Process for deinking electrostatic printed paper using a combination of non-ionic surfactants

• US 5,560,806 A
• Filed: 04/22/1994
• Issued: 10/01/1996
• Est. Priority Date: 04/22/1994
• Status: Expired due to Term

• Current Assignee: Joyce L. Morrison
• Original Assignee: PPG Industries Incorporated (Nouryon BV)
• Inventors: Vijayendran, Bhima R., Li, Chin, Hipolit, Kevin
• Primary Examiner(s): Czaja, Donald E.
• Assistant Examiner(s): NGUYEN, TAN D
• Application Number:
  US08/231,553
• Time in Patent Office: 893 Days
• Field of Search: 162/5, 162/4, 252/61, 252/174.22, 252/358, 252/DIG. 1, 252/162
• US Class Current: 162/5
• CPC Class Codes: D21C 5/027 Chemicals therefor
• CPC Class Codes: Y02W 30/64 Paper recycling

Abstract

Describes a method for deinking wastepaper printed with electrostatic ink or mixtures thereof with wastepaper printed with impact ink in which a combination of nonionic surfactants are added to an alkaline slurry of the paper fibers. The surfactants are a first nonionic surfactant represented by the formula,

R--Ph--(OC.sub.2 H.sub.4).sub.m --(OC.sub.3 H.sub.6).sub.n --(OC.sub.4

H₈)_p --R¹

and a second nonionic surfactant represented by R² --(OC₂ H₄)_r --OH, R³ --(OC₂ H₄)_s --R⁴ or mixtures of such second nonionic surfactants. R contains 8 to 10 carbon atoms, Ph is phenylene, R¹ is chloro or phenoxy, R² contains 10 to 16 carbon atoms, R³ contains 8 to 14 carbon atoms, R⁴ is chloro, the sum of m, n and p is a number of from 1 to 10, r is a number of from 1 to 5 and s is a number of from 0.5 to 15. The ratio of the first to second nonionic surfactants is from 1:100 to 1:1.

Claims

1. A method for deinking printed paper selected from the group consisting of electrostatically printed paper and a mixture of electrostatically printed paper and impact ink printed paper comprising the steps of:

(a) pulping such printed paper in an alkaline aqueous medium, thereby to produce an aqueous slurry of paper fibers and particles of electrostatic ink,

(b) adding to said slurry with agitation a deinking amount of deinking agent comprising, in combination,

(i) a first nonionic surfactant material represented by the formula;

space="preserve" listing-type="equation">R--Ph--(OC.sub.2 H.sub.4).sub.m --(OC.sub.3 H.sub.6).sub.n --(OC.sub.4 H.sub.8).sub.p --R.sup.1

wherein R is an aliphatic hydrocarbon group containing from about 8 to 10 carbon atoms, Ph is the bivalent phenylene group, R¹ is selected from the group consisting of chloro and phenoxy, m, n, and p are each a number of between 0 and about 10, provided that the sum of m, n, and p is a number between about 1 and 10; and

(ii) a second deinking nonionic surfactant material selected from the group consisting of;

a) a nonionic surfactant represented by the formula, R² --(OC₂ H₄)_r --OH, wherein R² is an aliphatic hydrocarbon group containing from about 10 to about 16 carbon atoms and r is a number of between about 1 and about 5;

b) a nonionic surfactant represented by the formula, R³ --(OC₂ H₄)_s --R⁴, wherein R³ is an aliphatic hydrocarbon group containing from about 8 to about 14 carbon atoms, R⁴ chloro and s is a number of between about 0.5 and about 15; and

c) mixtures of said second nonionic surfactants wherein the ratio of said first nonionic surfactant material (i) to the second nonionic surfactant material (ii) being from about 1;

100 to about 1;

1,

(c) agitating the slurry of step (b) to agglomerate the particles of electrostatic ink, and

(d) separating the agglomerated electrostatic ink particles form the aqueous slurry of paper fibers.

2. The method of claim 1 wherein R is an aliphatic hydrocarbon group of about 8 carbon atoms, R¹ is chloro, m is about 3, R² is an aliphatic hydrocarbon group containing from about 11 to about 15 carbon atoms, and r is about 3.

3. The method of claim 2 wherein a non-polar solvent (iii) having a flash point higher than 125°

F. is included with the deinking agent and the ratio of said first nonionic surfactant material (i) to the second deinking surfactant material (ii) to the non-polar solvent (iii) ranges from about 1;

46.5;

2.5 to about 1.5;

0.5;

3.

4. The method of claim 3 wherein from about 0.2 to 3.0 weight percent deinking agent, based on the weight of the dry pulp fiber, is used.

5. The method of claim 4 wherein the pH of the pulped slurry is from about 7.5 to about 11.5;

the temperature at which deinking is performed is from about 120°

F. to about 175°

F.; and

the agitation in step (c) is continued for between about 5 and about 60 minutes.

6. The method of claim 1 wherein a non-polar solvent (iii) having a flash point higher than 125°

F. is included with the deinking agent and the ratio of said first nonionic surfactant material (i) to the second surfactant material (ii) to the non-polar solvent (iii) ranges from about 1;

46.5;

2.5 to about 1.5;

0.5;

3.

7. The method of claim 6 wherein from about 0.2 to 3.0 weight percent deinking agent, based on the weight of the dry pulp fiber, is used.

8. The method of claim 7 wherein the pH of the pulped slurry is from about 7.5 to about 11.5;

the temperature at which deinking is performed is from about 120°

F. to about 175°

F.; and

the agitation in step (c) is continued for between about 5 and about 60 minutes.

9. The method of claim 6 wherein a chemical collector having solubility properties similar to the electrostatic ink is added to step (a) in an amount of from about 0.01 to about 5.0 weight percent based on the weight of the dry pulp fiber, said collector being a polymeric material having a glass transition temperature in the range of from about 20°

C. to about 95°

C.

10. The method of claim 9 wherein the collector is selected from the group consisting of polyvinyl chloride, polyurethane, polypropylene, polyacrylate, polystyrene, polyester and styrene-acrylate copolymer.

11. The method of claim 1 wherein from about 0.2 to 3.0 weight percent deinking agent, based on the weight of the dry pulp fiber, is used.

12. The method of claim 11 wherein the pH of the pulped slurry is from about 7.5 to about 11.5;

the temperature at which deinking is performed is from about 120°

F. to about 175°

F.; and

the agitation in step (c) is continued for between about 5 and about 60 minutes.

13. The method of claim 1 wherein a chemical collector having solubility properties similar to the electrostatic ink is added to step (a) in an amount of from about 0.01 to about 5.0 weight percent based on the weight of the dry pulp fiber, said collector being a polymeric material having a glass transition temperature in the range of from about 20°

C. to about 95°

C.

14. The method of claim 13 wherein the collector is selected from the group consisting of polyvinyl chloride, polyurethane, polypropylene, polyacrylate, polystyrene, polyester and styrene-acrylate copolymer.