Purification system

• US 5,554,300 A
• Filed: 02/22/1995
• Issued: 09/10/1996
• Est. Priority Date: 02/22/1995
• Status: Expired due to Term

• Current Assignee: Purifics Environmental Technologies Incorporated
• Original Assignee: Purifics Environmental Technologies Incorporated
• Inventors: Butters, Brian E., Powell, Anthony L.
• Primary Examiner(s): McCarthy, Neil
• Application Number:
  US08/394,548
• Time in Patent Office: 566 Days
• Field of Search: 210/748, 210/757, 210/763
• US Class Current: 210/748.14
• CPC Class Codes: A62D 2203/04 Combined processes involving two or more non-distinct steps covered by groups A62D3/10 - A62D3/40
• CPC Class Codes: A62D 3/176 Ultraviolet radiations, i.e. radiation having a wavelength of about 3nm to 400nm
• CPC Class Codes: A62D 3/37 by reduction, e.g. hydrogenation
• CPC Class Codes: A62D 3/38 by oxidation; by combustion
• CPC Class Codes: B01J 19/123 Ultraviolet light
• CPC Class Codes: C02F 1/32 with ultraviolet light
• CPC Class Codes: C02F 1/70 by reduction C02F1/4676 takes precedence
• CPC Class Codes: C02F 1/725 by catalytic oxidation
• CPC Class Codes: C02F 2305/10 Photocatalysts

Abstract

The present invention relates to a method for the purification of contaminated fluids by photocatalytic treatment. In accordance with the invention, an oxidation state where contaminant molecules are oxidized and/or a reduction state where contaminant molecules are reduced are employed to purify a contaminated fluid. The reduction state, where certain contaminant molecules are reduced, is induced by providing a reactant, such as citric acid, in the presence of an excited photocatalyst. A reduction state may alternate to an oxidation state, where contaminant molecules are oxidized, by the addition of an oxidizing agent, such as oxygen.

Claims

1. A method for purifying a contaminated fluid by photocatalytic treatment, comprising:

(a) providing a contaminated fluid including contaminant molecules in the presence of a photocatalyst;

(b) exciting said photocatalyst with ultraviolet light to form photocatalyst conduction band electrons and positive holes thereby inducing an oxidation state whereby some contaminant molecules are oxidized;

(c) inducing a reduction state, in the substantial absence of oxidizing agents that compete for said photocatalyst conduction band electrons, by adding a reactant comprising a carboxylic acid in sufficient quantity to provide surrogate electrons that react with said positive holes formed on the photocatalyst while the semiconductor catalyst is irradiated whereby other contaminant molecules are reduced by said photocatalyst conduction band electrons.

2. The method as recited in claim 1, wherein:

the reactant comprises a hydroxy carboxylic acid.

3. The method as recited in claim 1, wherein:

the reactant comprises citric acid.

4. The method as recited in claim 1, further comprising:

reverting to the oxidation state by the addition of an oxidizing agent.

5. The method as recited in claim 4, wherein:

the oxidizing agent is selected from the group consisting of;

oxygen, ozone, hydrogen peroxide, persulphate ions, bromate ions, chlorate ions, peroxymonophosphate ions, peroxymonosulphate ions, perchlorate ions, permanganate ions, ferrate ions and, peroxyacetic acid.

6. The method as recited in claim 1, wherein:

the semiconductor catalyst is TiO₂.

13. The method as recited in claim 1, wherein:

the reducing agent comprises a hydroxy carboxylic acid.

7. A method for purifying a contaminated fluid, comprising:

(a) mixing a contaminated fluid with photocatalytic particles to form a slurry;

(b) irradiating the slurry with ultraviolet light to excite the photocatalytic particles and render pairs of electrons and holes in the photocatalytic particles;

(c) oxidizing contaminants found in the slurry by utilization of the electron/hole pairs in the photocatalytic particles;

(d) adding a reactant, in the substantial absence of oxidizing agents that compete for said electrons of said electron/hole pairs, said reactant comprising a carboxylic acid in sufficient quantity that provides surrogate electrons to the slurry, the surrogate electrons reacting at the holes of the photocatalytic particles so as to isolate the electrons for reduction of other contaminants.

8. The method as recited in claim 7, wherein:

the photocatalytic particles comprises TiO₂.

9. The method as recited in claim 7, wherein:

the reactant comprises citric acid.

10. The method as recited in claim 7, wherein:

the contaminated fluid comprises water.

11. A method for purifying a contaminated fluid by photocatalytic treatment, comprising:

(a) providing a contaminated fluid including contaminant molecules in the presence of semiconductor particles;

(b) irradiating the semiconductor particles with ultraviolet light to form photocatalyst conduction band electrons and positive holes;

(c) supplying a reducing agent to the contaminated fluid, in the substantial absence of oxidizing agents that compete for said photocatalyst conduction band electrons, while the semiconductor particle is irradiated, said reducing agent comprising a carboxylic acid in sufficient quantity to provide surrogate electrons that react with said positive holes formed on the photocatalyst such that certain contaminant molecules are destroyed.

12. The method as recited in claim 11, further comprising:

deaerating the environment in which the contaminated fluid and semiconductor particles are present.

14. The method as recited in claim 11, wherein:

the reducing agent comprises citric acid.