Craft curing of modified isomonoolefin/para-alkylstyrene copolymers

• US 5,567,775 A
• Filed: 06/06/1995
• Issued: 10/22/1996
• Est. Priority Date: 11/27/1989
• Status: Expired due to Fees

• Current Assignee: Exxon Chemical Patents Inc. (Exxon Mobil Corporation)
• Original Assignee: Exxon Chemical Patents Inc. (Exxon Mobil Corporation)
• Inventors: Gardner, Irwin J., Wang, Hsien C., Fusco, James V.
• Primary Examiner(s): JAGANNATHAN, VASUDEVAN SALEM
• Application Number:
  US08/469,285
• Time in Patent Office: 504 Days
• Field of Search: 525/279, 525/285, 525/296, 525/301, 525/302, 525/305, 525/308, 525/309, 525/312, 525/317, 525/319
• US Class Current: 525/279
• CPC Class Codes: C08F 210/00 Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
• CPC Class Codes: C08F 212/12 Monomers containing a branched unsaturated aliphatic radical or a ring substituted by an alkyl radical
• CPC Class Codes: C08F 290/04 Polymers provided for in subclasses C08C or C08F
• CPC Class Codes: C08F 8/00 Chemical modification by after-treatment graft polymers, block polymers, crosslinking with unsaturated monomers or with polymers C08F251/00 - C08F299/00; of conjugated diene rubbers C08C

Abstract

This invention provides for curable and graft-cured polymer compositions prepared from a mixture comprising:

a) an elastomeric copolymer containing from about 0.01 up to about 10 mole % of Y ester groups randomly distributed along and pendant to the elastomeric polymer chain, said Y ester groups having the structure: ##STR1## wherein R₂ and R₃ are independently selected from the group consisting of hydrogen and an alkyl group containing 1 to about 6 carbon atoms and R₄ is selected from the group consisting of hydrogen, an alkyl group containing from 1 to about 28 carbon atoms, an aryl group and an alkenyl group containing from 2 to about 28 carbon atoms; and

b) at least one free radically polymerizable monomer. The invention also provides for a process for preparing graft-cured polymer compositions comprising forming the above recited mixture of (a) and (b) and subjecting said mixture to free radical polymerization conditions. The Y ester groups pendant to the elastomeric polymer chain, e.g. benzylic(meth)acrylic acid ester groups present in isobutylene/para-methystyrene interpolymer chains, are capable of participating in free radical initiated reactions with monofunctional or polyfunctional free radically polymerizable monomers to produce graft-crosslinked compositions having an unusual balance of physical properties. These compositions may be formed into shaped articles such as films, coatings, adhesive layers and moldings and subjected to free radical polymerization conditions to produce crosslinked shaped articles.

Claims

1. A curable polymer composition comprising a mixture of:

a) an elastomeric polymer containing from about 0.01 up to about 10 mole % of Y ester groups randomly distributed along and pendant to the elastomeric polymer chain, said Y ester groups having the structure;

##STR6## wherein R₂ and R₃ are independently selected from the group consisting of hydrogen and an alkyl group containing 1 to about 6 carbon atoms and R₄ is selected from the group consisting of hydrogen, an alkyl group containing from 1 to about 28 carbon atoms, an aryl group and an alkenyl group containing from 2 to about 28 carbon atoms; and

b) at least one free radically polymerizable monomer.

2. The composition of claim 1 wherein said mixture further contains a free radical initiator.

3. The composition of claim 1 wherein said elastomeric polymer is a random interpolymer comprising at least about 80 weight % of polymerized isoolefin containing from 4 to 7 carbon atoms and from about 0.05 up to about 20 weight % of aromatic monomer units comprising a mixture of the following structure randomly distributed therein:

##STR7## wherein R and R'"'"' are independently selected from the group consisting of hydrogen and C₁ to C₄ alkyl.

4. The composition of claim 3 wherein said C₄ to C₇ isoolefin is isobutylene and said copolymer contains at least about 90 weight % isobutylene and wherein R and R'"'"' are each hydrogen.

5. The composition of claim 4 wherein R₂ is methyl and R₃ and R₄ are each hydrogen.

6. The composition of claim 4 wherein R₂, R₃ and R₄ are each hydrogen.

7. The composition of claim 4 wherein R₂ and R₃ are each hydrogen and R₄ is C₄ alkenyl.

8. The composition of claim 1 containing from about 0.05 to about 2.0 mole % of said Y ester groups.

9. The composition of claim 3 wherein from about 5 up to about 60 mole % of said mixed aromatic monomer units have the structure (b).

10. The composition of claim 3 wherein said elastomeric interpolymer has a number average molecular weight in the range of from about 25,000 to about 1,000,000 and a compositional distribution (Mw/Mn) of less than about 7.

11. The composition of claim 1 wherein said free radically polymerizable monomer is present in said mixture at a level of from about 1 to 100 parts by weight per 100 parts by weight of said elastomeric copolymer.

12. The composition of claim 11 wherein said monomer comprises a monofunctional monomer selected from the group consisting of styrene and substituted styrene, alkyl acrylates and methacrylates, acrylic acid, methacrylic acid, acrylonitrile, methacrylonitrile, vinyl esters, vinylethers, acrylamide, methacrylamide, vinyl carbazole, vinyl chloride, vinyl acetate, vinyl pyridine, vinyl pyrrolidone, maleic acid or anhydride and mixtures thereof.

13. The composition of claim 12 wherein said monomer further comprises a polyfunctional monomer selected from the group consisting of butadiene, isoprene, di- or trivinyl benzene, alkylene glycol di- or triacrylates or methacrylates and mixtures thereof.

14. The composition of claim 12 wherein said mixture further contains a free radical initiator selected from the group consisting of organic peroxides and hydroperoxides.

15. A process for preparing a graft-cured polymer composition by forming a mixture comprising:

a) an elastomeric polymer containing from about 0.01 up to about 10 mole % of Y ester groups randomly distributed along and pendant to the elastomeric polymer chain, said Y ester groups having the structure;

##STR8## wherein R₂ and R₃ are independently selected from the group consisting of hydrogen and an alkyl group containing 1 to about 6 carbon atoms and R₄ is selected from the group consisting of hydrogen, an alkyl group containing from 1 to about 28 carbon atoms, an aryl group and an alkenyl group containing from 2 to about 28 carbon atoms; and

b) at least one free radically polymerizable monomer,

and subjecting said mixture to free radical polymerization conditions.

16. The process of claim 15 wherein said elastomeric polymer is a random interpolymer comprising at least about 80 weight % of polymerized isoolefin containing from 4 to 7 carbon atoms and from about 0.05 up to about 20 weight % of aromatic monomer units comprising a mixture of the following structure randomly distributed therein:

##STR9## wherein R and R'"'"' are independently selected from the group consisting of hydrogen and C₁ to C₄ alkyl.

17. The process of claim 16 wherein said mixture further contains a free radical polymerization initiator.

18. The process of claim 17 wherein said mixture is formed into a shaped article and wherein said free radical polymerization conditions comprise the application of heat sufficient to crosslink said shaped article.

19. A polymer composition comprising the cured reaction product of a mixture comprising:

a) an elastomeric polymer containing from about 0.01 up to about 10 mole % of Y ester groups randomly distributed along and pendant to the elastomeric polymer chain, said Y ester groups having the structure;

##STR10## wherein R₂ and R₃ are independently selected from the group consisting of hydrogen and an alkyl group containing 1 to about 6 carbon atoms and R₄ is selected from the group consisting of hydrogen, an alkyl group containing from 1 to about 28 carbon atoms, an aryl group and an alkenyl group containing from 2 to about 28 carbon atoms; and

b) at least one free radically polymerizable monomer.

20. The composition of claim 19 wherein said elastomeric polymer is a random interpolymer comprising at least about 80 weight % of polymerized isoolefin containing from 4 to 7 carbon atoms and from about 0.05 up to about 20 weight % of aromatic monomer units comprising a mixture of the following structure randomly distributed therein:

##STR11## wherein R and R'"'"' are independently selected from the group consisting of hydrogen and C₁ to C₄ alkyl.

21. The composition of claim 20 wherein said mixture further contains a free radical initiator.

22. The composition of claim 20 wherein said C₄ to C₇ isoolefin is isobutylene and said copolymer contains at least about 90 weight % isobutylene and wherein R and R'"'"' are each hydrogen.

23. The composition of claim 22 wherein R₂ is methyl and R₃ and R₄ are each hydrogen.

24. The composition of claim 22 wherein R₂, R₃ and R₄ are each hydrogen.

25. The composition of claim 22 wherein R₂ and R₃ are each hydrogen and R₄ is C₄ alkenyl.

26. The composition of claim 20 containing from about 0.05 to about 2.0 mole % of said Y ester groups.

27. The composition of claim 20 wherein from about 5 up to about 60 mole % of said mixed aromatic monomer units have the structure (b).

28. The composition of claim 20 wherein said elastomeric interpolymer has a number average molecular weight in the range of from about 25,000 to about 1,000,000 and a compositional distribution (Mw/Mn) of less than about 7.

29. The composition of claim 20 wherein said free radically polymerizable monomer is present in said mixture at a level of from about 1 to 100 parts by weight per 100 parts by weight of said elastomeric copolymer.

30. The composition of claim 29 wherein said monomer comprises a monofunctional monomer selected from the group consisting of styrene and substituted styrene, alkyl acrylates and methacrylates, acrylic acid, methacrylic acid, acrylonitrile, methacrylonitrile, vinyl esters, vinylethers, acrylamide, methacrylamide, vinyl carbazole, vinyl chloride, vinyl acetate, vinyl pyridine, vinyl pyrrolidone, maleic acid or anhydride and mixtures thereof.

31. The composition of claim 29 wherein said monomer further comprises a polyfunctional monomer selected from the group consisting of butadiene, isoprene, di- or trivinyl benzene, alkylene glycol di- or triacrylates or methacrylates and mixtures thereof.

32. The composition of claim 20 wherein said mixture further contains a free radical initiator selected from the group consisting of organic peroxides and hydroperoxides.

33. The composition of claim 20 wherein said cured reaction product is prepared by subjecting said mixture to free radical polymerization conditions.