Method for producing conductive polymeric coatings with positive temperature coefficients of resistivity and articles made therefrom

• US 5,556,576 A
• Filed: 09/22/1995
• Issued: 09/17/1996
• Est. Priority Date: 09/22/1995
• Status: Expired due to Fees

• Current Assignee: Shuho Company, Ltd.
• Original Assignee: Environmental Engineering Corporation
• Inventors: Nishino, Hiroshi, Kim, Yong C.
• Primary Examiner(s): Lieberman, Paul
• Assistant Examiner(s): KOPEC, MARK T
• Application Number:
  US08/532,536
• Time in Patent Office: 361 Days
• Field of Search: 252/511, 252/512, 252/518, 252/514, 106/1.05, 264/105
• US Class Current: 252/511
• CPC Class Codes: H01C 7/027 consisting of conducting or semi-conducting material dispersed in a non-conductive organic material
• CPC Class Codes: H01C 7/028 consisting of organic substances

Abstract

A method is provided for making a spreadable conductive polymeric coating having a positive temperature coefficient of resistivity including the steps of mixing aromatic solvents in a heated vessel, stirring, and heating to a temperature between 40 and 60 degrees Celsius; adding a quantity of substrate-forming elastomer, which contains no diene monomer, equal to 25% to 40%, by weight, of a conductor powder to be added in a later step; adding a quantity of a paraffin equal to 25% to 40%, by weight, by weight, of the conductor powder to be added and continuing to stir until all solids are dissolved; adding a fine conductor powder and continuing to stir until a smooth paste is formed; and mix-kneading the paste until a substantially uniform dispersion of the fine conductor powder in the paste is achieved. The paste, when suitably thinned, can be screen printed or otherwise spread on a wide variety of surfaces and thermally cured to form a thin conductive layer having a PTC of resistivity for use in heating without the need for thermostatic control of the temperature. The pastes can be formulated for a variety of PTCs.

Claims

1. A method for making a spreadable conductive polymeric coating having a positive temperature coefficient of resistivity, comprising the following sequential steps:

placing an aromatic solvent in a heated stirring vessel, stirring, and heating to a temperature between 40 and 60 degrees Celsius;

adding a quantity of substrate-forming material selected from the group consisting of thermoplastic resins, uncured thermosetting resins, and elastomers, which contains no diene monomer, equal to 25% to 40%, by weight, of a conductor powder to be added in a later step and continuing to stir;

adding a quantity of a paraffin equal to 25% to 40%, by weight, of the conductor powder to be added and continuing to stir until all solids are dissolved;

adding a fine conductor powder selected from the group consisting of graphite, carbon black, metal powder, metal-coated microbeads, and mixtures thereof, and continuing to stir until a smooth paste is formed; and

mix-kneading the paste until a substantially uniform dispersion of the fine conductor powder in the paste is achieved.

2. The method of claim 1, further comprising:

adding a hindered phenol-based heat resistant stabilizer to the solution in the mixer prior to adding the conductor powder.

3. The method of claim 1, wherein the aromatic solvent comprises a mixture of ketone in a 1:

4 ratio, by volume, with xylene or toluene and the substrate-forming material comprises a thermoplastic elastomer which is a copolymer of ethylene, propylene, and styrene.

4. The method of claim 2, wherein the aromatic solvent comprises a mixture of ketone in a 1:

4 ratio, by volume, with xylene or toluene and the substrate-forming material comprises a thermoplastic elastomer which is a copolymer of ethylene, propylene, and styrene.

5. The method of claim 1, wherein the substrate-forming material further comprises 20%-30%, by volume, of polystyrene.

6. The method of claim 2, wherein the substrate-forming material further comprises 20%-30%, by volume, of polystyrene.

7. The method of claim 1, wherein the conductor powder comprises graphite with a particle size of 5-30μ

and carbon black with a particle size of 0.030-0.060μ and

a ratio of graphite to carbon black in the range of 7;

3 to 8;

2, by volume.

8. The method of claim 2, wherein the conductor powder comprises graphite with a particle size of 5-30μ

and carbon black with a particle size of 0.030-0.060μ and

a ratio of graphite to carbon black in the range of 7;

3-8;

2, by volume.

9. The method of claim 2, wherein the aromatic solvent is selected from the group consisting of methyl ethyl ketone, methyl isobutyl ketone, diisobutyl ketone, diacetonealcol, octanone, and acetone.

10. The method of claim 3, wherein the aromatic solvent is selected from the group consisting of methyl ethyl ketone, methyl isobutyl ketone, diisobutyl ketone, diacetonealcol, octanone, and acetone.

11. The method of claim 1, wherein the aromatic solvent comprises methyl isobutyl ketone and xylene in a ratio of 1:

1, by volume, and the substrate-forming material comprises a modified polyethylene terephthalate.

12. The method of claim 2, wherein the aromatic solvent comprises methyl isobutyl ketone and xylene in a ratio of 1:

1, by volume, and the substrate-forming material comprises a modified polyethylene terephthalate.

13. The method of claim 11, wherein the paraffin comprises an alcohol-type wax.

14. The method of claim 12, wherein the paraffin comprises an alcohol-type wax.

15. The method of claim 1, wherein the material solvent is straight xylene and the substrate-forming polymer comprises an alkyd resin and a melamine resin in a 7:

3 ratio, by weight.

16. The method of claim 2, wherein the aromatic solvent is straight xylene and the substrate-forming polymer comprises an alkyd resin and a melamine resin in a 7:

3 ratio, by weight.