Hair relaxer compositions

• US 5,565,216 A
• Filed: 07/21/1993
• Issued: 10/15/1996
• Est. Priority Date: 07/21/1993
• Status: Expired due to Term

• Current Assignee: Aminco, Inc. (L'Oreal SA)
• Original Assignee: Carson Products Co. (Cosmair)
• Inventors: Adair, Tony R., Cowsar, Donald R.
• Primary Examiner(s): VENKAT, JYOTHSNA A
• Application Number:
  US08/093,956
• Time in Patent Office: 1,182 Days
• Field of Search: 424/71, 424/702, 424/704
• US Class Current: 424/704
• CPC Class Codes: A61K 2800/88 Two- or multipart kits
• CPC Class Codes: A61K 8/19 containing inorganic ingredients
• CPC Class Codes: A61K 8/43 Guanidines
• CPC Class Codes: A61Q 5/04 Preparations for permanent waving or straightening the hair

Abstract

The present invention relates to a two-component hair relaxer system comprising (a) a first component comprising a cream base containing a water-soluble salt of a relatively strong base with an anion capable of being precipitated by an alkaline earth metal ion under highly alkaline conditions, and (b) a second, separate component, which is substantially free of water, and containing an alkaline material having an alkaline earth metal ion which forms a precipitate with the anion when the first component and second component are mixed.

Claims

1. A two-component hair relaxer system for producing an alkaline hydroxide relaxer for relaxing hair comprising:

(a) a first component comprising a water-containing cream base containing a water-soluble salt of a relatively strong base selected from the group consisting of quanidine and N-methyl guanidine with an anion capable of being precipitated by an alkaline earth metal ion under highly alkaline conditions, and

(b) a second, separate component, which is substantially free of water, and containing an alkaline material which is an alkaline earth metal hydroxide, an alkaline earth metal oxide, or a mixture thereof having an alkaline earth metal ion which forms a precipitate with the anion when the first component and second component are mixed.

2. The relaxer system according to claim 1, wherein the anion of the water-soluble salt is selected form the group consisting of carbonate, sulfate, sulfite, phosphate, fluoride, oxalate, tartrate, laurate and alginate.

3. The relaxer system of claim 1, wherein the water-soluble salt is guanidine carbonate.

4. The relaxer system of claim 1, wherein the water-soluble salt is present in the cream base in an amount of 1 to 20% by weight of the cream base.

5. The relaxer system according to claim 1, wherein the water-soluble salt is present in the cream base in an amount of from about 1 to about 10% by weight of the cream base.

6. The relaxer system according to claim 1, wherein the water-soluble salt is present in the cream base in an amount of from about 6 to about 8% by weight of the cream base.

7. The relaxer system according to claim 1, wherein the cream base contains a conditioning agent.

8. The relaxer system according to claim 7, wherein the conditioning agent is present in an amount of about 0.1 to about 4% by weight of the cream base.

9. The relaxer system according to claim 7, wherein the conditioning agent is a non-polymeric quaternary nitrogen containing compound.

10. The relaxer system according to claim 1, wherein the alkaline material is calcium hydroxide, calcium oxide or a mixture thereof.

11. The relaxer system according to claim 1, wherein the second component contains less than about 20 weight percent water.

12. The relaxer system according to claim 1, wherein the second component contains less than 10% by weight water.

13. The relaxer system according to claim 1, wherein the second component is anhydrous.

14. The relaxer system according to claim 1, wherein the second component is a pourable suspension which contains 20 to 60 weight percent of the alkaline material.

15. The relaxer system according to claim 1, wherein the second component contains a water-miscible, hydrophilic liquid carrier.

16. The relaxer system according to claim 15, wherein the liquid carrier is a polyhydroxy compound or an ether.

17. The relaxer system according to claim 15, wherein the liquid carrier is selected from the group consisting of propylene glycol, glycerine, butylene glycol and hexylene glycol.

18. The relaxer system according to claim 1, wherein the second component is a powder.

19. The relaxer system according to claim 18, wherein the alkaline material is present in the powder in an amount of 20 to 100% by weight of the powder.

20. The relaxer system according to claim 1, wherein the alkaline material is present in the second component in an amount sufficient to provide a molar excess of from 5 to 200% with respect to the water-soluble salt of the cream base.

21. The relaxer system according to claim 1, wherein the volume ratio of the second component to the first component is from one part by volume second component to about 8 to 50 parts by volume first component.

22. The relaxer system according to claim 21, wherein the volume ratio of the second component to the first component is from one part by volume second component to about 10 to 25 parts by volume first component.

23. The relaxer system according to claim 1, wherein the density of the second component is from about 1.4 gm/ml to about 2.34 gm/ml.

24. The relaxer system according to claim 1, wherein the weight ratio of second component to first component is from one part by weight second component to about 6 to 30 parts by weight first component.

25. The relaxer system according to claim 1, wherein the weight ratio of second component to first component is from one part by weight second component to about 10 to 15 parts by weight first component.

26. The relaxer system according to claim 1, wherein the water-soluble salt is a salt of relatively strong organic nitrogen containing base with a carbonate anion and which is susceptible to alkaline hydrolysis and formation of ammonia, and wherein the first component contains a carbonate/bicarbonate buffer to retard decomposition of the water-soluble salt and formation of ammonia.

27. The relaxer system according to claim 26, wherein the buffer provides the cream base with a pH of from about 9.5 to about 10.5.

28. The relaxer system according to claim 27, wherein an acid which does not interfere with the relaxing is present in the cream base to form the buffer and provide the pH of from about 9.5 to about 10.5.

29. The relaxer system according to claim 28, wherein the acid is one which does not cause a degree of reversion of greater than about 15%.

30. The relaxer system according to claim 28, wherein the acid is an organic acid.

31. The relaxer system according to claim 28, wherein the acid is at least one acid selected from the group consisting of an aliphatic acid, an alicyclic acid, an aromatic acid and a heterocyclic acid.

32. The relaxer system according to claim 28, wherein the acid is at least one acid selected from the group consisting of a monocarboxylic acid and a dicarboxylic acid.

33. The relaxer system according to claim 28, wherein the acid is at least one acid selected from the group consisting of an aliphatic monocarboxylic acid and an aliphatic dicarboxylic acid.

34. The relaxer system according to claim 28, wherein the acid is at least one acid selected from the group consisting of succinic acid, maleic acid, oxalic acid, glutamic acid and lactic acid.

35. The relaxer system according to claim 28, wherein the acid is at least one acid selected from the group consisting of succinic, maleic acid, and glutamic acid.

36. The relaxer system according to claim 28, wherein the acid is succinic acid.

37. The relaxer system according to claim 28, wherein the acid is glutamic acid.

38. The relaxer system according to claim 28, wherein the acid is an inorganic acid.

39. The relaxer system according to claim 28, wherein the acid is sulfuric acid or phosphoric acid.

40. The relaxer system according to claim 28, wherein the acid contains at least one substituent selected from the group consisting of an amino group and a hydroxy group.

41. The relaxer system according to claim 28, wherein the acid is present in an amount of from about 2 to 20 mol % of the number of mols of water-soluble salt.

42. The relaxer system according to claim 28, wherein the acid is present in an amount of from 5 to 10 mol % of the number of mols of water-soluble salt.

43. The relaxer system according to claim 27, wherein the first component contains a pH indicator.

44. The relaxer system according to claim 43, wherein the pH indicator is present in an amount of from 0.0005 to 0.5% by weight of the first component.

45. The relaxer system according to claim 43, wherein the pH indicator is selected from the group consisting of Tropaeolin "O", Thiazole Yellow "G", Eosin I, Pourriers Blue, Mordant Blue #1, Mordant Red #3 and External D&

C Violet #2.

46. A process for producing a hair relaxer composition for relaxing hair comprising mixing the first component and second component of claim 1.

47. A hair relaxer composition comprising the mixture resulting from admixing the first component and second component of claim 26.

51. A two component hair relaxer system according to claim 1, wherein the water-soluble salt is guanidine carbonate and is present in the cream base in an amount of about 6 to about 8% by weight of the cream base, and the alkaline material is calcium hydroxide and is present in an amount sufficient to provide a molar excess of from 5 to 200% with respect to the guanidine carbonate.

52. A two component hair relaxer system according to claim 51, wherein the first component contains a carbonate/bicarbonate buffer to retard decomposition of the guanidine carbonate and formation of ammonia.

53. A two component hair relaxer system according to claim 52, wherein an acid which does not interfere with the relaxing process is present to form the buffer and provide a pH of from about 9.5 to 10.5.

54. A two component hair relaxer system according to claim 53, wherein the acid is at least one acid selected from the group consisting of a monocarboxylic acid and a dicarboxylic acid.

55. A two component hair relaxer system according to claim 53, wherein the acid is at least one acid selected from the group consisting of succinic acid, maleic acid and glutamic acid.

56. A two component hair relaxer system according to claim 51, wherein the weight ratio of second component to first component is from one part by weight second component to about 6 to 30 parts by weight first component.

48. A two-component hair relaxing system for producing an alkaline hydroxide relaxer for relaxing hair comprising:

(a) a first component comprising a liquid activator comprising a water-solution of a water-soluble salt of a relatively strong organic nitrogen containing base selected from the group consisting of guanidine and N-methyl guanidine with a carbonate anion and which is susceptible to alkaline hydrolysis and formation of ammonia, wherein the water-solution contains a carbonate/bicarbonate buffer to retard decomposition of the water-soluble salt and formation of ammonia, and

(b) a cream base which contains an alkaline material which is an alkaline earth metal hydroxide having an alkaline earth metal ion which forms a precipitate with the carbonate anion, the first component when subsequently mixed with the second component reacting with the alkaline material to produce a hair relaxer composition.

49. A two-component hair relaxing system according to claim 48, wherein the water-soluble salt is guanidine carbonate and the alkaline material is calcium hydroxide.

50. A two-component hair relaxing system according to claim 48, wherein the water-soluble salt is present in the first component in an amount of about 20 to about 30% by weight of the first component, and the alkaline material is present in the second component in an amount of about 4 to about 7% by weight of the second component.