Catalyst comprising an assembly of at least one wire and its use in combustion or in post-combustion

• US 5,565,401 A
• Filed: 07/31/1994
• Issued: 10/15/1996
• Est. Priority Date: 07/13/1993
• Status: Expired due to Fees

• Current Assignee: Institut Francais Du Petrole
• Original Assignee: Institut Francais Du Petrole
• Inventors: Le Page, Jean-Francois, Mabilon, Gil
• Primary Examiner(s): Caldarola, Glenn A.
• Application Number:
  US08/274,522
• Time in Patent Office: 807 Days
• Field of Search: 502/439, 502/527
• US Class Current: 502/439
• CPC Class Codes: B01J 23/862 Iron and chromium
• CPC Class Codes: B01J 35/56 Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
• CPC Class Codes: B01J 35/58 Fabrics or filaments

Abstract

The invention relates to a catalyst comprising an assembly of at least one wire that comprises, in % weight, between 60 and 90% iron, and between 10 and 25% chromium, at least one metal selected from the group formed by platinum, rhodium, palladium, ruthenium, iridium, gold and silver having been deposited on the assembly, the outside contour of the cross-section of the wire being included in a ring whose area is between a circle with a 90 μm diameter and a circle with a 5 mm diameter, the length of the wire being at least equal to 20 cm, and the assembly being mechanically integral, the wire having been subjected to a prior depositing of aluminum, in a proportion going up to 10% by weight in relation to the weight of the wire, followed by a redrawing.

A preferred assembly corresponds to a knitted structure (1) in the shape of a sock.

Claims

1. A catalyst comprising an assembly of at least one wire that comprises, by weight, about 60 to 90% iron, about 10 to 25% chromium, and up to about 10% aluminum, and deposited on the wire at least one metal which is platinum, rhodium, palladium, ruthenium, iridium, gold or silver the wire having a cross-section with an outside contour whose area ranges between that of a circle with about a 90 μ

m diameter and a circle with about a 5 mm diameter, the length of the wire being at least equal to about 20 cm, and wherein, prior to production of the assembly, aluminum is deposited on at least a portion of the assembly followed by redrawing of the wire.

2. A catalyst according to claim 1, wherein the assembly is coated before or during deposition of the platinum, rhodium, palladium, ruthenium, iridium, gold or silver with a layer comprising at least one of an aluminum oxide, a cerium oxide, a titanium oxide, a silicon oxide, or a vanadium oxide said layer optionally further comprising at least one compound of lanthanum, barium, iron or zirconium.

3. A catalyst according to claim 1, wherein the assembly is, prior to the metal depositing step subjected to the following:

a) winding said assembly so as to obtain at least one cylinder,

b) treating said cylinder to transform at least a portion of the aluminum present into alumina,

c) introducing said cylinder containing alumina into a tube,

d) rendering the cylinder contained in the tube coherent by brazing, soldering or sintering.

4. A catalyst according to 1, wherein the assembly is, prior to the metal depositing step subjected to the following:

a) winding the assembly so as to obtain at least one cylinder,

b) introducing said cylinder into a tube,

c) rendering the cylinder in the tube coherent by brazing, soldering or sintering,

d) treating the cylinder present in the tube to transform at least a portion of the aluminum present into alumina.

5. A catalyst according to claim 3 wherein, in between (a) and (b), the cylinder is compressed.

6. A catalyst according to claim 1 wherein the assembly is at least partially knitted or woven.

7. A catalyst according to claim 2, wherein the assembly is, prior to the coating step, subjected to the following:

a) winding so as to obtain at least one cylinder,

b) treating said cylinder to transform at least a portion of the aluminum present into alumina,

c) introducing said cylinder containing alumina into a tube,

d) rendering the cylinder contained in the tube coherent by brazing, soldering or sintering.

8. A catalyst according to claim 4, wherein in between (a) and (b), the cylinder is compressed.

9. A catalyst according to claim 6, wherein the wire is spirally wound to a substantially cylindrical shape.