Packaging material for thin film lithium batteries

• US 5,561,004 A
• Filed: 02/25/1994
• Issued: 10/01/1996
• Est. Priority Date: 02/25/1994
• Status: Expired due to Term

• Current Assignee: Martin Marietta Energy Systems, Inc.
• Original Assignee: Martin Marietta Energy Systems, Inc.
• Inventors: Dudney, Nancy J., Bates, John B., Weatherspoon, Kim A.
• Primary Examiner(s): Maples, John S.
• Application Number:
  US08/202,649
• Time in Patent Office: 949 Days
• Field of Search: 429/163, 429/162, 429/177, 429/185
• US Class Current: 429/162
• CPC Class Codes: H01M 50/117 Inorganic material
• CPC Class Codes: H01M 50/119 Metals
• CPC Class Codes: H01M 50/121 Organic material
• CPC Class Codes: H01M 50/124 having a layered structure
• CPC Class Codes: H01M 50/141 for protecting against humidity
• CPC Class Codes: H01M 6/18 with solid electrolyte
• CPC Class Codes: H01M 6/185 with oxides, hydroxides or oxysalts as solid electrolytes
• CPC Class Codes: H01M 6/40 Printed batteries , e.g. thin film batteries

Abstract

A thin film battery including components which are capable of reacting upon exposure to air and water vapor incorporates a packaging system which provides a barrier against the penetration of air and water vapor. The packaging system includes a protective sheath overlying and coating the battery components and can be comprised of an overlayer including metal, ceramic, a ceramic-metal combination, a parylene-metal combination, a parylene-ceramic combination or a parylene-metal-ceramic combination.

Claims

1. In a thin film battery including a thin film-deposited lithium anode which is capable of reacting upon exposure to air and water vapor, the improvement comprising:

a thin film-deposited protective sheath overlying and directly contacting the lithium anode of the battery so that every surface region of the lithium anode which is not contacted by another component of the thin-film battery is coated by the protective sheath so that the sheath provides a thin film barrier coating against the penetration of air and water vapor to the lithium anode.

2. The improvement as defined in claim 1 wherein said protective sheath includes a material selected from the group consisting of ceramic and parylene.

3. The improvement as defined in claim 1 wherein said protective sheath includes an overlayer selected from the group consisting of a metal overlayer, a ceramic overlayer, a ceramic-metal overlayer, a parylene-metal overlayer, a parylene-ceramic overlayer and a parylene-metal-ceramic overlayer.

4. The improvement as defined in claim 3 wherein the overlayer is a metal overlayer, and the metal of the overlayer does not alloy with lithium when placed in contact therewith.

5. The improvement as defined in claim 4 wherein the metal of the overlayer is chosen from a group consisting of chromium, iron, titanium, nickel, vanadium and manganese.

6. The improvement as defined in claim 3 wherein the overlayer is a ceramic overlayer, and the ceramic of the overlayer is lithium phosphorus oxynitride.

7. The improvement as defined in claim 2 wherein the sheath includes a layer of parylene which is in direct contact with at least one component of the battery.

8. The improvement as defined in claim 7 wherein the layer of parylene is a first layer and the sheath includes a second layer including material chosen from a group consisting of metal, ceramic and a metal-ceramic combination and wherein the second layer overlies the first layer.

9. The improvement as defined in claim 8 wherein the material of the second layer is metal and the metal of the second layer is selected from the group consisting of aluminum, titanium, vanadium, chromium and manganese.

10. The improvement as defined in claim 8 wherein the second layer is comprised of metal and the thickness of the first layer is at least about 500 nm and the thickness of the second layer is at least about 50 nm.

11. The improvement as defined in claim 8 wherein the first and second layers comprise a first upon the battery components and the sheath includes at least one additional laminate buildup overlying the first laminate buildup wherein each additional laminate buildup includes a layer of parylene and a layer of material chosen from a group consisting of metal, ceramic and a metal-ceramic combination.

12. The improvement as defined in claim 11 wherein each of the second and fourth layers is comprised of metal and the thickness of each of the first and third layers is at least about 500 nm and the thickness of each of the second and fourth layers is at least about 50 nm.

13. The improvement as defined in claim 1 further comprising a coating of ultraviolet-cured epoxy overlying the protective sheath.

14. An improved thin-film, electrochemical cell comprising:

a) a substrate;

b) a first conductive film and a second electrically conductive film which are each deposited on the surface of said substrate and in a spaced horizontal relationship from one another;

c) a third film of electrically conductive cathode material deposited over said first film;

d) a fourth film of an electrolyte having nitrogen contained therein deposited on and overlapping said third film to extend upon said first film and to partially extend upon a section of said substrate which separates said first and second films;

e) a fifth film of electrically conductive anode material deposited over the remainder of said substrate separating said first and second films and over a portion of each of said second and fourth films; and

f) a thin film-deposited outer sheath of a thin film protective coating which overlies and coats the films and which is nonreactive with said fifth film and provides a barrier against the penetration of air and water vapor.

15. The cell as defined in claim 14 wherein said protective coating includes a material selected from the group of metal, ceramic and parylene.

16. The cell as defined in claim 14 wherein said protective coating includes an overlayer selected from the group consisting of a metal overlayer, a ceramic overlayer, a ceramic-metal overlayer, a parylene-metal overlayer, a parylene-ceramic overlayer and a parylene-metal-ceramic overlayer.

17. The cell as defined in claim 16 wherein the metal of the overlayer is chosen from a group consisting of chromium, iron, titanium, nickel, vanadium and manganese.

18. The cell as defined in claim 16 wherein the overlayer is a ceramic overlayer, and the ceramic of the overlayer is one of a metal nitride and a metal oxide.

19. The cell as defined in claim 15 wherein the coating includes a layer of parylene which is in direct contact with at least one component of the battery.

20. The cell as defined in claim 18 wherein the layer of parylene is a first layer and the coating includes a second layer including material chosen from a group consisting of metal and ceramic and wherein the second layer overlies the first layer.

21. The cell as defined in claim 20 wherein the material of the second layer is metal, and the metal of the second layer is selected from the group consisting of aluminum, titanium, vanadium, chromium and manganese.

22. The cell as defined in claim 14 wherein the outer coating includes overlayers which are selected from the group consisting of metal overlayers, ceramic overlayers, ceramic-metal overlayers, parylene-metal overlayers, parylene-ceramic overlayers and parylene-metal-ceramic overlayers.

23. The cell as defined in claim 14 further comprising a coating of ultraviolet-cured epoxy overlying the outer sheath.

24. In a thin film battery including components which are capable of reacting upon exposure to air and water vapor, the improvement comprising:

a thin film-deposited protective sheath overlying and coating the battery components so that the sheath provides a thin film barrier against the penetration of air and water vapor wherein the protective sheath includes a layer of parylene which is in direct contact with at least one component of the battery, and the layer of parylene is a first layer and the sheath includes a second layer including material chosen from a group consisting of metal, ceramic and a metal-ceramic combination and wherein the second layer overlies the first layer.

25. The improvement as defined in claim 24 wherein the material of the second layer is metal and the metal of the second layer is selected from the group consisting of aluminum, titanium, vanadium, chromium and manganese.

26. The improvement as defined in claim 24 wherein the second layer is comprised of metal and the thickness of the first layer is at least about 500 nm and the thickness of the second layer is at least about 50 nm.

27. The improvement as defined in claim 24 wherein the first and second layers comprise a first laminate buildup upon the battery components and the sheath includes at least one additional laminate buildup overlying the first laminate buildup wherein each additional laminate buildup includes a layer of parylene and a layer of material chosen from a group consisting of metal, ceramic and a metal-ceramic combination.

28. The improvement as defined in claim 27 wherein each of the second and fourth layers is comprised of metal and the thickness of the first and third layers is at least about 500 nm and the thickness of each of the second and fourth layers is at least about 50 nm.

29. In a thin film battery including components which are capable of reacting upon exposure to air and water vapor, the improvement comprising:

a thin film-deposited protective sheath overlying and coating the battery components so that the sheath provides a thin film barrier against the penetration of air and water vapor; and

a coating of ultraviolet-cured epoxy overlying the protective sheath.