Air manager system for recirculating reactant air in a metal-air battery

• US 5,560,999 A
• Filed: 05/22/1995
• Issued: 10/01/1996
• Est. Priority Date: 04/30/1993
• Status: Expired due to Fees

• Current Assignee: Gillette Company (The Procter & Gamble Company)
• Original Assignee: AER Energy Resources, Inc.
• Inventors: Pedicini, Chris, Cherry, Ernest C., Skeggs, Leonard T., Young, Jeffrey E., Sieminski, Dennis P.
• Primary Examiner(s): Nuzzolillo, M.
• Application Number:
  US08/447,281
• Time in Patent Office: 498 Days
• Field of Search: 429/27, 429/35, 429/34, 429/49, 429/72, 429/82, 429/83
• US Class Current: 429/407
• CPC Class Codes: H01M 10/613 Cooling or keeping cold
• CPC Class Codes: H01M 10/633 characterised by algorithms, flow charts, software details or the like
• CPC Class Codes: H01M 10/651 characterised by parameters specified by a numeric value or mathematical formula, e.g. ratios, sizes or concentrations
• CPC Class Codes: H01M 10/654 located inside the innermost case of the cells, e.g. mandrels, electrodes or electrolytes
• CPC Class Codes: H01M 10/6563 with forced flow, e.g. by blowers
• CPC Class Codes: H01M 10/6565 with recirculation or U-turn in the flow path, i.e. back and forth
• CPC Class Codes: H01M 12/06 with one metallic and one gaseous electrode
• CPC Class Codes: H01M 12/065 with plate-like electrodes or stacks of plate-like electrodes
• CPC Class Codes: H01M 12/08 composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
• CPC Class Codes: H01M 50/30 Arrangements for facilitating escape of gases
• CPC Class Codes: H01M 6/50 Methods or arrangements for servicing or maintenance, e.g. for maintaining operating temperature constructional details of current conducting connections for detecting conditions inside cells or batteries, e.g. details of voltage sensing terminals, H01M50/569
• CPC Class Codes: H01M 6/5038 Heating or cooling of cells or batteries
• CPC Class Codes: H01M 8/04089 of gaseous reactants
• CPC Class Codes: H01M 8/04097 with recycling of the reactants H01M8/04119, H01M8/04104 take precedence
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

An air manager is disclosed which recirculates reactant air in a battery and exchanges only a minimal amount of recirculated air for ambient air that is necessary to maintain a sufficient oxygen concentration in the battery. In the air manager, the reactant air is recirculated in a defined air pathway that provides reactant air to the entire area of all the air cathodes. A catalyst element is also provided in the air manager to convert the hydrogen gas that is generated during the recharge of a metal-air battery to water vapor. The air manager is nevertheless compact and lightweight so that the resulting battery is portable.

Claims

1. An air manager system for a metal-air cell having an air cathode and anode, said system comprising a reactant air channel adjacent to said cathode to provide reactant air, comprising:

means for directing a flow of air adjacent to the air cathode to provide reactant air;

means for removing the reactant air from adjacent to the air cathode and for recirculating the flow of the reactant air back to the cathode;

means for admitting ambient air into the flow of said recirculating reactant air in an amount sufficient only to approximately replace oxygen removed from said recirculating reactant air by said cell;

means for controlling said amount of ambient air entering the flow of reactant air, comprising;

a current monitoring circuit connected to measure an output current drawn from said metal-air cell by a load during operation of said load; and

an oxygen control circuit responsive to said current drawn to open said means for admitting ambient air for a predetermined time to provide air to said metal-air cell when said current is insufficient to meet load demand.

2. The apparatus of claim 1 further comprising means for controlling air entering the recirculation system to maintain an output current density.

3. The apparatus of claim 1 wherein said means for recirculating the flow of air adjacent to said cathode defines a pathway from an exit location of said cathode to an entry location of said cathode.

4. The apparatus of claim 3 further comprising a humidifier incorporated into said air passageway.

5. The apparatus of claim 4 further comprising a bypass channel for selectively directing said air around the humidifier.

6. The apparatus of claim 5 further comprising a humidity monitor means for selectively directing said air through said bypass channel.

7. The apparatus of claim 3 wherein said reactant air plenum encloses said cathode so as to define a closed volume communicating with said pathway.

8. The apparatus of claim 7 further comprising an oxygen generator connected to deliver oxygen to said closed pathway.

9. The apparatus of claim 7 further comprising means for admitting an amount of new air into said closed volume.

10. The apparatus of claim 9 further comprising means for exhausting from said closed volume an amount of air corresponding to said new air admitted.

11. An air manager system for a metal-air cell having an air cathode and defining a reactant air plenum, comprising:

an air passageway connected at one end thereof to said plenum at an air inlet and at another end thereof to said plenum at an air outlet;

said connected plenum and passageway forming a recirculation system isolated from general air circulation around said cell;

means for circulating air around said recirculation system; and

means for replacing air within said recirculation system in an amount sufficient only approximately to replace oxygen removed by operation of said cell.

12. An air manager system for a metal-air cell having an air cathode assembly and defining a reactant air plenum, said metal-air cell enclosed within a cell housing, comprising:

an air passageway connected at one end thereof to said plenum at an air inlet and at another end thereof to said plenum at an air outlet;

said connected plenum and passageway forming a recirculation system isolated from general air circulation around said cell;

an air moving device for circulating air around said recirculation system; and

at least one air exchange opening defined in said pathway for admitting only ambient air to said recirculation system, the rate of flow of said amount of ambient air being minimized to a rate needed to replace oxygen depleted by operation of said cell.

13. The apparatus of claim 12 wherein the opening is sized to permit a flow equal to the inverse of the difference between the percent of oxygen in the ambient air minus the desired oxygen content of the make-up air within said housing.

14. The apparatus of claim 13 wherein said opening is sized to permit an air flow rate of 9.1 times the rate at which oxygen is consumed.

15. The air manager system of claim 12, wherein said air inlet is open to said air plenum on a first side of said cell and said air outlet end is open to said air plenum on a second opposite side of said cell such that air flows through said pathway from said first side to said opposite second side.

16. The air manager system of claim 12, wherein said amount of ambient air admitted is in an amount such that the oxygen concentration of the air in said air reactant air path is maintained between 7 and 19 percent.

17. The air manager system of claim 12, wherein said air moving device for directing said flow of air throughout said channels is within said air plenum.

18. The air manager system of claim 17, wherein said air moving device is in said air plenum and said air exchange opening is on a positive pressure side of said air moving device.

19. The air manager system of claim 12, wherein said air exchange opening has an area from between about 0.05 square inch to about 0.15 square inch.

20. The air manager system of claim 12, wherein said air cathode assembly comprises a perforated air plenum enclosing an air cathode so as to define a select volume interacting with said pathway.

21. The air manager system of claim 12, wherein said metal-air cell is rechargeable, said rechargeable metal-air cell generating oxygen and hydrogen gas within said housing during cell charging, further comprising a catalyst element positioned within said housing, said catalyst element catalyzing a recombination of oxygen and hydrogen gas.

22. The air manager system of claim 17, wherein said catalyst element is positioned within said pathway.

23. The air manager system of claim 17, wherein said catalyst element is positioned in the path of said flow of air from said air moving device.

24. The air manager system of claim 20, wherein said air moving device pulsates during cell charging, said pulsating air moving device creating a pulsating air flow.

25. The air manager system of claim 23, wherein said catalyst element is palladium.

26. A metal-air power supply including a metal-air cell for providing energy to a load, wherein said load has a plurality of modes of operation, comprising:

an air cathode and an anode;

a reactant air pathway directed adjacent to said cathode, said pathway being operative for directing a flow of air adjacent to the air cathode to provide reactant air and for removing the reactant air from adjacent to the air cathode;

an adjustable air inlet for admitting ambient air into the flow of said recirculating reactant air;

an output monitoring circuit connected to measure an output current drawn from said metal-air cell during operation of said load; and

output control means, connected to said load, for monitoring the mode of operation of said load and for operating said air inlet responsive to the mode of operation of said load.

27. The apparatus of claim 26 wherein said output control means adjusts said air inlet to a predetermined optimum position for the detected mode of operation.

28. The apparatus of claim 27 wherein said output control means further comprises means for storing a value for the optimum air inlet position for a particular mode of operation of said load.

29. The apparatus of claim 28 wherein said output control means adjusts said air inlet to a predetermined optimum position based on said value stored for the optimum air inlet position stored in said means for storing.

30. The apparatus of claim 29 wherein said output control means further comprises means for determining whether said air inlet position is positioned at the predetermined optimum position based on the mode of operation of said load and for adjusting said air inlet when said air inlet is not positioned at the predetermined optimum position.

31. The apparatus of claim 30 further comprising means for determining the amount of current being drawn by said load, and means for adjusting said air inlet based on a comparison of the mode of operation of said load with said amount of current being drawn.

32. The apparatus of claim 31 wherein said output control means further comprises a timer and means for starting said timer when said air inlet position is not at the optimum position for the present mode of operation of said load and said current drawn is less than the minimum current required for the present mode of operation of said load and wherein said output control means adjusts said air inlet position to the preselected optimum position after said timer indicates that a preselected time limit has expired.

33. An air manager system for an metal-air battery, comprising:

a housing,

an arrangement of one or more cell stacks within said housing, said cell stacks each further comprising a plurality of metal-air cells each having a cell casing and an air cathode assembly, said cells positioned at spaced apart levels by one or more spacer barriers extending between each said air cathode assembly and a facing wall, said facing wall being a portion of said housing or of the cell casing of an adjacent cell;

an air pathway, said air pathway comprising;

a plurality of channels, said channels defined by said spacer barriers and by said facing walls, said channels each having an air inlet end and an air outlet end; and

an air plenum defined within said housing, said air plenum opened to said air inlet ends and to said air outlet ends of said channels

an air moving device positioned to direct a flow of air throughout said channels from said air inlet end to said air outlet end, the air becoming depleted of oxygen in said channels by the operation of said cells; and

at least one air exchange opening in said pathway for exchanging a select amount of the depleted air with ambient air from outside of said housing through said air exchange opening, said select amount based on the oxygen depleted by the operation of said cells, the non-exchanged depleted air being recirculated with said ambient air by said air moving device.

34. The air manager system of claim 33, wherein said air inlet ends of said channels are open to said air plenum on a first side of said cell stack arrangement and said air outlet ends are open to said air plenum on a second opposite side of said cell stack arrangement such that air flows through said channels of said cell stacks from said first side to said opposite second side.

35. The air manager system of claim 33, wherein said spacer barriers are positioned such that, at each level, air flows from said air inlet end of said channel adjacent to a portion of said air cathode assembly in a first direction and then in an opposite direction adjacent to the remaining portion of said air cathode assembly to said air outlet end.

36. The air manager system of claim 33, wherein said cell stacks are positioned adjacent to each other, and said air cathode assemblies are spaced apart an equal distance in said adjacent cell stacks, said channels being between the same levels of cells in said adjacent cells stacks such that said channels each span all of said cell stacks.

37. The air manager system of claim 33, wherein said spacer barriers are positioned in said channels such that, at each channel, air flows from said air inlet end of said channel adjacent to a portion of said air cathode assemblies in a first direction and then in an opposite direction adjacent to the remaining portion of said air cathode assemblies to said air outlet end.

38. The air manager system of claim 33, wherein said select amount of air exchanged is in an amount such that the oxygen concentration of the air in said air plenum is maintained between 7 and 19 percent.

39. The air manager system of claim 33, wherein said air moving device for directing said flow of air throughout said channels is within said air plenum.

40. The air manager system of claim 33, wherein said air moving device is in said air plenum and said air exchange opening is on a positive pressure side of said air moving device.

41. The air manager system of claim 33, wherein said air exchange opening has an area from between about 0.05 square inch to about 0.15 square inch.

42. The air manager system of claim 33, wherein said air cathode assembly comprises a perforated air plenum enclosing an air cathode so as to define a select volume interacting with said channels.

43. A rechargeable metal-air battery comprising:

a housing;

at least one metal-air cell within said housing, said metal-air cell generating oxygen and hydrogen gas during cell charging;

an air flow path within said housing,

a catalyst element positioned in said air flow path, said catalyst element catalyzing the recombination of oxygen and hydrogen gas; and

an air moving device for directing a flow of the generated oxygen and hydrogen gas from said cells to said catalyst element during cell charging.

44. The air manager system of claim 43, wherein said air moving device pulsates during cell charging, said pulsating air moving device creating a pulsating air flow.

45. The air manager system of claim 43, wherein said air flow path is a recirculation air flow path directing gas flowing from said cells back to said cells.