Secondary battery having non-aqueous electrolyte

• US 5,561,005 A
• Filed: 04/28/1994
• Issued: 10/01/1996
• Est. Priority Date: 04/28/1993
• Status: Expired due to Term

• Current Assignee: Sony Corporation (Sony Group Corp.)
• Original Assignee: Mitsui Petrochemical Industries, Ltd. (Mitsui Chemicals), Sony Corporation (Sony Group Corp.)
• Inventors: Yokoyama, Keiichi, Hihara, Akio, Omaru, Atsuo, Fujita, Shigeru
• Primary Examiner(s): Willis, Jr., Prince
• Assistant Examiner(s): CHANEY, CAROL DIANE
• Application Number:
  US08/233,992
• Time in Patent Office: 887 Days
• Field of Search: 429/197
• US Class Current: 429/326
• CPC Class Codes: H01M 10/0569 characterised by the solvents
• CPC Class Codes: H01M 4/583 Carbonaceous material, e.g. graphite-intercalation compounds or CFx
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

A secondary battery having a non-aqueous electrolyte according to the present invention includes a negative electrode using a carbonaceous material capable of doping and undoping lithium ions as the anode material, a positive electrode using a composite oxide of lithium and-a transition metal as the cathode material, and a non-aqueous electrolyte formed by dissolving an electrolyte into a non-aqueous solvent, the non-aqueous solvent containing methylethyl carbonate and dimethyl carbonate. According to the present invention, a secondary battery having a non-aqueous electrolyte in which normal charge/discharge reactions can be maintained even in battery overcharge and after high-temperature storage of the charged battery, and which exhibits high energy density, long cycle life, high safety performance and excellent environment-resistance, can be produced.

Claims

1. A secondary battery having a non-aqueous electrolyte comprising:

a negative electrode consisting essentially of a resin binder and a non-graphitic carbonaceous material capable of doping and undoping lithium ions as an active anode material, said non-graphitic carbonaceous material exhibiting an interplanar distance of the (002) plane of 0.37 nm and greater, a true density of 1.7 g/cm³ and less, and an exothermic peak at 700°

C. and lower observed in differential thermal analysis in an air current;

a positive electrode including a composite oxide of lithium and a transition metal as an active cathode material; and

a non-aqueous electrolyte including a dissolved electrolyte in a non-aqueous solvent, the solvent including from about 20% to about 80% by volume of a mixture of methylethyl carbonate and dimethyl carbonate wherein the volume ratio of methylethyl carbonate and dimethyl carbonate is from about 1;

9 to about 8;

2, respectively, and a high dielectric constant propylene carbonate solvent.

2. The secondary battery having a non-aqueous electrolyte as is claimed in claim 1, wherein diethyl carbonate is present in the non-aqueous solvent in an amount of from about 1 to 20 vol %.

3. A secondary battery as defined in claim 1, wherein the dissolved electrolyte is selected from the group consisting of:

LiPF₆, LiClO₄, LiAsF₆ and LiBF₄ and the dissolved electrolyte is present in an amount of from about 0.1 to about 3 moles per liter of non-aqueous solvent.

4. A secondary battery as defined in claim 1, wherein the composite oxide is LiCoO₂.

5. A secondary battery having a non-aqueous electrolyte comprising:

a negative electrode consisting essentially of a graphitic carbonaceous material capable of doping and undoping lithium ions as an active anode material, said graphitic carbonaceous material exhibiting an interplanar distance of the (002) plane of 0.340 nm and smaller, a crystallite size of 14.0 nm and greater in C-axis, and a true density of 2.1 g/cm³ and greater;

a positive electrode including a composite oxide of lithium and a transition metal as an active cathode material; and

a non-aqueous electrolyte including a dissolved electrolyte in a non-aqueous solvent, the solvent including from about 20% to about 80% by volume of a mixture of methylethyl carbonate and dimethyl carbonate wherein the volume ratio of methylethyl carbonate and dimethyl carbonate is from about 1;

9 to about 8;

2, respectively, and a high dielectric constant ethylene carbonate solvent.

6. A secondary battery as defined in claim 5, wherein the dissolved electrolyte is selected from the group consisting of:

LiPF₆, LiClO₄, LiAsF₆ and LiBF₄ and the dissolved electrolyte is present in an amount of from about 0.1 to about 3 moles per liter of non-aqueous solvent.

7. A secondary battery as defined in claim 5, wherein the composite oxide is LiCoO₂.