric cold mirror of claim 1 wherein said first polymeric material is polystyrene and said second polymeric material is polyethylene.

6. The polymeric cold mirror of claim 1 wherein said first polymeric material is polycarbonate and said second polymeric material is polymethyl methacrylate.

7. The polymeric cold mirror of claim 1 wherein said polymeric cold mirror comprises at least 200 layers.

8. The polymeric cold mirror of claim 1 wherein at least 80% of peak reflecting visible light of a wavelength of between about 380-680 nm incident on said polymeric cold mirror is reflected.

9. The polymeric cold mirror of claim 1 wherein at least 80% of infrared light between about 680-2000 nm incident on said polymeric cold mirror is transmitted.

10. The polymeric cold mirror of claim 1 wherein said mirror is laminated to or coextruded with a substrate material.

11. The polymeric cold mirror of claim 10 where said substrate material is selected from the group consisting of glass, metal, polycarbonate, polymethyl methacrylate, polyetherimide, and copolymers of gluterimide and methyl methacrylate.

12. The polymeric cold mirror of claim 1 wherein said mirror includes a protective skin layer on at least one major surface thereof.

13. The polymeric cold mirror of claim 12 wherein said protective skin layer is removable.

14. The polymeric cold mirror of claim 1 wherein said mirror is extruded as a profile.

15. The polymeric cold mirror of claim 1 wherein said mirror is post formed into a profile.

16. The polymeric cold mirror of claim 1 in which a coloring agent is incorporated into at least one layer of said mirror.

17. The polymeric cold mirror of claim 1 in which said coloring agent is selected from the group consisting of pigments and dyes.

18. The polymeric cold mirror of claim 1 in which said coloring agent is incorporated into at least one surface layer of said mirror.

19. The polymeric cold mirror of claim 1 in which said coloring agent is incorporated into at least one interior layer of said mirror.

20. The polymeric cold mirror of claim 1 in which said mirror is formed as a coatable composition from a multiplicity of mirror platelets in a liquid dispersion.

21. The polymeric cold mirror of claim 1 in which said mirror is formed from a multiplicity of mirror platelets which are embossed into the surface of a substrate.

22. The polymeric cold mirror of claim 1 in which said mirror is formed from a multiplicity of mirror platelets which are spread onto the surface of an adhesive substrate.

23. The polymeric cold mirror of claim 22 in which said mirror is formed from a multiplicity of mirror platelets which are spread onto the surface of a substrate and a transparent sheet is laminated over said mirror platelets.

24. The polymeric cold mirror of claim 1 in which said polymeric materials are elastomers.

25. The polymeric cold mirror of claim 1 in which at least one of the surfaces of said mirror is embossed or textured to diffuse light reflected or transmitted from said mirror.