Tin oxide based conductive powders and coatings

• US 5,565,144 A
• Filed: 04/24/1995
• Issued: 10/15/1996
• Est. Priority Date: 08/18/1994
• Status: Expired due to Term

• Current Assignee: Milliken & Company
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Hormadaly, Jacob, Feist, Thomas P., Jacobson, Howard W.
• Primary Examiner(s): Lieberman, Paul
• Assistant Examiner(s): Delcotto, Gregory R.
• Application Number:
  US08/427,313
• Time in Patent Office: 540 Days
• Field of Search: 252/518, 106/443, 423/593
• US Class Current: 252/520.1
• CPC Class Codes: C01G 19/02 Oxides
• CPC Class Codes: C09D 5/24 Electrically-conducting paints conductive materials H01B1/00
• CPC Class Codes: H01B 1/08 oxides
• CPC Class Codes: H01B 1/20 Conductive material dispersed in non-conductive organic material organic macromolecular compounds or compositions C08

Abstract

A product and process are disclosed that relate to electroconductive powders based on tantalum niobium, or phosphorus or any combination thereof doped tin oxide and coatings containing such powders. These powders can be used for making transparent coated films that are conductive and have desirable properties for a number of end uses. Some important end uses are in static dissipative fiber and films, coatings for recyclable containers, materials involved in packaging, where the presence of certain heavy metals is undesirable, transparent conductive coatings, among other uses.

Claims

1. An electroconductive powder consisting essentially of about 0.1 to 10% by weight of silica and tin oxide doped with tantalum wherein said powder is substantially free of pyrochlore.

4. The electroconductive powder of claim 1, 2 or 3 wherein the distance from whiteness is less than about 20%.

5. The electroconductive powder of claim 1, 2 or 3 wherein said dopant ranges from about 0.25 to 15 wt % based upon the tin oxide.

6. The electroconductive powder of claim 1, 2 or 3 wherein said powder comprises crystallites that range is size from about 40-500 Angstroms.

7. The electroconductive powder of claim 1, 2 or 3 wherein said powder has a dry powder resistivity of about 0.1 to 1,000 Ohms.

2. An electroconductive powder consisting essentially of about 0.1 to 10% by weight of silica and tin oxide doped with at least one member selected from the group of tantalum and niobium;

wherein said powder is substantially free of pyrochlore.

3. An electroconductive powder consisting essentially of tin oxide which has been doped with phosphorus and at least one member from the group of Ta and Nb.

8. The electroconductive powder of claim 3 further consisting essentially of silica.