Method for making an electrochemical cell

• US 5,567,210 A
• Filed: 07/12/1994
• Issued: 10/22/1996
• Est. Priority Date: 07/29/1992
• Status: Expired due to Term

• Current Assignee: Martin Marietta Energy Systems, Inc.
• Original Assignee: Martin Marietta Energy Systems, Inc.
• Inventors: Dudney, Nancy J., Bates, John B.
• Primary Examiner(s): Maples, John S.
• Application Number:
  US08/248,891
• Time in Patent Office: 833 Days
• Field of Search: 29/623.5, 29/623.1, 429/127, 429/162
• US Class Current: 29/623.5
• CPC Class Codes: H01L 23/58 Structural electrical arrangements for semiconductor devices not otherwise provided for , e.g. in combination with batteries H01L23/49593, H01L23/49596 take precedence
• CPC Class Codes: H01L 2924/00 Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
• CPC Class Codes: H01L 2924/0002 Not covered by any one of groups H01L24/00, H01L24/00 and H01L2224/00
• CPC Class Codes: H01L 2924/12044 OLED
• CPC Class Codes: H01M 50/209 adapted for prismatic or rectangular cells H01M50/216 takes precedence
• CPC Class Codes: H01M 6/18 with solid electrolyte
• CPC Class Codes: H01M 6/40 Printed batteries , e.g. thin film batteries
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product
• CPC Class Codes: Y10T 29/49108 Electric battery cell making
• CPC Class Codes: Y10T 29/49115 including coating or impregnating

Abstract

Described is a thin-film battery, especially a thin-film microbattery, and a method for making same having application as a backup or primary integrated power source for electronic devices. The battery includes a novel electrolyte which is electrochemically stable and does not react with the lithium anode and a novel vanadium oxide cathode Configured as a microbattery, the battery can be fabricated directly onto a semiconductor chip, onto the semiconductor die or onto any portion of the chip carrier. The battery can be fabricated to any specified size or shape to meet the requirements of a particular application. The battery is fabricated of solid state materials and is capable of operation between -15° C. and 150° C.

Claims

1. A method for making a thin-film electrochemical cell comprising the steps of:

a) depositing a first and a second horizontally displaced film of electrically conductive material on a substrate surface such that a portion of said substrate surface separates said first and second films, said first film being larger than said second film;

b) depositing a third film of electrically conductive material on said first film;

c) depositing a fourth film of an electrolyte having nitrogen contained therein on said third film to overlap said third film, the overlap of said fourth film extending onto said first film and partially onto said portion of said substrate separating said first and second films; and

d) depositing a fifth film of electrically conductive material over the remainder of said substrate separating said first and second films and over a portion of all of said second film and substantially all of said third film.

2. The method of claim 1 wherein said third film of electrically conductive material is an amorphous metal oxide.

3. The method of claim 1 wherein the electrolyte has the composition Li_x PO_y N_z where x has an approximate value of 2.8, 2y+3z has an approximate value of 7.8 and z has a value between 0.16 and 0.46.

4. The method of claim 1 wherein all films but said fourth film are deposited by a technique selected from the group consisting of reactive dc magnetron sputtering, rf magnetron sputtering, diode sputtering, and thermal evaporation.

5. The method of claim 1 wherein the fourth film is deposited by a technique selected from the group consisting of rf magnetron sputtering, diode sputtering, and thermal evaporation.