Catalyst component for olefin polymerization and process for producing polyolefins

• US 5,556,820 A
• Filed: 03/02/1994
• Issued: 09/17/1996
• Est. Priority Date: 12/28/1989
• Status: Expired due to Term

• Current Assignee: Idemitsu Kosan Company Limited
• Original Assignee: Idemitsu Petrochemical Co., Ltd. (Idemitsu Kosan Company Limited)
• Inventors: Iwasaki, Sigeo, Tanaka, Akira, Toda, Masatoshi, Ota, Tsuyoshi, Matsuo, Youichi, Funabashi, Hideo, Tsuruoka, Masayuki, Sugahara, Akinobu, Akimaru, Tsutomu
• Primary Examiner(s): TESKIN, FRED M
• Application Number:
  US08/204,607
• Time in Patent Office: 930 Days
• Field of Search: 526/125, 526/124.3, 526/123.1, 502/111, 502/104, 502/112, 502/115, 502/118, 502/119, 502/134, 502/172, 264/9, 423/497, 423/498, 423/499, 568/841, 568/851
• US Class Current: 502/111
• CPC Class Codes: B01J 19/18 Stationary reactors having moving elements inside B01J19/08, B01J19/26 take precedence
• CPC Class Codes: B01J 2219/00094 Jackets
• CPC Class Codes: B01J 2219/00768 vertical
• CPC Class Codes: B01J 2219/185 vertical
• CPC Class Codes: C08F 10/00 Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
• CPC Class Codes: C08F 10/02 Ethene
• CPC Class Codes: C08F 110/02 Ethene
• CPC Class Codes: C08F 2/34 Polymerisation in gaseous state
• CPC Class Codes: C08F 2/40 using retarding agents
• CPC Class Codes: C08F 210/08 Butenes
• CPC Class Codes: C08F 210/16 Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
• CPC Class Codes: C08F 2500/04 Broad molecular weight distribution, i.e. Mw/Mn > 6
• CPC Class Codes: C08F 2500/07 High density, i.e. > 0.95 g/cm3
• CPC Class Codes: C08F 2500/17 Viscosity
• CPC Class Codes: C08F 2500/24 Polymer with special particle form or size
• CPC Class Codes: C08F 4/6094 containing oxygen
• CPC Class Codes: C08F 4/6095 containing nitrogen
• CPC Class Codes: C08F 4/6492 containing aliphatic unsaturation
• CPC Class Codes: C08F 4/6494 containing oxygen
• CPC Class Codes: C08F 4/654 with magnesium or compounds thereof
• CPC Class Codes: C08F 4/6548 : magnesium or compounds thereof, not provided for in C08F4/6543 or C08F4/6546

Abstract

A solid product as a catalyst component for an olefin polymerization catalyst is obtained by the reaction of metallic magnesium, an alcohol, and a halogen in an amount ranging from 0.019 to 0.06 gram-atom per one mole of metallic magnesium. Alternatively, the halogen component is a halogen-containing compound which contains not less than 0.0001 gram-atom of a halogen atom per one gram-atom of metallic magnesium.

Claims

1. A solid product useful for the preparation of a solid catalyst component for olefin polymerization, which is obtained by the reaction of metallic magnesium, an alcohol, and a halogen in an amount ranging from 0.019 to 0.06 gram-atom for 1 mol of the metallic magnesium.

2. A solid product as claimed in claim 1, wherein the halogen is iodine.

3. A solid product as claimed in claim 1, which has a sphericity (S) smaller than 1.60 as defined by formula (1) below and a particle size distribution index (P) smaller than 5.0 as defined by formula (2) below:

space="preserve" listing-type="equation">S=(E.sub.1 /E.sub.2).sup.2 (

     1)

wherein E₁ denotes the measured perimeter of the projected image of a particle, taken with a scanning electron microscope at ×

150 magnification, and E₂ denotes the perimeter of a circle determined from measurement of the area of the projected image of said particle;

space="preserve" listing-type="equation">P=D.sub.90 /D.sub.10 (

     2)

wherein, having determined the particle size distribution of 90 wt. % of the particles of a given mass of particles and the particle size distribution of the remaining 10 wt. % of particles, D₉₀ is the average particle diameter of said 90 wt. % of particles, and D₁₀ is the average particle diameter of said 10 wt. % of particles.

4. A solid catalyst composition obtained from the solid product (a) defined in any one of claims 1 to 3 and a titanium compound (b).

5. A solid catalyst composition obtained from the solid product (a) defined in any one of claims 1 to 3, a titanium compound (b), and an electron donor compound (c).

6. A solid catalyst composition as claimed in claim 4, which has a pore volume greater than 0.4 cc/g and a specific surface area greater than 300 m² /g.

7. A solid catalyst composition as claimed in claim 5, which has a pore volume greater than 0.4 cc/g and a specific surface area greater than 300 m² /g.

8. A solid product useful in preparation of a solid catalyst component for olefin polymerization, obtained by the reaction of metallic magnesium, alcohol and a halogen-containing compound containing from 0.019 to 0.06 gram-atom of a halogen atom, per 1 gram-atom of the metallic magnesium.

9. A solid product according to claim 8, wherein the halogen-containing compound is a halogen-containing metal compound.

10. A solid product according to claim 8 or 9, which has a sphericity (S) of less than 1.60 as defined by the following Formula (1):

space="preserve" listing-type="equation">S=(E.sub.1 /E.sub.2).sup.2 (

     1)

wherein E₁ denotes the measured perimeter of the projected image of a particle, taken with a scanning electron microscope at ×

150 magnification, and E₂ denotes the perimeter of a circle determined from measurements of the area of the projected image of a particle, and a particle size distribution index (P) of less than 5.0 as defined by the following Formula (2);

space="preserve" listing-type="equation">P=D.sub.90 /D.sub.10 (

     2)

wherein, having determined the particle size distribution of 90 wt. % of the particles of a given mass of particles and the particle size distribution of the remaining 10 wt. % of the particles, D₉₀ is the particle diameter of said 90 wt. % of particles, and D₁₀ is the particle diameter of said 10 wt. % particles.

11. A solid catalyst composition prepared from (a) a solid product set forth in claim 8 or 9 and (b) a titanium compound.

12. A solid catalyst composition prepared from (a) a solid product set forth in claim 8 or 9;

(b) a titanium compound; and

(c) an electron donor compound.

13. A solid catalyst composition prepared by reacting at least:

(a) a solid product obtained by the reaction of metallic magnesium, alcohol and from 0.019 to 0.06 gram-atom, per 1 gram-atom of the metallic magnesium, of halogen or a halogen-containing compound containing from 0.019 to 0.06 gram-atom, per 1 gram-atom of the metallic magnesium, of a halogen atom, and

(b) a titanium compound,

said reaction being carried out in a vessel having a stirring wing fixed to a stirring axle placed in the center of the vessel, the stirring wing comprising a bottom paddle wing located close to the bottom of the vessel and an upper wing located higher than the bottom paddle wing, and during the reaction, the stirring wing satisfying the following equation;

space="preserve" listing-type="equation">H/L>

0.5

wherein H is height between the bottom of the vessel and the most upper portion of the upper wing; and

L is the liquid level during a reaction, and the most upper portion of the bottom paddle wing being located lower than the liquid level.

15. The solid catalyst composition according to claim 13, wherein the components of solid product (a) are reacted under the stated stirring conditions in a vessel having a stirring wing fixed to a stirring axle placed in the center of the stirring vessel, the stirring wing comprising a bottom paddle wing located close to the bottom of the vessel and an upper wing located higher than the bottom paddle wing, and during a reaction the stirring wing satisfying the following equation:

space="preserve" listing-type="equation">H/L>

0.5

wherein H is the height between the bottom of the vessel and the most upper portion of the upper wing; and

L is the liquid level during a reaction, and the most upper portion of the bottom paddle wing being located lower than the liquid level.

16. The solid catalyst composition according to claim 13, wherein the components of solid product (a) are reacted in the vessel configured as described under the stated conditions.

17. The solid catalyst composition according to claim 13, wherein the components of solid product (a) are reacted in the vessel configured as described under stirring conditions which satisfy the following equation:

space="preserve" listing-type="equation">4.3×

10.sup.3 <

n.sup.3 d.sup.2 <

4.0×

10.sup.6

wherein d (m) is a diameter of the stirring wing; and

n (rpm) is the rotation rate.

14. A solid catalyst composition prepared by reacting at least:

(a) a solid product obtained by the reaction of metallic magnesium, alcohol and from 0.019 to 0.06 gram-atom, per 1 gram-atom of the metallic magnesium, of halogen or a halogen-containing compound containing from 0.019 to 0.06 gram-atom, per 1 gram-atom of the metallic magnesium, of a halogen atom, and

(b) a titanium compound,

said reaction being carried out in a vessel having a stirring wing fixed to a stirring axle placed in the center of a stirring vessel, said stirring being conducted under stirring conditions which satisfy the following equation;

space="preserve" listing-type="equation">4.3×

10.sup.3 <

n.sup.3 d.sup.2 <

4.0×

10.sup.6

wherein d (m) is the diameter of the stirring wing; and

n (rpm) is the rotation rate.

18. The solid catalyst composition according to claim 14, wherein the components of solid product (a) are reacted in the vessel configured as described under the stirring conditions as stated.