Process for engraving ceramic surfaces using local laser vitrification

• US 5,554,335 A
• Filed: 02/22/1995
• Issued: 09/10/1996
• Est. Priority Date: 02/22/1995
• Status: Expired due to Term

• Current Assignee: Fundraising Brick LLC
• Original Assignee: Laser Light Technologies, Inc.
• Inventors: Fields, William C., Hannan, Phyllis, Lukashevsky, Igor, Fredrick, Dan, Grannemann, Steve
• Primary Examiner(s): Vargot, Mathieu D.
• Application Number:
  US08/392,046
• Time in Patent Office: 566 Days
• Field of Search: 264/400, 264/434, 264/482, 430/346, 430/945, 219/121.65, 219/121.66, 219/121.68, 219/121.69
• US Class Current: 264/400
• CPC Class Codes: B23K 2103/52 Ceramics
• CPC Class Codes: B23K 26/16 Removal of by-products, e.g. particles or vapours produced during treatment of a workpiece by a fluid stream B23K26/142
• CPC Class Codes: B23K 26/40 taking account of the properties of the material involved
• CPC Class Codes: B41M 1/34 on glass or ceramic surfaces ink-jet printing on glass or ceramic surfaces B41M5/00
• CPC Class Codes: B41M 5/24 Ablative recording, e.g. by burning marks; Spark recording marking by high energetic means, e.g. by laser otherwise than burning or ablative removal B41M5/26; materials or methods for recording or reproduction by optical means G11B7/00
• CPC Class Codes: B44C 1/228 by laser radiation
• CPC Class Codes: C04B 35/00 Shaped ceramic products characterised by their composition porous ceramic products C04B38/00; ceramic articles characterised by particular shape, see the relevant classes, e.g. linings for casting ladles, tundishes, cups or the like B22D41/02; ceramic substrates for microelectronic semi-conductors H01L23/15; Ceramics compositions containing free metal bonded to carbides, diamond, oxides, borides, nitrides, silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides or sulfides other than as macroscopic reinforcing agents C22C; shaping of ceramics B28B; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products chemical preparation of powders of inorganic compounds C01; infiltration of sintered ceramic preforms with molten metal C04B41/51
• CPC Class Codes: C04B 41/0036 Laser treatment working by laser beam B23K26/00
• CPC Class Codes: C04B 41/009 characterised by the material treated
• CPC Class Codes: C04B 41/5022 with vitreous materials composition of vitreous glazes and enamels C03C; ceramic pigments C09C1/0009
• CPC Class Codes: C04B 41/53 involving the removal of at least part of the materials of the treated article, e.g. etching, drying of hardened concrete C04B41/0036 - C04B41/0054 take precedence
• CPC Class Codes: C04B 41/80 of only ceramics

Abstract

A process is provided for producing contrasting, long lasting, glassy heat fused images on the surface of ceramic materials such as bricks using a laser to vitrify the substrate material. The process is accomplished in three stages: Stage 1) the laser produces a non-adherent, highly light absorptive layer by heating and removing material from the marking field to create depth into the brick'"'"'s surface; Stage 2) melting of the main portion of the substrate material along the marking field using the non-adherent light absorptive layer from Stage 1 as an effective light absorber/heat transducer to cause vitrification along the marking field; Stage 3) residue from the melting in stage 2 is removed by laser ablation to produce the vitrified finished mark.

Claims

1. A process for engraving ceramic surfaces using a laser, said process comprising applying said laser to said ceramic surface along an area to be engraved such that a portion of said ceramic material in said engraving area is removed and melted by said laser to a sufficient degree such that said melted material is fused into a surrounding unmelted portion of said ceramic material whereby an adherent, contrasting marking is created along said engraving area to a depth within and below said ceramic surface, said engraving taking place in three stages:

a first stage in which said laser removes a portion of said ceramic material to form said depth for said marking within and below said ceramic surface;

a second stage in which said laser continues to deliver energy to melt and vitrify said ceramic material whereby it is fused into surrounding unmelted ceramic material within said depth; and

a third stage in which said laser removes residue from said ceramic surface to effect said adherent, contrasting marking.

2. The process of claim 1 in which said laser hatches over said engraving area, said laser being programmed to direct light beams in hatching passes of parallel orientation, each subsequent adjacent beam pass overlapping a prior pass by one half of a diameter of said beam, whereby a heating efficiency is enhanced.

3. The process of claim 1 in which in said first stage a non-adherent, highly light adsorptive layer is created upon removal of said portion of said ceramic material, whereby an increased heating efficiency in said second stage is effected.

4. The process of claim 3 in which said non-adherent, highly light adsorptive layer is comprised of a fine stratum of residue and ash particles produced by heating said ceramic material.

5. The process of claim 1 in which in said first stage, said laser is set to pulse 4,000 times per second with a writing speed of 50 mm per second.

6. The process of claim 1 in which in said second stage, said laser is set to pulse 32,000 times per second with a writing speed of 100 mm per second.

7. The process of claim 1 in which in said third stage, said laser is set to pulse 6,000 times per second with a writing speed of 350 mm per second.

8. The process of claim 1 wherein in said first stage, said laser is set to pulse 4,000 times per second with a writing speed of 50 mm per second;

in said second stage, said laser is set to pulse 32,000 times per second with a writing speed of 100 mm per second; and

in said third stage, said laser is set to pulse 6,000 times per second with a writing speed of 350 mm per second.