Process for manufacturing granular igniter

• US 5,565,710 A
• Filed: 01/23/1995
• Issued: 10/15/1996
• Est. Priority Date: 01/24/1994
• Status: Expired due to Term

• Current Assignee: NOF Corporation
• Original Assignee: NOF Corporation
• Inventors: Sawada, Yoshio, Ochi, Koji, Asano, Nobukazu
• Primary Examiner(s): Jordan, Charles T.
• Assistant Examiner(s): Hardee, John R.
• Application Number:
  US08/377,712
• Time in Patent Office: 631 Days
• Field of Search: 264/3.6, 264/3.4, 264/3.5, 149/38, 149/111, 149/114
• US Class Current: 264/3.4
• CPC Class Codes: C06B 21/0066 by granulation, e.g. flaking
• CPC Class Codes: C06C 9/00 Chemical contact igniters; Chemical lighters
• CPC Class Codes: Y10S 149/111 Nitrated organic compound
• CPC Class Codes: Y10S 149/114 Inorganic fuel

Abstract

There is provided a process for manufacturing a granular igniter, which facilitates control of the igniter preparation, handling of the granule igniter and improvement in manufacturized yield. The present invention also provides a process for manufacturing a granular igniter which is free from toxic gas generation when burned and which has excellent fluidity. The present invention moreover reduces the number of manufacturing process facilitating the production process, and reducing production costs.

An igniter containing boron and potassium nitrate are mixed together with water in a homogenizer to form a homogeneous slurry. The mixing ratio of the igniter to the water is set in the range of 1.0:0.6 to 1.0:1.6 in terms of weight ratio. The slurry is sprayed in a spray dryer where it is dried and granulated. Micropowder, which failed to be collected as the granule, is recovered through a cyclone, and recirculated as the raw material.

Claims

1. A method for manufacturing granular igniter comprising:

a) forming a slurry by mixing an igniter material with an aqueous medium, said igniter material including a mixture of boron and potassium nitrate, in a weight ratio of said igniter material to the aqueous medium in a range from 100 to 60 to 100 to 140 by weight;

b) spraying the slurry in the form of droplets under a heated atmosphere in a spray dryer to obtain crude granular igniter;

c) subjecting said crude granular igniter to separation process by means of a cyclone cylinder to provide a first group of granular igniter and a second group of micropowder, the separated micropowder of said second group having an average diameter smaller than about 50 micrometers; and

d) recycling the micropowder separated in step c by mixing it with the slurry of step a.

2. The method as set forth in claim 1 wherein said boron has an average grain size in a range from 0.1 to 10 micrometers.

3. The method as set forth in claim 2 wherein said boron is amorphous and has a specific surface area in a range from 1 to 50 m² /g.

4. The method as set forth in claim 2 wherein said potassium nitrate has an average grain size of at most 100 micrometers.

5. The method as set forth in claim 4 wherein a weight ratio of boron to potassium nitrate is in a range from 1:

1 to 1;

9.

6. The method as set forth in claim 5 wherein said slurry is homogeneously formed by a homogenizer having a high speed turbine.

7. The method as set forth in claim 6 further including a step for heating the slurry from 40°

C. to 80°

C. before the spraying operation.

8. The method as set forth in claim 7 wherein the slurry is sprayed through a nozzle.

9. The method as set forth in claim 8 wherein the slurry is sprayed upward through a nozzle.

10. The method as set forth in claim 9 wherein said aqueous medium is water.

11. The method as set forth in claim 10 wherein said water is ion-exchanged water or distilled water.

12. The method as set forth in claim 5 wherein said igniter material further includes at least one agent selected from the group consisting of plasticizer, lubricant, slurry dispersant and antifoamer.

13. A method for manufacturing granular igniter comprising:

a) forming a slurry by mixing an igniter material with an aqueous medium, said igniter material including of mixture consisting of boron and potassium nitrate, in a weight ratio of said igniter material to the aqueous medium in a range from 100;

60 to 100;

140 by weight;

b) spraying the slurry in the form of droplets under a heated atmosphere to obtain crude granular igniter;

c) subjecting said crude granular igniter to separation process by means of a cyclone cylinder to provide a first group of granular igniter and a second group of micropowder, the separated micropowder of said second group having an average diameter smaller than about 50 micrometers; and

d) recycling the micropowder separated in step c by mixing it with the slurry of step a.

14. A method for manufacturing granular igniter comprising:

a) forming a slurry by mixing an igniter material with an aqueous medium, said igniter material including a mixture of magnesium and polytetrafluoroethylene both bound to each other by an inorganic binder, in a weight ratio of said igniter material to the aqueous medium in a range from 100 to 60 to about 100 to 140 by weight, a weight ratio of magnesium to polytetrafluoroethylene in a range from 7 to 3 to about 3 to 7;

b) spraying the slurry in the form of droplets under a heated atmosphere in a spray dryer to obtain crude granular igniter;

c) subjecting said crude granular igniter to separation process by means of a cyclone cylinder to provide a first group of granular igniter and a second group of micropowder, the separated micropowder of said second group having an average diameter smaller than about 50 micrometers; and

d) recycling the micropowder separated in step c by mixing it with the slurry of step a.

15. The method as set forth in claim 14 wherein said inorganic binder is a colloidal silica and the content of the colloidal silica in the igniter material is in a range from 1 to 10% by weight.

16. The method as set forth in claim 15 wherein said slurry is homogeneously formed by a homogenizer having a high speed turbine.

17. The method as set forth in claim 16, further including a step for heating the slurry from 40°

C. to 80°

C. before the spraying operation.

18. The method as set forth in claim 17 wherein the slurry is sprayed through a nozzle.

19. The method as set forth in claim 18 wherein the slurry is sprayed upward through a nozzle.

20. The method as set forth in claim 19, wherein said aqueous medium is water.

21. The method as set forth in claim 20 wherein said water is ion-exchanged water or distilled water.

22. The method as set forth in claim 15 wherein said igniter material further includes at least one agent selected from the group consisting of plasticizer, lubricant, slurry dispersant and antifoamer.

23. A method for manufacturing granular igniter comprising:

a) forming a slurry by mixing an igniter material with an aqueous medium, said igniter material including a mixture consisting of magnesium and polytetrafluoroethylene both bound to each other by an inorganic binder, in a weight ratio of said igniter material to the aqueous medium in a range from 100;

60 to 100;

140 by weight, a weight ratio of magnesium to polytetrafluoroethylene in a range from 7;

3 to 3;

7;

b) spraying the slurry in the form of droplets under a heated atmosphere to obtain crude granular igniter;

c) subjecting said crude granular igniter to separation process by means of a cyclone cylinder to provide a first group of granular igniter and a second group of micropowder, the separated micropowder of said second group having an average diameter smaller than about 50 micrometers; and

d) recycling the micropowder separated in step c by mixing it with the slurry of step a.