Rechargeable battery system and method and metal-air electrochemical cell for use therein

• US 5,558,947 A
• Filed: 04/14/1995
• Issued: 09/24/1996
• Est. Priority Date: 04/14/1995
• Status: Expired due to Term

• Current Assignee: George D. Robison
• Original Assignee: George D. Robison
• Inventors: Robison, George D.
• Primary Examiner(s): Willis, Jr., Prince
• Assistant Examiner(s): NUZZOLILLO, MARIA
• Application Number:
  US08/422,450
• Time in Patent Office: 529 Days
• Field of Search: 429/13, 429/14, 429/15, 429/17, 429/19, 429/49, 429/50, 429/51
• US Class Current: 429/404
• CPC Class Codes: B60L 1/003 to auxiliary motors, e.g. for pumps, compressors
• CPC Class Codes: B60L 50/64 Constructional details of batteries specially adapted for electric vehicles
• CPC Class Codes: B60L 50/66 Arrangements of batteries
• CPC Class Codes: B60L 53/11 DC charging controlled by the charging station, e.g. mode 4
• CPC Class Codes: B60L 53/80 Exchanging energy storage elements, e.g. removable batteries
• CPC Class Codes: H01M 6/5077 Regeneration of reactants or electrolyte
• CPC Class Codes: H01M 8/06 Combination of fuel cells with means for production of reactants or for treatment of residues regenerative fuel cells H01M8/18
• CPC Class Codes: H01M 8/184 Regeneration by electrochemical means
• CPC Class Codes: H01M 8/225 Fuel cells in which the fuel is based on materials comprising particulate active material in the form of a suspension, a dispersion, a fluidised bed or a paste
• CPC Class Codes: Y02E 60/50 Fuel cells
• CPC Class Codes: Y02T 10/70 Energy storage systems for electromobility, e.g. batteries
• CPC Class Codes: Y02T 10/7072 Electromobility specific charging systems or methods for batteries, ultracapacitors, supercapacitors or double-layer capacitors
• CPC Class Codes: Y02T 90/12 Electric charging stations
• CPC Class Codes: Y02T 90/14 Plug-in electric vehicles

Abstract

Rechargeable metal-air battery systems comprise a plurality of plate groups (40) disposed within a battery cell (12) and have input and output conduits (13, 14). A fluid electrolyte is circulated through the battery cell by a pump (22) and regenerated by a divester (20) for recirculation through the battery cell (12). The divester (20) divests the particles of active material suspended within the electrolyte of their oxide layer resulting from passivation caused by the electrolyte solution being saturated with oxide. The divester (20) performs its function by bringing the particles of active material into frictional contact with one another. The battery system (10) constructed in accordance with the present invention may be chemically recharged by removing the spent active material suspended within the electrolyte and replacing it with new active material.

Claims

1. A rechargeable battery system having an electrolyte slurry containing active metal particles, a portion of the active metal particles having an outer layer of reacted metal oxide, comprising:

a plurality of plates forming an anode and a cathode;

a cell case housing said plates and having an output and an input conduit;

divester means in communication with said cell case for at least partially divesting the outer layer of reacted metal oxide from the active metal particles in the electrolyte slurry;

and pump means for recirculating the electrolyte slurry from the output conduit to the input conduit through said divester means.

2. The system of claim 1, wherein said divester means removes said oxide from said metal particles and re-suspends said metal particles in the electrolyte slurry.

3. The system of claim 1, wherein said divester means comprises:

a container having at least one conduit port for introducing said electrolyte slurry into said container; and

grinding means disposed in said container for grinding said metal particles.

4. The system of claim 1, further comprising an oxide separator tank connected to said output conduit of said cell case for separating oxide and active metal particles.

5. The system of claim 1, further comprising an active metal storage tank connected to said port of said divester means for holding new active metal particles for introduction into said divester means.

6. The system of claim 1, further comprising an oxide storage tank connected to said port of said divester means for providing storage means for spent metal oxide or hydroxide particles.

7. The system of claim 1, further comprising means for chemically recharging said battery system by removing said oxide and said electrolyte slurry and introducing new active metal particles and electrolyte in said battery system.

8. The system of claim 1, further comprising means for removing a portion of said electrolyte containing oxide.

9. The system of claim 1, further including a frame structure in said cell case for providing structural rigidity to said plates.

16. The system of claim 1, wherein said divester means agitates said metal particles.

10. A method for sustaining operation of a metal-air battery having a battery case, comprising the steps of:

retrieving from said battery case electrolyte substantially saturated with reactant metal particles and oxide;

divesting the reactant metal particles in the saturated electrolyte of an oxide layer so as to expose a portion of an active metal of said metal particles;

suspending said divested metal particles and oxide particles in the electrolyte;

recirculating said suspended metal particles in the electrolyte into said battery case.

11. The method of claim 10, wherein the step of divesting comprises the step of de-oxidizing the reactant metal particles by bringing said reactant metal particles into frictional contact with one another.

12. The method of claim 10, further comprising the step of separating the active metal particles suspended in the electrolyte and the oxide in the electrolyte.

13. The method of claim 10, further comprising the step of introducing new active metal particles into the electrolyte.

15. The rechargeable battery system as set forth in claim 13, wherein said divester means comprise a pair of meshing gears and means for directing said electrolyte solution through said gears, said outer layer of said active metal being removed from said active metal particles as said metal particles pass through said gears.

17. The method of claim 10, wherein the step of divesting comprises a step of de-oxidizing the reactant metal particles by agitating said reactant metal particles.

14. A rechargeable battery system comprising:

a battery having a cell case with an input port and an output port, said cell case for holding a liquid electrolyte solution comprised of a suspension of active metal particles having an outer layer of reacted metal oxide;

divester means for receiving said electrolyte solution and for removing at least a portion of said outer layer of said reacted metal oxide on said active metal particles; and

means for pumping said electrolyte solution from said output port of said cell case to said divester means and then from said divester means to said input port of said cell case.

18. The rechargeable battery system as set forth in claim 14, wherein said divester means comprises a pair of rollers and means for directing said electrolyte through said rollers, said outer layer of said active metal being substantially removed from said active metal particles as said metal particles pass through said rollers.

19. The rechargeable battery system as set forth in claim 14, wherein said divester means agitates said active metal particles in order to at least partially remove said outer layer of said reacted metal oxides from said active metal particles.