Play balls or pressureless tennis balls

• US 5,558,325 A
• Filed: 08/05/1993
• Issued: 09/24/1996
• Est. Priority Date: 08/05/1993
• Status: Expired due to Term

• Current Assignee: Head Technology GmbH
• Original Assignee: Gencorp Incorporated
• Inventors: Yeoh, Oon H., Wilson, John A., Miranda, Richard A., Hargis, I. Glen
• Primary Examiner(s): Thibodeau, Paul
• Assistant Examiner(s): Critharis, Mary
• Application Number:
  US08/102,686
• Time in Patent Office: 1,146 Days
• Field of Search: 428/35.7, 428/36.4, 428/36.8, 273/58 B, 273/58 J, 273/61 R, 273/61 C, 273/DIG. 4, 273/DIG. 5
• US Class Current: 473/606
• CPC Class Codes: A63B 39/00 Hollow non-inflatable balls , i.e. having no valves rigid balls A63B37/00
• CPC Class Codes: C08K 3/013 Fillers, pigments or reinforcing additives
• CPC Class Codes: C08L 1/00 Compositions of cellulose, modified cellulose or cellulose derivatives
• CPC Class Codes: C08L 21/00 Compositions of unspecified rubbers
• CPC Class Codes: C08L 23/06 Polyethene
• CPC Class Codes: C08L 23/0853 Vinylacetate
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/24 Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
• CPC Class Codes: C08L 51/06 grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
• CPC Class Codes: C08L 7/00 Compositions of natural rubber
• CPC Class Codes: C08L 9/00 Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
• CPC Class Codes: Y10S 273/04 Ethylene
• CPC Class Codes: Y10S 273/05 Vinyl
• CPC Class Codes: Y10T 428/1352 Polymer or resin containing [i.e., natural or synthetic]
• CPC Class Codes: Y10T 428/1372 Randomly noninterengaged or randomly contacting fibers, filaments, particles, or flakes
• CPC Class Codes: Y10T 428/1386 Natural or synthetic rubber or rubber-like compound containing

Abstract

A hollow rubber play ball is disclosed that uses a combination two or more fillers to produce desirable playing properties in a tennis ball as specified by the International Lawn Tennis Federation (ITF). The preferred play ball is a pressureless tennis ball. The specific fillers disclosed are mineral type particulate reinforcing fillers such as silicas and carbon black, polymeric fillers such as cellulose, a reaction product of grafting polyethylene with cellulose, and ethylene-vinyl acetate copolymers. These fillers can also have surface treatments to enhance the elastomer-filler interaction. Another reinforcing filler that can be introduced with the rubber components is the non-rubber constituents in skim rubber that serve to increase the modulus of a compounded rubber.

Claims

1. A play ball comprising:

a blend of at least

a) one or more crosslinked rubbers,

b) one or more reinforcing particulate fillers comprising silica or carbon black or combinations thereof, and

c) a polymeric filler being an ethylene-vinyl acetate copolymer with from about 1 to 10 weight percent vinyl acetate and/or the reaction product of cellulose grafted with a low density polyethylene in the presence of a free-radical source,

wherein said polymeric filler is blended into said one or more rubbers before they are crosslinked, and

wherein said ball is in the form of a hollow sphere.

2. A play ball according to claim 1, wherein said polymeric filler is the reaction product of cellulose grafted with low density polyethylene in the presence of a free-radical source, wherein said reaction product is present in the amounts from 5 to 40 phr, said reaction product having a weight ratio of said low density polyethylene to cellulose of from 10:

90 to 90;

10.

3. A play ball according to claim 1, wherein said one or more crosslinked rubbers contain skim rubber in amounts from 5 to about 40 phr.

4. A play ball according to claim 2, wherein said cellulose has a ribbon structure and has a surface coating, and where the weight ratio of polyethylene to cellulose is from 70:

30 to 30;

70.

12. A play ball according to claim 1, wherein

said one or more reinforcing particulate fillers comprises silica present in amounts from 1 to 30 phr,

said one or more rubbers or comprise 1,4-polybutadiene, 1,4-polyisoprene, or skim rubber or combinations there of;

said play ball optionally has a felt cover; and

said play ball has a diameter of from 65.4 to 68.6 mm, a weight of from 56.7 to 58.5g, and an internal pressure of from about negative 0.02 to positive 0.034 MPa as measured from atmospheric pressure.

5. In a tennis ball comprising a hollow sphere which is comprised of a crosslinked blend of one or more rubbers and reinforcing filler, the improvement comprising the inclusion of a grafted product of the reaction of low density polyethylene with cellulose in the presence of a free-radical source and wherein said grafted reaction product is present in amounts from 10 to 50 phr.

6. In a tennis ball according to claim 5, comprising as said one or more rubbers, skim rubber.

8. A play ball according to claim 6, wherein said one or more rubbers further include cis 1,4- polyisoprene and/or cis 1,4-polybutadiene, said reinforcing filler is one or more silicas, said silicas are present from 5 to 30 phr, said cellulose has a ribbon structure, and said cellulose is present from about 25 to about 50 phr.

7. In a tennis ball comprising a hollow sphere of a blend of one or more crosslinked rubbers and reinforcing fillers, the improvement wherein said fillers comprise in combination, an ethylene-vinyl acetate copolymer, having from about 1 to 10 weight percent vinyl acetate and from 90 to 99 weight percent ethylene, and a particulate reinforcing filler selected from carbon black or silica or combinations thereof which are blended into said one or more rubbers before they are crosslinked.

9. A play ball according to claim 7, wherein the play ball optionally includes a felt cover, said play ball has an external diameter from 65.4 to 68.6 mm and a weight of 56.7 to 58.5 g, and said play ball has an internal pressure of from a negative 0.02 to a positive 0.034 MPa as measured from atmospheric pressure.

10. A play ball according to claim 9, including from about 5 to about 30 phr skim rubber.

11. In rubber ball halves including one or more rubbers, fillers, and curatives wherein the improvement comprises having from 5 to 50 phr 6f a filler, said filler being a reaction product of low density polyethylene, cellulose fiber, and a free radical initiator reacted at from about 90°

to about 190°

C. which forms cellulose grafted with said polyethylene.

13. A play ball comprising:

a blend of

(a) one or more crosslinked rubbers,

(b) one or more reinforcing particulate fillers comprising silica or carbon black or combinations thereof, and

(c) an ethylene-vinyl acetate copolymer comprising from about 1 to 10 weight percent vinyl acetate and from about 90 to 99 weight percent ethylene;

wherein said ethylene-vinyl acetate copolymer is blended into said blend before said one or more rubbers are crosslinked, and

wherein said ball is in the form of a hollow sphere.

14. A play ball according to claim 13, wherein said one or more particulate fillers comprises silica present in amounts from 5 to 30 phr, and wherein said one or more rubbers comprise polybutadiene with at least 75 percent 1,4 units, polyisoprene with at least 90 percent 1,4 units, skim rubber or combinations thereof.

15. A play ball according to claim 14, wherein the play ball optionally has a felt cover, wherein said play ball has a diameter of from 65.4 to 68.6 mm and a weight of from 56.7 to 58.5 g, and wherein the play ball has an internal pressure of from about a negative 0.02 to a positive 0,034 MPa as measured from atmospheric pressure.

16. A play ball according to claim 15, wherein said ethylene-vinyl acetate copolymer is present from about 5 to about 30 phr and consists essentially of from about 1 to 10 weight percent vinyl acetate and from 90 to 99 weight percent ethylene.

17. A play ball according to claim 13, further comprising skim rubber in amounts from 5 to 40 phr and wherein said ethylene-vinyl acetate copolymer is present from about 5 to about 30 phr.

18. A play ball according to claim 16, wherein said ethylene-vinyl acetate copolymer consists essentially of from about 2 to about 5 wt. % vinyl acetate and from 95 to 98 wt. % ethylene.

19. A play ball according to claim 18, wherein said silica has been treated with a mercaptosilane.